• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.165-168
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• 2015

To measure laminar burning velocity in methane/air/ethylene mixture flame, propagating centrally ignited spherical premixed flame to radial direction was measured by high-speed schlieren images with elevated pressure. In this study, The experimentally measured unstretched laminar burning velocities of methane was compared with GRI mech 3.0 to validate experimental data and choose the radius range, respectively. numerical prediction using the PREMIX code with GRI mech 3.0, USC mech II,, and Wang mech were evaluated through comparison with experimental burning velocity with consideration of extrapolation on linear/nonlinear model.

• Journal of the Korea Safety Management & Science
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• v.25 no.1
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• pp.51-58
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• 2023

Determination of explosion reference pressure is important in designing and testing flameproof enclosures (Ex d). Although relative humidity affects to explosion pressure, its effect is not well investigated for the gas group IIB, IIA, and I. This study tested explosion pressure for Ethylene (8 vol.%), Propane (4.6 vol.%), and Methane (9.8 vol.%), which are the representative gas of the gas group IIB, IIA, and I, at ambient temperature and atmospheric pressure (1 atm) under different relative humidity (0% ~ 80%). Ethylene- and Propane-air mixed gases generally tended to decrease as the relative humidity increased; however, explosion pressure was largely dropped at 20% of relative humidity compared to 0% and 10% of relative humidity. On the other hand, Methane-air mixture gas showed similar pressures at 0% and 10% of relative humidity; but no explosion occurred at more than 20%. The results of this study can be used in setting a testing protocol of explosion reference pressure for designing and testing a flameproof enclosure.

• Journal of the Korean Society of Industry Convergence
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• v.16 no.1
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• pp.21-26
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• 2013

Burned gas of methane-air mixtures with water vapor have been analysed to study the exhaust emission using gas-chromatography and computation. The computations were carried out for the gas analysis using premix code of Chemkin program to compare the experimental results. The quantity of water vapor contained were changed 5% and 10% of total mixtures, and equivalence ratio of mixtures between 0.6 and 1.2 were tested under the ambient temperature 323K and 373K. The results showed CO, $CO_2$ decreased and $H_2$ increased by increasing the water contents. The CO increased and $CO_2$ decreased by increasing the ambient temperature. The $CO_2$ shows the maximum product at equivalence ratio 1.0, in otherwise the $CH_4$ produced the minimum values in the same range. The results showed little difference between these two methods.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.11
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• pp.916-923
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• 2009

The effects of configuration of fuel and air tubes on the flame stabilization were experimentally investigated in half-closed combustors. Flame behaviors and stabilities of methane, propane, and DME flames were compared by changing tube diameters and the locations of the fuel and air tubes. It was found that flammability limits are significantly affected by the outlet boundary condition, which disturbs compositions of burned and unburned mixtures near the flame base. And it was found that there exist critical inner tube heights, over which flame stability is determined only by the fuel flow rate. Conclusively, flame stabilization is governed by the flame propagation velocity in an ordinary mixing flow and the non-uniform mixture concentration in the combustion space which is affected by flow recirculation and the combustor configuration. The compositions of $NO_x$ and CO were compared to know basic characteristics of methane, propane, and DME flames.

• Journal of ILASS-Korea
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• v.3 no.4
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• pp.43-49
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• 1998

In order to clarify the effect of equivalence ratio and kinds of fule in flame structure, a numerical simulation of triple flame developed in a co-flowing methane-air and air stream was carried out by the elementary chemical reaction mechanism. The following conclusions were obtained. Equivalence ratio at which the apparent burning velocity is maximum is a little larger than that of the one-dimensional premixed flame. Apparent burning velocities are two times higher than that of the one-dimensional premixed flame for the methane-air. The flame thrusts out forward in the downstream of the boundary between mixture and air stream, and a part of the flow is bent and forks out in this protruding flame so that a triple flame is originated; this triple flame is composed of fuel rich and lean premixed flame branches and a diffusion flame branch. Near the equivalence ratio at which the burning velocity of rule-dimensional premixed flame is the largest the effect of one-dimensional premixed flame becomes large and the fuel rich premixed flame advances and becomes vertical to the flow direction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.4
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• pp.583-592
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• 2001

The combustion characteristics of the hybrid catalytic(catalytic+thermal) combustor with a lean methane-air mixture on platinum catalyst were investigated numerically using a 2-D boundary layer model with detailed homogeneous and heterogeneous chemistries. for the more accurate calculations, the actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. It was found that the homogeneous reactions in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. However, the radicals such as OH and CO were produced rapidly at exit by homogeneous reactions. The effect of operation conditions such as equivalence ratio, temperature, velocity, pressure and diameter of the monolith channel at the entrance were studied. In thermal combustor, the production of N$_2$O was more dominant than that of NO due to the relative importance of the reaction N$_2$+O(+M)→N$_2$O(+M). Finally the productions of CO and NOx by amount of methane addition were studied.

• Clean Technology
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• v.20 no.3
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• pp.314-320
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• 2014

The purpose of this work is to optimize composition of mixture refrigerants used in the C3MR (Propane & Mixed Refrigerants) process by a statistical optimization technique. C3MR studied in this work is one of widely used commercial natural gas liquefaction processes with high efficiency. Process simulation was performed in a commercial process simulator and methane ($C_1$), ethane ($C_2$), propane ($C_3$), and nitrogen ($N_2$) were selected as mixed refrigerants. Using the process model, optimum composition of refrigerants mixture was determined via mixture design and central composite design to produce minimum energy consumption. As a result, it was confirmed that energy consumption is reduced down to 11.3% comparing to existing design. It was also compared with heat effectiveness through temperature profile of MCHE (main cryogenic heat exchanger).

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.306-309
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• 2005

One of the most critical issues in sol id oxide fuel cell (SOFC)running on hydrocarbon fuels is the risk of carbon formation from the fuel gas. The simple method to reduce the risk of carbon formation from the reactions is to add steam to the fuel stream, leading to the carbon gasification react ion. However, the addition of steam to fuel is not appropriate for the auxiliary power unit (APU) and potable power generation (PPG) systems due to an increase of complexity and bulkiness. In this regard, many researchers have focused on so-called 'direct methane' operation of SOFC, which works with dry methane without coking. However, coking can be suppressed only by the operation with a high current density, which may be a drawback especially for the APU and PPG systems. The single chamber fuel cell (SC-SOFC) is a novel simplification of the conventional SOFC into which a premixed fuel/air mixture is introduced. It relies on the selectivity of the anode and cathode catalysts to generate a chemical potential gradient across the cell. Moreover it allows compact and seal-free stack design. In this study, we fabricated honeycomb type mixed-gas fuel cell (MGFC) which has advantages of stacking to the axial direction and increasing volume power density. Honeycomb-structured SOFC with four channels was prepared by dry pressing method. Two alternative channels were coated with electrolyte and cathode slurry in order to make cathodic reaction sites. We will discuss that the anode supported honeycomb type cell running on mixed gas condition.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.4
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• pp.276-282
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• 2008

The effects of hydrogen enrichment to methane have been investigated with swirl-stabilized premixed hydrogen-enriched methane flame in a laboratory-scale pre-mixed combustor. The hydrogen-enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of hydrogen addition to the methane fuel and different swirl strengths. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using micro-thermocouple, particle image velocity meter (PIV) and chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in ignition energy from recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The higher combustibility of hydrogen makes reaction faster, raises the temperature of reaction zone and expands the reaction zone, consequently recirculation flow to reaction zone is reduced. The temperature of reaction zone increases with hydrogen addition even though the adiabatic flame temperature of the mixture gas decreases with increase in the amount of hydrogen addition in this experiment condition because the higher combustibility of hydrogen reduces the cooler recirculation flow to the reaction zone.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.1
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• pp.75-81
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• 2012

Autoignited lifted flames in laminar jets with hydrogen-enriched methane fuels have been investigated experimentally in heated coflow air. The results showed that the autoignited lifted flame of the methane/hydrogen mixture, which had an initial temperature over 920 K, the threshold temperature for autoignition in methane jets, exhibited features typical of either a tribrachial edge or mild combustion depending on fuel mole fraction and the liftoff height increased with jet velocity. The liftoff height in the hydrogen-assisted autoignition regime was dependent on the square of the adiabatic ignition delay time for the addition of small amounts of hydrogen, as was the case for pure methane jets. When the initial temperature was below 920 K, where the methane fuel did not show autoignition behavior, the flame was autoignited by the addition of hydrogen, which is an ignition improver. The liftoff height demonstrated a unique feature in that it decreased nonlinearly as the jet velocity increased. The differential diffusion of hydrogen is expected to play a crucial role in the decrease in the liftoff height with increasing jet velocity.