• 대한치과교정학회지
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• 제44권3호
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• pp.105-112
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• 2014

Objective: The purpose of this study was to evaluate the effects of three different surface conditioning methods on the shear bond strength (SBS) of metal brackets bonded directly to gold alloy with chemically cured resin. Methods: Two hundred ten type III gold alloy specimens were randomly divided into six groups according to the combination of three different surface conditioning methods (aluminum oxide sandblasting only, application of a metal primer after aluminum oxide sandblasting, silica coating and silanation) and thermocycling (with thermocycling, without thermocycling). After performing surface conditioning of specimens in accordance with each experimental condition, metal brackets were bonded to all specimens using a chemically cured resin. The SBS was measured at the moment of bracket debonding, and the resin remnants on the specimen surface were evaluated using the adhesive remnant index. Results: Application of metal primer after aluminum oxide sandblasting yielded a higher bond strength than that with aluminum oxide sandblasting alone (p < 0.001), and silica coating and silanation yielded a higher bond strength than that with metal primer after aluminum oxide sandblasting (p < 0.001). There was no significant change in SBS after thermocycling in all groups. Conclusions: With silica coating and silanation, clinically satisfactory bond strength can be attained when metal brackets are directly bonded to gold alloys using a chemically cured resin.

• The Journal of Advanced Prosthodontics
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• 제7권5호
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• pp.392-399
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• 2015

PURPOSE. The aim of this study was to evaluate the effect of metal primers on the bonding of dental alloys and veneer resin. Polyvinylpyrrolidone solution's tarnish effect on bonding strength was also investigated. MATERIALS AND METHODS. Disk-shape metal specimens (diameter 8 mm, thickness 1.5 mm) were made from 3 kinds of alloy (Co-Cr, Ti and Au-Ag-Pd alloy) and divided into 4 groups per each alloy. Half specimens (n=12 per group) in tarnished group were immersed into polyvinylpyrrolidone solution for 24 hours. In Co-Cr and Ti-alloy, Alloy Primer (MDP + VBATDT) and MAC-Bond II (MAC-10) were applied, while Alloy Primer and V-Primer (VBATDT) were applied to Au-Ag-Pd alloys. After surface treatment, veneering composite resin were applied and shear bond strength test were conducted. RESULTS. Alloy Primer showed higher shear bond strength than MAC-Bond II in Co-Cr alloys and Au-Ag-Pd alloy (P<.05). However, in Ti alloy, there was no significant difference between Alloy Primer and MAC-Bond II. Tarnished Co-Cr and Au-Ag-Pd alloy surfaces presented significantly decreased shear bond strength. CONCLUSION. Combined use of MDP and VBATDT were effective in bonding of the resin to Co-Cr and Au-Ag-Pd alloy. Tarnish using polyvinylpyrrolidone solution negatively affected on the bonding of veneer resin to Co-Cr and Au-Ag-Pd alloys.

• 대한치과보철학회지
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• 제40권4호
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• pp.344-351
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• 2002

The purpose of this study is to compare tensile bond strength between Cr-Co alloy and three denture base resins after surface treatment. Following the manufacturer's instructions, 180 bonded specimens were made from three denture base resins (Lucitone 199. Paladent 20. POSS resin) and three surface treatment methods (sandblasting. metal primer. silicoating) 20 samples were made in each group and a half was ther-mocycled 1000 times between $5^{\circ}C$ and $55^{\circ}C$. The tensile bond strength was measured using an Instron with 5mm/min crosshead speed. Data was analyzed with one-way ANOVA, T-test and Duncan test. The results were as follows : 1. Samples with metal primer coating had significantly high tensile bond strength than the other surface treated groups (p<.05). Significantly low tensile bond strength was shown in sand blasted groups (p<.05). 2. No significant difference was observed in metal primer coating groups before and after ther-mocycling (p>.05) 3. Tensile bond strength was decreased in silicoated samples after thermocycling (p<.05). 4. Of the surface treated groups with metal primer, Lucitone 199 had the greatest bond strength and POSS resin and Paladent 20 were followed (p<.05). 5. Of the surface treated groups with silicoating, POSS resin and Lucitone 199 had greater bond strength than Paladent 20 (p<.05).

• 대한치과보철학회지
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• 제40권4호
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• pp.396-405
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• 2002

The purpose of this study was to evaluate the effects of four metal surface treatments on the shear bond strength of reline resin to Ni-Cr alloy. The denture base metal used in this study was Ni-Cr alloy(Ticonium Premium 100. Ticonium Co., U.S.A.). 120 specimens were divided into five metal surface treatments: sandblasting only, MR. BOND(Tokuyama Corp.. Japan), Cesead Opaque Primer(Kuraray Co., Japan), METALPRIMER II(GC Corp., Japan) and Super-Bond C&B(Sun Medical Co., Japan) after sandblasting. They were bonded with one of three reline resins Mild Rebaron(GC Corp., Japan), Mild Rebaron LC(GC Corp., Japan) and Meta Base M(Sun Medical Co., Japan). Then they were thermocycled 1,000 times at temperature of $4^{\circ}C$ and $60^{\circ}C$. The shear bond strengths were measured using the universal testing machine(Instron, Model 4301, England) with a cross-head speed of 2 mm/min. The results were as follows : 1. All metal primers and adhesive cement significantly improved the bond strength of reline resin to Ni-Cr alloy compared with sandblasted specimens. 2. In Mild Rebaron and Mild Rebaron LC. Cesead Opaque Primer showed the highest bond strength, but the differences among Cesead Opaque Primer, MR. BOND and METALPRIMER II were not significant. The bond strength of Cesead Opaque Primer was significantly different with that of Super-Bond C&B. 3. In Meta Base M, Super-Bond C&B showed the highest bond strength, but there was no difference between Super-Bond C&B and three metal primers. 4. There was no difference in the bond strength between Mild Rebaron and Mild Rebaron LC when metal surface was treated with the same method. 5. The bond strengths of Mild Rebaron and Mild Rebaron LC treated with Cesead Opaque Primer were higher than that of Meta Base M. The bond strengths of Mild Rebaron treated with MR. BOND and METALPRIMER II was higher than that of Meta Base M, However, there was no difference among three reline resins treated with Super-Bond C&B.

• 대한치과보철학회지
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• 제36권2호
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• pp.336-354
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• 1998

Traditionally, many kinds of mechanical bonding techniques were used for bonding resins to the surface of the metal alloys. If there is a seperation between resin and metal junction by stress accumulation and temperature change of oral cavity, the cracks or crazing may occur, accompanied by failure of resin bonding to metal. This study was designed to compare the shear bond strength of the type IV gold alloy and Cr-Co alloy surfaces treated with various methods and thermocycling. Universal Instron (Model 1000) and scanning electron microscope (JEOL, Japan) was used to record the shear bond strength of 5 groups. Forty specimens were made for each group ; group 1 was treated with sandblasting only, group 2 was coated with V-primer after sandblasting, group 3 was coated with Metal primer, group 4 wase coated with MR Bond and group 5 was coated with silane. After treated with various methods, thermocycling was done for half of the each group. The surfaces of failed pattern were observed with SEM. The results were as follows : 1. Shear bond strength of the group 1 was lower than that of another groups in type IV gold alloys and bond strength of the group 1, 2 were lower than that of group 3, 4, 5 in Cr-Co alloys. 2. Shear bond strength of the gold alloy with resin was higher than that of Cr-Co alloy when specimens were coated with V-primer. 3. Shear bond strength of the Co-Cr alloys with resin was higher than that of gold alloys when specimens were coated with Metal primer. 4. The bond strength of all specimens did not decreased significantly after thermocycling. 5. Adhesive failures were found in group 1 and Cr-Co alloy in group 2, but adhesive and cohesive failures were found in another groups.

• 대한치과보철학회지
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• 제35권4호
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• pp.697-705
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• 1997

The purpose of this study was to evaluate the effects of two metal adhesive primers on the shear bond strengths of self-curing resin to Ni-Cr a]toy and the effects of 1000 thermal cycling on the durability of the bond. The two selected metal adhesive primers were Metal Primer II(G-C corp., Japan) and MR Bond(Tokuyama corp., Japan) and no treatment groups were used as control. All specimens were divided into two groups according to thermal cycling. In the group without thermal cycling, the specimens were stored in water for 24 hours. In the group with thermal cycling, the specimens were thermocycled 1000 times at temperature of $5^{\circ}C\;and\;55^{\circ}C$. Shear bond strengths were measured using the Universal testing machine(Zwick 145641, Germany) with a crosshead speed of 0.5 mm/min. The results were as follows: 1. MR Bond significantly improved the shear bond strength of resin to Ni-Cr alloy before and after thermal cycling. 2. There were no difference in the shear bond strength of resin to Ni-Cr alloy between Metal Primer II treated group and no treatment group. 3. Regardless of the type and the use of adhesive primers, there were tendency of decrease in shear bond strength with 1000 thermal cycling.

• 대한치과보철학회지
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• 제57권2호
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• pp.95-101
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• 2019

목적: 레진 시멘트와 코발트 크롬 합금 간의 미세인장결합강도에 다양한 프라이머들이 미치는 영향을 평가하기 위한 것이다. 재료 및 방법: 본 실험에서는 4개의 프라이머(Universal primer, Metal primer II, Alloy primer, and Metal/Zirconia primer)와 2개의 레진 시멘트(Panavia F2.0, G-CEM LinkAce)를 사용하였고, 길이 6 mm, 폭 1 mm, 두께 1 mm의 150개의 코발트 크롬 빔들이 캐스팅 과정을 통해 제작되었다. 150개의 코발트 크롬 빔들을 프라이머와 레진 시멘트의 종류에 따라 프라이머 처리를 하지 않은 대조군을 포함하여 10개 그룹으로 나누었다. 금속과 레진시멘트를 산화알루미늄($125{\mu}m$ 크기)으로 샌드블라스팅 처리한 후 실리콘 틀을 이용하여 접착시켰다. 실험 전에, 입체현미경(stereomicroscope)을 이용하여 모든 금속-레진 빔들을 검사하였고, 미세인장결합강도 실험을 시행하였다. 통계적인 평가에는 one-way ANOVA와 Tukey's test를 사용하였다. 결과: 모든 그룹들의 평균 미세인장결합강도는 20 - 28 MPa이었으며, 그룹 간에 통계적으로 유의한 차이는 없었다. Panavia F2.0과 G-CEM LinkAce 그룹 모두에서 접착 파절과 응집 파절이 동시에 나타나는 혼합 파절이 가장 흔하게 일어난 파절 양태였다. 결론: 모든 실험군들의 미세인장결합강도는 상대적으로 높았지만, 본 실험에서는 프라이머의 사용이 Panavia F2.0 및 G-CEM LinkAce 레진시멘트와 코발트 크롬 합금 사이의 미세인장결합강도를 증가시키지 않았다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.316-321
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• 2003

The spatter and porosity could be occurred during $CO_2$ CW laser welding of Primer-coated Steel for Shipbuilding. This study has suggested an alternative idea by examining of weld-defect formation mechanism. The primer-coated plate has caused the spatter, humping bead and porosity and these are main part of the welding defect, attributed to the powerful vaporizing pressure of primer attached on the base metal. The zinc of primer has a boiling point that is the lower temperature than melting point of steel. Zinc va}X)f will build up at the interface between the two sheets and this tends to deteriorate the quality of the weld by ejecting weld material from lap position or leaving porosity. Therefore introducing a small gap clearance in the lap position, the zinc vapor could escape through it and sound weld beads can be acquired. In conclusion, we suggested the occurred and prevented mechanism of weld defects with searching the factor.

• 대한치과보철학회지
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• 제50권2호
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• pp.112-118
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• 2012

연구 목적: 이 연구의 목적은 실란과 인산 모노머를 혼합한 프라이머인 Monobond plus (Ivoclar Vivadent, Schaan, Liechtenstein)를 사용했을 때 레진 시멘트와 수복물 간의 전단 결합 강도가 귀금속, 비귀금속, 글라스 세라믹과 지르코니아 네 가지 재료 모두에서 기존의 프라이머를 사용했을 때의 결합 강도와 비교하여 유의한지 평가하는 것이다. 연구 재료 및 방법: 디스크 모양(${\phi}\;9mm{\times}3mm$)의 귀금속(Argedent Euro) 시편 16개, 비귀금속(T-4) 시편 20개, 지르코니아(Cercon) 시편 20개, 글라스 세라믹(IPS e.max press) 시편 20개를 제작한 후 아크릴릭 레진(${\phi}\;15mm{\times}15mm$)에 포매하였다. 귀금속 시편에 airborne-particle abrasion을 시행하고 대조군으로 사용한 8개 시편에는 귀금속용 프라이머(Metal primer II)를, 나머지 8개 시편에는 Monobond plus를 도포하였다. 비귀금속 시편과 지르코니아 시편은 airborne-particle abrasion 후 각각 두 그룹으로 나누어 대조군 10개 시편에는 비귀금속 및 지르코니아용 프라이머(Alloy primer)를, 나머지 10개에는 Monobond plus를 도포하였다. 글라스 세라믹 시편은 4% 불산으로 부식한 후, 대조군 10개 시편에는 실란(Monobond-S)을, 나머지 10개에는 Monobond plus를 적용했다. 표면 처리된 시편 위에 디스크 형태(${\phi}\;5mm{\times}2mm$)로 레진 시멘트(Multilink N)를 위치시키고 중합하였다. 제작된 모든 시편을 열순환($5^{\circ}C$와 $55^{\circ}C$, 1분씩 2060회)시킨 후 전단 결합 강도를 측정하였다. 전단 결합 강도의 유의차를 살펴보기 위해 Shapiro-Wilk test를 이용하여 모집단의 분포에 대한 검정을 하고 그 결과에 따라 Two sample $t$-test 또는 Mann-Whitney U test를 실시하였다(${\alpha}$=.05). 파절된 시편을 확대경으로 관찰하여 그 양상을 분류하였다. 결과: 귀금속과 글라스 세라믹 군에서는 두 프라이머간의 전단 결합 강도에 유의한 차이가 존재하지 않았으나($P$>.05) 비귀금속 군과 지르코니아 군에서는 기존 프라이머(Alloy primer)를 사용했을 때 레진 시멘트와 수복물간의 전단 결합 강도가 Monobond plus를 사용한 군보다 통계적으로 유의하게 높았다(비귀금속 군$P$=.004, 지르코니아 군$P$=.001). 결론: 실란과 인산 모노머를 혼합한 다용도 프라이머는 귀금속과 글라스 세라믹 군에서는 기존의 프라이머를 대신하여 사용할 수 있을 것이다. 그러나 비귀금속과 지르코니아 세라믹에서는 10-MDP 프라이머에 비해 접착 강도가 낮아 기존 프라이머를 대신하여 적용하기 위해서는 좀 더 연구가 필요할 것이다.

• Journal of Advanced Marine Engineering and Technology
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• 제28권1호
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• pp.109-115
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• 2004

The spatter and porosity could be occurred during$CO_2$CW laser welding of Primer- coated steel for shipbuilding. This study has suggested an alternative idea by examining of weld-defect formation mechanism. The primer-coated plate induced the spatter humping bead and porosity and these are main part of the welding defect. attributed to the powerful vaporizing pressure of primer attached on the base metal The zinc of Primer has a boiling point that is the lower temperature than melting point of steel zinc vapor will build up at the interface between the two sheets and this tends to deteriorate the quality of the weld by ejecting weld material from lap position or leaving porosity. Therefore introducing a small gap clearance in the lap position. the zinc vapor could escape through it and sound weld beads can be acquired. In conclusion, we suggested the occurred and prevented mechanism of weld defects with searching the factor.