• Title/Summary/Keyword: Metallic Environment

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The Influence of the Asian Dust on the Metallic Composition of Fine and Coarse Particle Fractions (황사와 비황사기간의 중금속 농도분포 특성: 2001년 황사기간에 대한 비교연구)

  • 최규훈;김기현;강창희;이진홍
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.1
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    • pp.45-56
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    • 2003
  • In this study the distribution patterns of the metallic components were analyzed both before and after the Asian Dust (AD) events at 2001 by comparing the chemical composition of metallic components in terms of various statistical methods. According to the AD/NAD concentration ratio of metallic components, the main components of crustal soils were exhibiting the values above 1.0; but opposite results were seen dominantly for hazardous metallic components. Examination of fine-to-coarse (F/C) ratios of metallic components showed higher values for major anthropogenic components including Pb (5.83). Ni (2.61), etc. Comparison of our measurement data with those obtained within and across the Korean peninsula indicated that the metallic distribution patterns of the study area can be distinguished from previous studies. The results of our analysis, when investigated in relation with air mass movement patterns. indicated evidence of the direct influence of AD events and anthropogenic processes.

Distribution of Organic Matters and Metallic Elements in the Surface Sediments of Masan Harbor, Korea (마산항 표층 퇴적물의 유기물 및 금속원소의 분포)

  • Hwang Dong-Woon;Jin Hyun-Gook;Kim Seong-Soo;Kim Jung-Dae;Park Jong-Soo;Kim Seong-Gil
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.2
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    • pp.106-117
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    • 2006
  • We measured the concentrations of organic matter and metallic elements (Al, Fe, Cr, Mn, Ni, Cu, Zn, As, Cd, Pb and Hg) in the surface sediments of Masan Harbor (in the southern sea, Korea) to evaluate the geochemical characters of sediment and the pollutions by organic matter and metallic elements. The mean grain size of the surface sediments in the study area ranged from $5.6{\phi}$ to $7.8{\phi}$, indicating silt sediment. The water content of the surface sediments exceeded 60% except at some stations. The contents of ignition loss (IL), total organic carbon (TOC) and total nitrogen (TN) ranged from 7.2-14.3%, 1.2-3.2%, and 0.10-0.28%, respectively. Based on the C/N ratios, the organic matter in the surface sediments of Masan Harbor may originate from terrigenous sources including fluvial inputs (mainly sewage in urban areas). The chemical oxygen demand (COD) and acid volatile sulfide (AVS) ranged from $11.3-29.9\;mgO_2/g\;dry$ and 0.20-4.47 mgS/g dry, respectively, and low concentrations were observed near a shipping route. In addition, the concentrations of metallic elements showed large spatial variations in Masan Harbor and the distributions of metallic elements were also comparable to those of organic matter. This implies that the distributions of organic matter and metallic elements in the surface sediments of Masan Harbor are mainly controlled by biogenic matter and artificial action (mainly dredging). In addition, we calculated the enrichment facto. (EF) and geoaccumulation index (Igeo) in order to evaluate pollution by metallic elements. The enrichment of metallic elements relative to Al was three to eighteen times higher at the study sites, compared to levels in the Earth's crust except for Fe, Ni and Mn. In addition, the Igeo class indicated that the surface sediments in the study area were moderately to strongly polluted in terms of metallic elements.

Effect of Nanomaterials on the Early Development of Fish Embryos: (2) Metallic Nanomaterials (어류수정란 발달에 미치는 나노독성 연구동향: (2) 금속계 나노물질)

  • Shin, Yu-Jin;An, Youn-Joo
    • Journal of Korean Society on Water Environment
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    • v.28 no.6
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    • pp.943-953
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    • 2012
  • Because of their unique properties, nano-sized metallic nanomaterials (NMs) have been used in extensive applications of biomedicine, electronics, optics, engineering, and personal care products. Accordingly, with the increasing release of NMs into the environment, numerous studies of nanoecotoxicity have been conducted. Fish embryo toxicity test (FET) has many benefits in evaluating toxicity of NMs as an alternative to a whole-body test in fish. In this study, we collected and analyzed the toxicity studies of metallic NMs on freshwater fish embryos. Most studies have demonstrated that metallic NMs are highly toxic during the early development of fish embryos. However, it should be noted that the results for the same NMs on the same test species show variation due to differences in the size or surface properties of the test NMs and exposure conditions. For the safe use of metallic NMs, we need to analyze their effects based on their properties, test species, environmental media, and diverse conditions.

A Study on the Characteristics of $PM_{10}$ and Air-borne Metallic Elements Produced in the Industrial City (산업도시 대기 중$PM_{10}$의 농도 및 금속원소 성분의 특성 연구)

  • 나덕재;이병규
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.1
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    • pp.23-35
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    • 2000
  • PM10, which is below 10 ${\mu}{\textrm}{m}$ in a diameter, has a high deposition in the lung or the bronchus by breathing and is generally composed of a lot of organic matters, viruses, algae, mold, and metallic elements that are very toxic to people. This study identified the characteristics of concentration of PM10 and air-borne jmetallic elements produced in the industrial city, Ulsan, and analyzed the correlatuion between sources and generation patterns of PM10 and metallic elements. We classified the five areas(green, residential, heavy traffic, mechanic, and petrochemcal and non-ferrous metal) which might have different characteristics of sources of PM10 and metallic elements. The average concentrations of PM10 in the five areas were as follows(petrochemical and non-ferrous metal(99.9$\mu\textrm{g}$/㎥)>mechanic(77.5 $\mu\textrm{g}$/㎥)>heavy traffic(47.1 $\mu\textrm{g}$/㎥)>residential(39.3 $\mu\textrm{g}$/㎥)>green(32.8 $\mu\textrm{g}$/㎥)). Those of petrochemical and non-ferrous metal areas were higher than other areas. In this study, the average concentration trend of metallic elements contained in PM10 are shown as follows: Fe>Zn>Pb>Cu>Mn>Cr>As>Cd>Sn>Hg, respectively. The metallic elements identified in PM10 showed the highest concentration in the petrochemical and non-ferrous areas. Metal combinations showed that a high correlation among concentrations of heavy metals were as follows: As, Cd and Fe in the residential area; Zn, Mn, Cu and Pb in the mechanical area; and Zn, Cu, As, Pb in the petrochemical and non-ferrous industrial area.

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Analysis on Activation Energy Measurement and Application of Nuclear Equipment Non-metallic Materials (원전기기 비금속재료의 활성화에너지 측정 및 적용성 분석)

  • Bhang, Keug-Jin;Hong, Jun-Hee
    • Journal of Power System Engineering
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    • v.20 no.4
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    • pp.38-43
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    • 2016
  • Safety-related equipments of Nuclear Power Plants(NPP) have to perform environmental qualification test in accordance with IEEE-323 standards. However, non-metallic materials replace new one regularly instead of the test because they are considered as consumable parts. In this study, the seven kinds of non-metallic materials are selected and their activation energy was experimentally evaluated with uncertainty analysis by using thermogravimetric analyzer(TGA). In order to obtain activation energy of non-metallic materials, mass difference, temperature raising rate and conversion rate on the specimen are analyzed. It is postulated that the three experiment conditions are important to get a reliable activation energy. This postulate was experimentally confirmed using Arrhenius equation and Flynn-Wall-Ozawa analysis.

A Folded Label Tag for Metallic Environment over UHF Band (금속환경에 적용가능한 UHF대역 라벨 태그의 구현 및 성능평가)

  • Eum, Tae-Hwan;Moon, Byung Hyun
    • Journal of Korea Society of Industrial Information Systems
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    • v.20 no.2
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    • pp.19-24
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    • 2015
  • In this paper, a folded label type RFID tag antenna is designed and produecd for metellic environment over UHF band. Since performance of regular label type RFID tag is seriously degraded for the metallic environment, a folded label tag is proposed to improve the performance. The proposed tag is operating at 910MHz by using inductive T Matching Feed and simulated in HFSS by Ansoft. The actual size is $65{\times}23{\times}3(mm)$ with the impedance of $52-j158{\Omega}$. The maximum distance of identification for the proposed tag is measured as 5.5 meters.

동위원소를 이용한 폐금속광산 지역 오염원 추적 연구

  • Yeom Seung-Jun;Lee Pyeong-Gu;Lee In-Gyeong;Lee Uk-Jong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.209-212
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    • 2006
  • Using sulfur sotope analysis of dissolved sulfate in surface water, we have investigated the source of sulfate in order to identify the abandoned metallic mines, which have the potential of heavy metal contamination within watershed. The range of the sulfur isotope values for dissolved sulfate in stream waters (DD-1 and 2) are similar to those of sulfides from the Dunjun mine, which suggests that oxidation of sulfides is the principal source of $SO_4^{2-}$ in these stream waters. Also, heavier sulfur isotopes in waters near Baekjun and Hamchang mines imply the possibility of contamination in waters by these metallic mines.

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Development of Metallic Bipolar Plate Material with W-addition in Austenitic Stainless Steel for PEMFC Environment

  • Kim, Kwang Min;Koh, Sung Ung;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.5 no.5
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    • pp.153-159
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    • 2006
  • Austenitic stainless steels with addition of various amounts of Mo and W were evaluated in terms of corrosion and contact resistance to determine optimum alloy composition of metallic bipolar plate for PEMFC. The corrosion property was evaluated by both acid fume exposure test at $130^{\circ}C$ and by electrochemical polarization tests in $H_3PO_4$ solution at $80^{\circ}C$. Austenitic stainless steel with proper amount of Mo and W demonstrated not only good corrosion resistance but also low contact resistance. Analyses on the passive film show that partial substitution of Mo by W enhances passive film stability and repassivation property. Test results suggest that austenitic stainless steel with 2 wt%Mo and 4 wt%W has optimum composition for metallic bipolar plate used in PEMFC.

Influence of Metallic Sodium on Repair Weldability for Type 316FR Stainless Steel

  • Chun, Eun-Joon;Lee, Su-Jin;Suh, Jeong;Lee, Ju-Seung;Kang, Namhyun;Saida, Kazuyoshi
    • Journal of Welding and Joining
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    • v.35 no.1
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    • pp.79-88
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    • 2017
  • The effect of residual metallic sodium on the solidification cracking susceptibility of type 316FR stainless steel was investigated via transverse-Varestraint tests. And a solidification brittle temperature range (BTR) of type 316FR stainless steel was 37 K. However, the BTR expanded from 37 to 67 K, as the amount of metallic sodium at the specimen surface increased from 0 to $7.99mg/cm^2$. Microstructural observation of the weld metal suggested that metallic sodium existed in the weld metal, including in the cell boundaries, during welding solidification. Thermodynamic calculations suggested that sodium expanded the temperature range of solidliquid coexistence during welding solidification of the steel weld metal. Therefore, the increased solidification cracking susceptibility (i.e., expansion of the BTR) in the residual sodium environment was attributed to enhanced segregation of sodium during the welding solidification; this segregation, in turn, resulted in an expanded temperature range of solid-liquid coexistence.