• Title/Summary/Keyword: Metallic material

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Influence of Selenization Temperature on the Properties of Cu2ZnSnSe4 Thin Films (Selenization 온도가 Cu2ZnSnSe4 박막의 특성에 미치는 영향)

  • Yeo, Soo Jung;Gang, Myeng Gil;Moon, Jong-Ha;Kim, Jin Hyeok
    • Current Photovoltaic Research
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    • v.3 no.3
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    • pp.97-100
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    • 2015
  • The kesterite $Cu_2ZnSnSe_4$ (CZTSe) thin film solar cells were synthesized by selenization of sputtered Cu/Sn/Zn metallic precursors on Mo coated soda lime glass substrate in Ar atmosphere. Cu/Sn/Zn metallic precursors were deposited by DC magnetron sputtering process with 30 W power at room temperature. As-deposited metallic precursors were placed in a graphite box with Se pellets and selenized using rapid thermal processing furnace at various temperature ($480^{\circ}C{\sim}560^{\circ}C$) without using a toxic $H_2Se$ gas. Effects of Selenization temperature on the morphological, crystallinity, electrical properties and cell efficiency were investigated by field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD), J-V measurement system and solar simulator. Further details about effects of selenization temperature on CZTSe thin films will be discussed.

A study on the micro-formability of $Zr_{62}Cu_{17}Ni_{13}Al_8$ Bulk Metallic Glasses using micro-forging and Finite Element Method applications (마이크로 단조를 이용한 Zr 계 벌크 비정질합금의 미세 성형성 평가와 유한요소해석 적용에 관한 연구)

  • Kang Sung-Gyu;Park Kyu-Yeol;Son Seon-Cheon;Lee Jong-Hon;Na Young-Sang
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.4 s.181
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    • pp.153-161
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    • 2006
  • Micro-forming is a suited technology to manufacture very small metallic parts(several $mm{\sim}{\mu}m$). Micro-forming of $Zr_{62}Cu_{17}Ni_{13}Al_8$ bulk metallic glass(BMG) as a candidate material for this developing process are feasible at a relatively low stress in the supercooled liquid state without any crystallization during hot deformation. In this study, micro- formability of a representative bulk metallic glass, $Zr_{62}Cu_{17}Ni_{13}Al_8$. was investigated for micro-forging of U-shape pattern. Micro-formability was estimated by comparing $R_f$ values ($=A_f/A_g$), where $A_g$ is cross-sectional area of U groove, and $A_f$ the filled area by material. Micro-forging process was simulated and analyzed by applying finite element method. FEM simulation results showed reasonable agreement with the experimental results when the material properties and simulation conditions such as top die speed, remeshing criteria and boundary conditions were tightly controlled. The micro-formability of $Zr_{62}Cu_{17}Ni_{13}Al_8$ was increased with increasing load and time in the temperature range of the supercooled liquid state. Also, FEM simulation using a commercial software, DEFORM was confirmed to be applicable for the optimization of micro-forming process.

A study on the micro-formability of $Zr_{62}Cu_{17}Ni_{13}Al_8$ bulk metallic glass using micro-forging and finite element method application (Zr 계 벌크비정질합금의 마이크로 단조를 이용한 미세 성형성 평가와 유한요소해석 적용에 관한 연구)

  • Kang S.G.;Na Y.S.;Park K.Y.;Son S.C.;Lee J.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.589-592
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    • 2005
  • Micro-forming is a suited technology to manufacture very small metallic parts(several $mm{\sim}{\mu}m$). Micro-forming of $Zr_{62}Cu_{17}Ni_{13}Al_8$ bulk metallic glass(BMG) as a candidate material for this developing process are feasible at a relatively low stress in the supercooled liquid state without any crystallization during hot deformation. In this study, micro-formability of a representative bulk metallic glass, $Zr_{62}Cu_{17}Ni_{13}Al_8$, was investigated for micro-forging of U-shape pattern. Micro-formability was estimated by comparing $R_f$ values $(=A_f/A_g)$, where Ag is cross-sectional area of U groove, and $A_f$ the filled area by material. Microforging process was simulated and analyzed by applying finite element method. FEM simulation results should reasonable agreement with the experimental results when the material properties and simulation conditions such as top die speed, remeshing criteria and boundary conditions tightly controlled. The micro-formability of $Zr_{62}Cu_{17}Ni_{13}Al_8$ was increased with increasing load and time in the temperature range of the supercooled liquid state. Also, FEM Simulation using DEFORM was confirmed to be applicable for the micro-forming process simulation.

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Analysis on Activation Energy Measurement and Application of Nuclear Equipment Non-metallic Materials (원전기기 비금속재료의 활성화에너지 측정 및 적용성 분석)

  • Bhang, Keug-Jin;Hong, Jun-Hee
    • Journal of Power System Engineering
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    • v.20 no.4
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    • pp.38-43
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    • 2016
  • Safety-related equipments of Nuclear Power Plants(NPP) have to perform environmental qualification test in accordance with IEEE-323 standards. However, non-metallic materials replace new one regularly instead of the test because they are considered as consumable parts. In this study, the seven kinds of non-metallic materials are selected and their activation energy was experimentally evaluated with uncertainty analysis by using thermogravimetric analyzer(TGA). In order to obtain activation energy of non-metallic materials, mass difference, temperature raising rate and conversion rate on the specimen are analyzed. It is postulated that the three experiment conditions are important to get a reliable activation energy. This postulate was experimentally confirmed using Arrhenius equation and Flynn-Wall-Ozawa analysis.

Friction Characteristics of automotive friction materials containing different metallic fibers against Al-MMC and cast iron disk specimens (자동차용 마찰재에 사용되는 금속섬유의 종류에 따른 마찰특성의 변화에 관한 연구)

  • Lee, Jin-Soo;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.255-264
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    • 1999
  • Friction characteristics of automotive friction materials containing different metallic fibers rubbing against Al-MMC and cast iron disk specimens have been studied. Friction materials containing aluminum, copper or low steel carbon fiber were tested. Friction tests were composed of three different phases to investigate the effect of temperature, pressure, speed, and drag time. The results showed that the friction material containing Al fibers has lower friction force and wear amount than the others with Cu or Steel fiber. On the other hand, the wear of friction material was severe in the case of using Al-MMC rotors. These results showed that the thermal decomposition of solid lubricants (and organic components), formation of transfer layer, and SiC particles in the AI-MMC rotor play crucial roles in determining the friction characteristics.

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Design and Characteristics of AE Sensor for Detection of Metallic particle in GIS (GIS 내의 금속이물 탐지용 AE 센서의 설계와 특성)

  • 홍재일;정영호;류주현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.502-508
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    • 2000
  • In order to detect the partial discharge with the metallic particle in GIS the AE(Acoustic Emission) sensor was designed and simulated by ANSYS 5.5 and manufactured as the coupled vibration mode. The measured resonant frequency and the maximum sensitivity frequency of three coupled AE sensors were as follows ; 147.88 kHz in 8.1mm $\Phi$$\times$8.1mm 128.82 kHz and 58.8 kHz in 9.5 mm$\Phi$$\times$9.5mm, 85.22 kHz and 32.6 kHz in 14.3 mm$\Phi$$\times$14.3 mm, resonant frequency of the AE sensor. The AE sensor of 9.5 mm$\Phi$$\times$9.5mm responded higher than the other coupled vibration mode AE sensor at the partial discharge detection in GIS.

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Improvement of the Corrosion Fatigue Life of Metal Material by Shot Peening (쇼트피닝가공에 의한 금속재료의 부식피로수명 개선)

  • Nam Ji-Hun;Kou Dae-Lim;Lee Kook-Jin;Lee Dong-Sun;Cheong Seong-Kyun
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.716-721
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    • 2004
  • Corrosion highly affects to reduce lifetime and performance of machinery metallic components. The effects of shot peening on the fatigue life of metal material under corrosive environment are investigated in this paper. Experimental results show that the fatigue limit of shot peened specimen increases about 52$\%$. That means the fatigue life of metallic components is highly extended by shot peening. The corrosion greatly reduces the fatigue strength depending on the corrosive condition from one week up to one year. In case of shot peened specimen, the corrosion does not reduce the fatigue strength and fatigue life up to six months. It means that shot peening has superior effectiveness to reduce the influence of corrosion to the metallic materials.

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Characteristics of AE Sensor for Detection of Metallic particle in GIS (가스절연개체장치의 금속이물 탐지용 AE 센서의 특성)

  • 홍재일;민석규;정영호;류주현
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.286-289
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    • 1999
  • In order to detect the partial discharge with the metallic particle in GIS, AE sensor was designed and simulated by ANSYS, and manufactured as the coupled vibration mode. The resonant frequency of three Coupled AE sensors were as follows ; 147.88 kHz in 8.1 mm$\Phi$ $\times$ 8.1mm, 128.82 kHz in 9.5 mm$\Phi$ $\times$ 9.5mm, 85.22 kHz in 14.3mm$\Phi$ $\times$14.3mm. That frequency is λ/2 resonant frequency. AE sensor of 9.5mm$\Phi$ $\times$9.5mm responded higher than the other coupled vibration mode AE sensor at the partial discharge detection in GIS.

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The Application of Metallic Thin Film for Tep Electrode of Poly-Si Solar Cell (다결정 실리콘 태양전지의 상부 전극용 금속 박막 적용)

  • 김상수;임동건;심경석;이준신;김흥우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.202-205
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    • 1997
  • We investigated grain boundary effect for terrestrial applications of solar cell\ulcorner with low cost, large area, and high efficiency. Grain boundaries are known as potential barriers and recombination centers for the photo-generated charge carriers, which make it difficult to achieve a high efficiency cell. To reduce these effects of grain boundaries, we investigated various influencing factors such as thermal treatments, various grid patterns, selective wet etchings for grain boundaries, buried contact metallizations along grain boundaries, and use of metallic thin films. From the various grid patterns we learned that the series resistance of solar cell reduced open circuit voltage and consequently decreased the cell efficiency. This paper describes the effect of various grid patterns and the employment of metallic thin films for a top electrode.

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