DOI QR코드

DOI QR Code

Analysis on Activation Energy Measurement and Application of Nuclear Equipment Non-metallic Materials

원전기기 비금속재료의 활성화에너지 측정 및 적용성 분석

  • Bhang, Keug-Jin (Safety Qualification Center, KHNP Central Research Institute) ;
  • Hong, Jun-Hee (Mechanical Engineering Department, Chungnam National University)
  • 방극진 (한수원(주) 중앙연구원 안전검증센터) ;
  • 홍준희 (충남대학교 기계공학과)
  • Received : 2016.05.04
  • Accepted : 2016.08.19
  • Published : 2016.08.31

Abstract

Safety-related equipments of Nuclear Power Plants(NPP) have to perform environmental qualification test in accordance with IEEE-323 standards. However, non-metallic materials replace new one regularly instead of the test because they are considered as consumable parts. In this study, the seven kinds of non-metallic materials are selected and their activation energy was experimentally evaluated with uncertainty analysis by using thermogravimetric analyzer(TGA). In order to obtain activation energy of non-metallic materials, mass difference, temperature raising rate and conversion rate on the specimen are analyzed. It is postulated that the three experiment conditions are important to get a reliable activation energy. This postulate was experimentally confirmed using Arrhenius equation and Flynn-Wall-Ozawa analysis.

Keywords

References

  1. IEEE Std. 323, 2003, Standard for Qualification Class 1E Equipment for Nuclear Power Generating Stations.
  2. S. Schuller, P. Schilinsky, J. Hauch, C. J. Brabec, 2004, "Determination of the degradation constant of bulk heterojunction solar cells by accelerated lifetime measurements," Appl. Phys. A 79, pp. 37-40. https://doi.org/10.1007/s00339-003-2499-4
  3. M. Celina, K.T. Gillen and R.A. Assink, 2005, "Accelerated aging and lifetime prediction: review of non-Arrhenius behaviour due to two competing processes," Polym. Degrad. Stab. Vol. 90, pp. 395-404. https://doi.org/10.1016/j.polymdegradstab.2005.05.004
  4. H. E. Kissinger, Anal and Chem., 29, 1702, 1957 https://doi.org/10.1021/ac60131a045
  5. S. Vyazovkin, Handbook of Thermal Analysis and Calorimetery, M. E. Brown and P. K. Gallagher, Elsevier, Vol 5, p 503, 2008.
  6. Elena V. Bystritskaya, Tatyana V. Monakhova, Victor B. Ivanov, 2013, "TGA application for optimising the accelerated aging conditions and predictions of thermal aging of rubber, Polymer Testing," Vol. 32, pp. 197-201. https://doi.org/10.1016/j.polymertesting.2012.10.013