• Title/Summary/Keyword: Metal contamination

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Chemical Assessment of Heavy Metal Contamination in Soil

  • Yang, Jae-E.;Choi, Moon-Heon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1997.05a
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    • pp.8-11
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    • 1997
  • Current methods of evaluating soil contamination by heavy metals rely on analyzing samples for total contents of metals or quantities recovered in various chemical extracting solutions. Results from these approaches provide only an index for evaluation because these methodologies yield values not directly related to bioavailability of soil-borne metals. In addition, even though concentrations of metals may be less than those required to cause toxic effects to biota, they may cause substantial effects on soil chemical parameters that determine soil quality and sustainable productivity. The objective of this research was to characterize effects of Cu or Cd additions on soil solution chemistry of soil quality indices, such as pH, EC, nutrient cation distribution and quantity/intensity relations (buffer capacity). Metals were added at rates ranging from 0 to 400 mg/kg of soil. Soil solution was sequentially extracted from saturated pastes using vacuum. Concentrations of Cu or Cd remaining in soil solutions were very low as compared to those added to the soils, warranting that most of the added metals were recovered as nonavailable (strongly adsorbed) fractions. Adsorption of the added metals released cations into soil solution causing increases of soluble cation contents and thus ionic strength of soil solution. At metal additions of 200~400 mg/kg, EC of soil solution increased to as much as 2~4 dS/m; salinity levels considered high enough to cause detrimental effects on plant production. More divalent cations (Ca+Mg) than monovalent cations (K+Na) were exchanged by Cu or Cd adsorption. The loss of exchangeable nutrient cations decreased long-term nutrient supplying capacity or each soil. At 100 mg/kg or metal loading, the buffering capacity was decreased by 60%. pH of soil solution decreased linearly with increasing metal loading rates, with a decrement of up to 1.3 units at 400 mg Cu/kg addition. Influences of Cu on each of these soil quality parameters were consistently greater than those of Cd. These effects were of a detrimental nature and large enough in most cases to significantly impact soil productivity. It is clear that new protocols are needed for evaluating potential effects of heavy metal loading of soils.

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Monitering of Heavy Metal (loid)s Contamination of Arable Soils near Industrial Complexes in Gyeongnam Province of South Korea

  • Park, Hye Jin;Lee, Hyun Ho;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.589-597
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    • 2016
  • There are a number of industrial complexes which could be a source of heavy metal (loid)s contamination of arable soil in Gyeongnam province of South Korea. Heavy metal (loid)s accumulation of plant is more related to the concentration of plant available heavy metal (loid)s in arable soil than that of total heavy metal (loid)s. The objectives of this study were 1) to examine heavy metal concentrations in soils located near industrial complexes in Gyeongnam province and 2) to determine the relationship between concentration of plant available heavy metal (loid)s and chemical properties of soil. Soil samples were collected from 85 sites of arable lands nearby 7 industrial complexes in Gyeongnam province. Total heavy metal (loid)s concentration, available heavy metal (loid)s concentration, and chemical properties of collected soils were measured. The mean concentrations of arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn) in the soils were $5.8mg\;kg^{-1}$, $1.3mg\;kg^{-1}$, $0.03mg\;kg^{-1}$, $51.5mg\;kg^{-1}$, and $68.7mg\;kg^{-1}$, respectively. Total concentration of Cd and Zn in arable soil located near ${\nabla}{\nabla}$ industrial complex exceeded the warning criteria ($4mg\;kg^{-1}$ and $300mg\;kg^{-1}$ for Cd and Zn, respectively) as described by in the soil environmental conservation Act of Korea. The concentration of plant available heavy metal (loid)s was negatively related to the soil pH and available Pb and Zn concentrations had relatively high correlation coefficient when compared with other heavy metal (loid)s. The concentration of plant available Pb and Zn was negatively related to that of organic matter (OM). Based on the above results, it might be a good soil management to control pH and OM concentration with soil amendments such as lime and compost to reduce phytoavailability of heavy metal (loid)s in arable soil located near industrial complex.

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1171-1175
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    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

Effect of Dietary Copper Exposure on Accumulation, Growth and Hematological Parameters of the Juvenile Rockfish, Sebastes schlegeli

  • Kim, S. G.;J. H. Jee;S. W. Jang;Park, D. K.;S. Y. Song;Y. H. Keum;J. C. Kang
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2003.05a
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    • pp.158-159
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    • 2003
  • Although the sub-chronic toxic effects of metal on fishes are well documented, that is mostly in fishes exposed to waterborne metal but few studied have been conducted on the effects of dietary metal (Handy, 1996). The realization that dietary uptake of metal is a major cause of long-term contamination in wild fish has renewed interest in the nutritional and toxicological effects of metal in the food of fishes (Handy, 1996). (omitted)

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충북지역 폐금속광산 주변 토양오염도 평가

  • Jeong Myeong-Chae;Gang Man-Hui;Ji Han-Gu;Hwang Beom-Sun;Park Jeong-Gu;Jeong Hyeon-Seok
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.24-27
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    • 2005
  • This study has focused on investigation on As and heavy metal contamination derived from metalliferous mining activities in the Choongbuk Province in Korea. Soil, mine effluent, surface water and ground water samples were taken in and around 27 abandoned metal mines, and analyzed for As, Cd, Cu, Ni, Pb and Zn using AAS and anions in water samples using IC. In general, the heavy metal concentrations in soils decreased with Increasing distance from the each mine audit. Tailings and mine waste soils from several mines contained over the guideline of Soil Conservation Act in Korea. Soil samples from the Seobo, Honga, Daehwa, Jeungjadong, Youngbo and Munbaek mines contained over the action levels of the metals due to intensive mining activities. Therefore, a proper remediation work needs to control the metal dispersion around the mines.

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Risk Assessment for Heavy Metal Pollutants of Abandoned Mines Using Statistical Techniques (통계적 기법을 이용한 휴폐광산의 중금속 위해성 평가)

  • Dho, Hyon-Seung;Kim, Sung-Duk;Lee, Seung-Joo
    • Journal of the Korea Safety Management & Science
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    • v.11 no.3
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    • pp.41-48
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    • 2009
  • The risk assessment for heavy metal pollutions were analyzed by using statistical techniques including correlation and cluster analyses. The contamination data in this investigation obtained were from the Chungcheongnam-do abandoned mines. The descriptive statistical analysis showed that the values of Pb and Zn were relatively higher than other heavy metal values. The detection of heavy metals by distance from abandoned mines within 1,000m were mostly As, Cd, Pb, and Zn. It was noted, especially, that Zn was even detected at 4,000m The results of coefficient correlation showed that Zn to Cd was the highest values. The cluster and dendogram analyses were generated. The results showed the two clear groups by heavy metal characteristics.

Microstructural study of polycrystalline films prepared by Ni vapor induced crystallization

  • Ahn, Kyung-Min;Lee, Kye-Ung;Ahn, Byung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.715-717
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    • 2006
  • $NiCl_2$ vapor was introduced into conventional furnace to conduct vapor-induced crystallization (VIC) process. We made the metal chloride atmosphere by sublimating the $NiCl_2$ compound. The $NiCl_2$ atmosphere enhanced the crystallization of amorphous silicon thin films. As the result, polycrystalline Si film with large grain size and low metal contamination has been obtained.

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Solidification of Heavy Metal Ions using Magnesia-Phosphate (인산염 마그네시아에 의한 중금속 이온 고정화)

  • Song, Myong-Shin;Kang, Hyun-Ju;Choi, Hun;Kim, Ju-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.317-318
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    • 2010
  • At the latest industry develops, heavy metals or sludge contaminated surrounding farm land and rivers. In this study, wished to solve problem by saying contaminated sludge and tailing and heavy metals to do solidification using Magnesia phosphate cement. Confirmed through above experiment that magnesia is effect in solidification and stabilization of chromium and lead.

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A Study on the Soil Contamination in Incheon Metropolitan Area Based on GIS (GIS 기법을 이용한 인천지역의 토양오염도 작성에 관한 연구)

  • Park, Jeong-Jun;Shin, Eun-Chul
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.4
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    • pp.1-11
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    • 2008
  • This paper analyzed the status of contaminated soils in order to manage it efficiently in Incheon using Geographic Information System (GIS) and investigated the concepts and techniques of the GIS and interpolation method. GIS technique is applied to the analysis of soil quality monitoring data. The purposes of this research are to assess the soil contamination of Incheon metropolitan area and to analyze the existing contents of heavy metals (Cd, Cu, As, Hg, Pb, $Cr^{+6}$) and pH in soil. The samples had been collected from year 1998 to year 2002 by the Soil Contamination Monitoring Network. The soil quality monitoring results were imported with the geographical information of the monitoring programs in capital area. It is found that currently available GIS technique has a great extend of potential for soil quality management. From the analysis of soil quality monitoring results, the GIS application demonstrates the poor soil quality in the central capital area and the it is improved as it travels down to the suburb area. Concerning about the data interpolation, the discrepancy caused by applying different method was ignorable, although Kriging method is further developed.

The AS4059 Hydraulic System Cleanliness Classification System: Replacement of NAS1638

  • Day, Mik;Hong, Jeong-Hee
    • Journal of Drive and Control
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    • v.9 no.2
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    • pp.39-45
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    • 2012
  • The NAS 1638 cleanliness classification system was originally developed in 1966 by the US Aircraft Industries of America to both simplify reporting of particle count data and to control the introduction of dirt during the assembly of aircraft fluid systems. The numbers of particles at stated sizes are represented by broad bands where the interval was generally a doubling of contamination. A number of systems have been introduced since this to suit differing requirements. NAS 1638 and AS4059 are used in other industrial sectors such as the Off-shore & Sub-Sea and the Primary Metal Industries. The changes to ISO contamination measurement standards controlled by ISO/TC131/SC6 in 1999 meant that a revision of most of these classification systems was necessary. The body responsible for NAS 1638 decided to withdraw it for new installations and replace it with an update of an existing standard, SAE AS 4059. This paper details the philosophy behind the contamination coding systems, the reasons for the changes to the ISO contamination standards and explains the workings of AS 4059, the replacement for NAS 1638. It goes on to detail the latest changes to this standard.