• Title/Summary/Keyword: Metal foil

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Gas sensing properties of CuO nanowalls synthesized via oxidation of Cu foil in aqueous NH4OH (NH4OH 수용액 하에서 Cu 호일의 산화를 통해 합성한 CuO 나노벽의 가스센싱 특성)

  • ;;;Lee, Si-Hong;Lee, Sang-Uk;Lee, Jun-Hyeong;Kim, Jeong-Ju;Heo, Yeong-U
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.141-141
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    • 2018
  • Copper is one of the most abundant metals on earth. Its oxide (CuO) is an intrinsically p-type metal-oxide semiconductor with a bandgap ($E_g$) of 1.2-2.0 eV 1. Copper oxide nanomaterials are considered as promising materials for a wide range of applications e.g., lithium ion batteries, dye-sensitized solar cells, photocatalytic hydrogen production, photodetectors, and biogas sensors 2-7. Recently, high-density and uniform CuO nanostructures have been grown on Cu foils in alkaline solutions 3. In 2011, T. Soejima et al. proposed a facile process for the oxidation synthesis of CuO nanobelt arrays using $NH_3-H_2O_2$ aqueous solution 8. In 2017, G. Kaur et al. synthesized CuO nanostructures by treating Cu foils in $NH_4OH$ at room temperature for different treatment times 9. The surface treatment of Cu in alkaline aqueous solutions is a potential method for the mass fabrication of CuO nanostructures with high uniformity and density. It is interesting to compare the gas sensing properties among CuO nanomaterials synthesized by this approach and by others. Nevertheless, none of above studies investigated the gas sensing properties of as-synthesized CuO nanomaterials. In this study, CuO nanowalls versus nanoparticles were synthesized via the oxidation process of Cu foil in NH4OH solution at $50-70^{\circ}C$. The gas sensing properties of the as-prepared CuO nanoplates were examined with $C_2H_5OH$, $CH_3COCH_3$, and $NH_3$ at $200-360^{\circ}C$.

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Modeling the Heterogeneous Microstructures of Ti-MMCs in Consolidation Process (강화공정에 따른 비균질 티타늄 금속기 복합재료 모델링)

  • Lee Soo-Yeun;Kim Tae-Won
    • Composites Research
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    • v.18 no.3
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    • pp.21-30
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    • 2005
  • Vacuum hot pressing has been used for the development of titanium metal matrix composites using foil-fiber-foil method. Heterogeneous microstructures prior to and following consolidation have been quantified, and the relations to densification behavior investigated. As shown by the results, dramatic variations of the microstructures including equiaxed $\alpha$, transformed $\beta$ and $ Widmanst\ddot{a}tten$ $\alpha$ are obtained during the process according to the fiber distributions. The dependence of microstructures on the consolidation then has been explained in terms of the change in mechanisms such as grain growth and recrystallization that occur with changing levels of inhomogeneity of deformation. Further, micro-mechanics based constitutive model enabling the evolution of density over time together with the evolutions of microstructure to be predicted has been developed. The mode developed is then implemented into finite element scheme so that practical process simulation has been carried out.

Wet Etching of Stainless Steel Foil by Aqueous Ferric Chloride Solution (염화제이철 수용액에 의한 스테인레스 강판의 식각에 관한 연구)

  • Lee, Hyung Min;Park, Mooryong;Park, Gwang Ho;Park, Chinho
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.211-216
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    • 2012
  • Wet chemical etching of stainless steel foil by aqueous ferric chloride solution was investigated in this study. Effects of various process parameters (e.g. etchant agitation rate, etchant temperature, $Fe^{3+}$ ion concentration, free HCl concentration, specific gravity, etc.) on the etch rate was first studied, and it was found that the etch rate of AK (aluminum-killed) steel, chromium metal and stainless steel (STS430J1L alloy) follows the pseudo-first order reaction equation. When the fatigue ratio of etchant was kept under 16%, sludge was not formed in the solution, and the etched surface showed smooth roughness. The etch rate decreases as Baume of etchant increases, but the effect of free HCl concentration on the etch rate turned out to be minimal. Experimental data were compared with the calculated results from modeled equation, showing very good agreement.

Development of GDL-carbon Composite Bipolar Plate Assemblies for PEMFC (PEM 연료전지용 가스확산층-탄소 복합재료 분리판 조합체 개발)

  • Lim, Jun Woo
    • Composites Research
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    • v.34 no.6
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    • pp.406-411
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    • 2021
  • PEM (proton exchange membrane) fuel cells generate only water as a by-product, and thus are in the spotlight as an eco-friendly energy source. Among the various components composing the stack of the fuel cell, research on the bipolar plate that determines the efficiency of the fuel cell is being actively conducted. The composite bipolar plate has high strength, rigidity and corrosion resistance, but has the disadvantage of having a relatively low electrical conductivity. In this study, to overcome these shortcomings, a gas diffusion layer (GDL)-composite bipolar plate assembly was developed and its performance was experimentally verified. The graphite foil coating method developed in the previous study was applied to reduce the contact resistance between the bipolar plate and the GDL. In addition, in order to improve electron path in the stack and minimize the contact resistance between the GDL and the bipolar plate, a GDL-bipolar plate assembly was fabricated using a thin metal foil. As a result of the experiment, it was confirmed that the developed GDL-bipolar plate assembly had 98% lower electrical resistance compared to the conventional composite bipolar plate.

Development of Meander-shaped Metallic Magnetic Calorimeters

  • Yoon, W.S.;Jang, Y.S.;Kim, G.B.;Lee, H.J.;Lee, J.Y.;Lee, M.K.;Kim, Y.H.
    • Progress in Superconductivity
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    • v.14 no.2
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    • pp.102-105
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    • 2012
  • We are developing meander-shaped metallic magnetic calorimeters using micro-fabrication methods. A planar Nb coil in a meander shape was fabricated on a Si substrate. The coil was designed to have a persistent current using a metal heater evaporated on a part of the coil. A paramagnetic sensor, $5{\mu}m$ thick Au:Er foil, was glued on top of the meander structure with epoxy. The magnetization and heat capacity were measured at different temperatures, and applied field currents matched well with expected values. The detector showed an energy resolution of 4 keV FWHM for the 5.5 MeV alpha particles.

Entangled-Mesh Graphene for Highly Stretchable Electronics

  • Han, Jae-Hyeon;Yeo, Jong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.351.1-351.1
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    • 2016
  • While conventional electronic devices have been fabricated on the rigid and brittle Si based wafer as a semiconducting substrate, future devices are increasingly finding applications where flexibility and stretchability are further integrated to enable emerging and wearable devices. To achieve high flexibility and stretchability, various approaches are investigated such as polymer based conducting composite, thin metal films on the polymer substrate, and structural modifications for stretchable electronics. In spite of many efforts, it is still a challenge to identify a solution that offers both high stretchability and superior electrical properties. In this paper, we introduce a highly stretchable entangled-mesh graphene showing a potential to address such requirements as stretchability and good electrical performance. Entangle-mesh graphene was synthesized by CVD graphene on the Cu foil. To analyze the mechanical properties of entangled-mesh graphene, endurance and stretching tester have been used.

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Characteristics of Greenish Pigments from Silkwarm Excrement by Ethanol Extraction (누에 배설물에서 Ethanol 추출한 녹색색소의 일반적 성질)

  • 김용환
    • The Korean Journal of Food And Nutrition
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    • v.11 no.4
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    • pp.375-380
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    • 1998
  • A study of characteristics of greenish pigments from silkwarm excrement by ethanol extraction. Through visible absorption scanning, it showed two absorption peaks at 415 and 657nm, and it was shown to be greenish color. In the presence of light, the stability of pigments rapidly degraded, but in the presence of Al-foil, green and blue cover were very stable. It was shown to be stabilized at the temperature of 7$0^{\circ}C$ until 20days and presence of metal ions, such as Na+, K+, Ca2+, Mg2+ and Zn2+. The pigments was shown to be stabilized in 5% acetic acid solution, but in the presence of lactic acid, citric acid and tartaric acid solution were unstable. On the result of TLC analysis, pigments were shown to be composed of eight color fractions, and main color fractions were F-1, F-2 and F-3. In F-1, F-2 fractions were revealed green color and F-3 fraction were revealed yellow color.

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Development of On-line Wrinkle Measurement System Using Machine Vision (머신 비젼을 이용한 실시간 링클 측정 시스템 개발)

  • Shin, Dong-Keun;To, Hoang-Minh;Ko, Sung-Lim
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.3
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    • pp.274-279
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    • 2008
  • Roll to roll (R2R) manufacturing process, also known as 'web processing', has been tried for producing electronic devices on a flexible plastic or metal foil. To increase the performance and productivity the R2R process, effective control and on-line supervision for web quality becomes very important. Wrinkle is one of the defects, which is incurred due to compressive stresses. A system for on-line measurement of wrinkle is developed using area scan camera and machine vision laser. The 2D image, obtained by area scan camera, is produced by Gaussian regression method to characterize the wrinkle on a transparent web. The experiment proves that 0.3mm wrinkle height can be measured successfully with 74fps.

Study on Thermal expansion properties of metal foils substrate for flexible solar cells (플렉서블 태양전지 기판재용 금속포일의 열팽창 특성 연구)

  • Yim, Tai-Hong;Lee, Heung-Yeol;Koo, Seung-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.265-268
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    • 2007
  • 플렉서블 태양전지용 연성기판재에는 플라스틱재와 금속재가 있다. 기존의 연성기판인 플라스틱의 경우 열과, 내구성, 화학약품에 약하다는 단점이 있으며, 금속기판은 높은 생산원가, 박판화의 어려움 등의 문제를 안고 있다. 상업적으로 응용되거나 연구에 활용되는 플렉서블 기판재의 단점을 보완할 수 있는 가능성을 밝혀보기 위해 전주성형법으로 합금 금속 포일을 제조하여 상용 금속 기판재의 열팽창 거동과 비교해 보았다. 본 연구에서는 플렉서블 태양전지용으로 적용되거나 연구되고 있는 금속 기판 재료인 두께 50 ${\mu}m$인 Ti, Mo, Al 포일을 선택하여 열팽창거동을 조사하였고 이를 전주성형법으로 제조한 두께 10 ${\mu}m$인 Fe-40Ni, Fe-45Ni, Fe-52Ni 합금포일의 열팽창 거동과 비교 분석하였다. 금속 및 합금 포일의 열팽창 거동은 TMA 장비를 사용하여 조사하였다.

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Fabrication of Electrospun Cobalt Nanofiber (전기 방사 기반의 코발트 나노 섬유의 제작)

  • Heo, Joonseong;Lim, Geunbae
    • Journal of Sensor Science and Technology
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    • v.24 no.1
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    • pp.35-40
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    • 2015
  • Electrospinning method has easy preparation of nanofibers with a simple and versatile technique. Electrospun nanofiber is widely used by the simple approach and have great potentials in the numerous applicaitons of medicine, photonics, catalysts, sensors, etc. including advantage of their specific characteristics such as large surface to volume ratio. This paper focused on the fabrication of cobalt electrospun nanofibrer for applications such as electronic, optical and mechanical devices by metal based material. We fabricated cobalt nanofibers on aluminum foil by an electrospinning method. The electrospinning process was performed at a high voltage, 8 kV. The distance between the needle tip and the solution surface in the bath was 5 cm. The PVB - cobalt based nitrate solution was filled in a 10 mL syringe connected to a 22 gauge needle. We confirmed electrospun cobalt nanofiber after annealing process by SIMS (Secondary Ion Mass Spectrometry) analysis. The concept design, fabrication and results of mapping measurements are reported.