• Title/Summary/Keyword: Metakaolin

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Strength and toughness prediction of slurry infiltrated fibrous concrete using multilinear regression

  • Shelorkar, Ajay P.;Jadhao, Pradip D.
    • Advances in concrete construction
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    • v.13 no.2
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    • pp.123-132
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    • 2022
  • This paper aims to adapt Multilinear regression (MLR) to predict the strength and toughness of SIFCON containing various pozzolanic materials. Slurry Infiltrated Fibrous Concrete (SIFCON) is one of the most common terms used in concrete manufacturing, known for its benefits such as high ductility, toughness and high ultimate strength. Assessment of compressive strength (CS.), flexural strength (F.S.), splitting tensile strength (STS), dynamic elasticity modulus (DME) and impact energy (I.E.) using the experimental approach is too costly. It is time-consuming, and a slight error can lead to a repeat of the test and, to solve this, alternative methods are used to predict the strength and toughness properties of SIFCON. In the present study, the experimentally investigated SIFCON data about various mix proportions are used to predict the strength and toughness properties using regression analysis-multilinear regression (MLR) models. The input parameters used in regression models are cement, fibre, fly ash, Metakaolin, fine aggregate, blast furnace slag, bottom ash, water-cement ratio, and the strength and toughness properties of SIFCON at 28 days is the output parameter. The models are developed and validated using data obtained from the experimental investigation. The investigations were done on 36 SIFCON mixes, and specimens were cast and tested after 28 days of curing. The MLR model yields correlation between predicted and actual values of the compressive strength (C.S.), flexural strength, splitting tensile strength, dynamic modulus of elasticity and impact energy. R-squared values for the relationship between observed and predicted compressive strength are 0.9548, flexural strength 0.9058, split tensile strength 0.9047, dynamic modulus of elasticity 0.8611 for impact energy 0.8366. This examination shows that the MLR model can predict the strength and toughness properties of SIFCON.

Fundamental Properties of Antiwashout Underwater Concrete Mixed with High Reactivity Metakaloin

  • Moon, Han Young;Shin, Kook Jae;Song, Yong Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.1077-1080
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    • 2003
  • High reactivity metakaolin (HRM) is a manufactured pozzolan produced by thermal processing of purified kaolinitic clay. Field performance and laboratory research of concrete containing HRM have demonstrated its value for bridge decks, bridge deck overlays, high-strength concrete and masonry products. This paper discusses laboratory evaluations to assess the physical properties of antiwashout underwater concrete (AWC) containing HRM, such as pH value, suspended solids, slump flow, and compressive strength. There were not much variations of pH value with the changing HRM contents, but suspended solid test showed that the amount of suspended solids of AWC with 10 and 20% of HRM were reduced in comparison with plain. Due to the fast hydration and reaction property of HRM, slump flow was decreased with increasing HRM contents. According to the results of compressive strength test, AWC with 10 and 20% of HRM showed higher strength characteristic than plain at all curing ages.

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An Experimental Study on the Properties of Hwangtoh Mortar for the Application of Construction Material (건축적 적용을 위한 황토모르터의 물성에 관한 실험적 연구)

  • Lee, Hyun-Chul;Lee, Gun;Go, Seong-Seok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.43-46
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    • 2006
  • The Hwangtoh is one of the traditional construction material used in wall, plastering material, and ondol (Korean underfloor heating system) with stone and wood. It is an important greenness material and it has much advantages such as; high storage of heat, auto-purification, antibiotic ability, and emission of far infrared rays. But, it is not developed and not used in modern construction because of its low strength and properties of dry shrinkage crack. According to the recent researches and studies, it is evaluated for natural pozzolanic material like flyash or pozzolan. It's possibility on construction material is high because it's chemical and mineralogical proportion is like as Metakaolin and Kaolinite. In this point of view, this study aims to analyze the physical properties on Hwangtoh mortar through an experiment with various activation condition of Hwangtoh, which is natural pozzolanic material, for the purpose of increase the using possibility in construction material.

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Improvement of Strength in ALC using Admixtures and Grain Size (혼합재 및 입도에 따른 경량기포콘크리트의 강도특성 개선)

  • Kim, Young-Yup;Song, Hun;Lee, Jong-Kyu;Chu, Yong-Sik
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.79-82
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    • 2007
  • Recently, the use of ALC has became increasingly popular. ALC is a unique building material. Because of its cellular nature, it is lightweight, self-insulating, sound and fireproof, as well as insect and mold resistant. Furthermore, ALC is free of VOCs and various fibers associated with wood and glass wool construction. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. These properties make troubles under construction such as cracking and popout. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures, and grain size. Admixtures make use of metakaolin, silica fume, sodium silicate and sodium hydroxide. From the test result, the ALC using admixture have a good fundamental properties compared with plain specimen. Compressive strength, specific strength and abrasion's ratio were improved depending on increasing admixtures ratio's, and grain size.

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Bond Properties of Structural Poly Vinyl Alcohol Fiber in Cement Based Composites with Metakaolin and Silica Fume Contents (메타카올린 및 실리카퓸 첨가율에 따른 구조용 PVA 섬유와 시멘트 복합재료의 부착특성)

  • Lee, Jung-Woo;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.5
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    • pp.9-16
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    • 2012
  • In this study, the effect of metakaoline and silica fume on the bond performances of structural polyvinyl alcohol (PVA) fiber in cement mortar, including bond strength, interface toughness, and microstructure analysis are presented. Metakaoline and silica fume contents ranging from 0 % to 15 % are used in the mix proportions. Pullout tests are conducted to measure the bond performance of PVA fiber from cement mortar. Test results showed the incorporation of metakaoline and silica fume can effectively enhance the PVA fiber-cement mortar interfacial properties. Bond strength and interface toughness increased with metakaoline and silica fume content up to 10 % in cement mortar and decreased when the metakaoline and silica fume content reached 15 %. The microstructural observation confirms the findings on the interface bond mechanism drawn from the fiber pullout test results.

Temperature and leaching effects of zeolite-X derived from kaolin

  • Henry E. Mgbemere;Henry Ovri;Anna-Lisa Sargent
    • Advances in materials Research
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    • v.13 no.2
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    • pp.103-114
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    • 2024
  • Zeolites are microporous materials that find applications in different fields due to their numerous interesting properties. This research investigated the effect of leaching on unheated Ifon kaolin in dilute hydrochloric acid and sulphuric acid. The hydrothermal method synthesized zeolite-X type, and the resulting sample was characterized using different techniques. The silica/alumina ratio in the synthesized sample was approximately 5.6, while Infrared spectra confirmed that the synthesized material was Zeolite-X. Based on the X-ray diffraction patterns, other phases were also formed in addition to zeolite-X crystals. Thermogravimetry results indicated that the synthesized zeolite was relatively stable below 500℃, so its weight loss was only 13% after heating to about 200℃. A differential thermal analyzer confirmed this amount of weight loss, and endothermic and exothermic reactions were also observed for the samples calcined respectively at 700 and 900℃. Based on Brunauer-Emmett-Teller (BET) analyses, samples at 700℃ showed slower adsorption-desorption isotherms, pore volume, and sizes than those at 900℃. These results have shown that leaching and calcination temperature significantly affect the type of zeolite produced.

Preventive Measures on Alkali-Silica Reaction of Crushed Stones (쇄석 골재의 알칼리-실리카 반응 방지 대책)

  • Jun Ssang-Sun;Lee Hyo-Min;Seo Ki-Young;Hwang Jin-Yeon;Jin Chi-Sub
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.129-137
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    • 2005
  • In Korea, due to the insufficiency of natural aggregates and increasing needs of crushed stones, it is necessary to examine the alkali-silica reaction of the crushed stones. The reaction produces an alkali-silica reaction gel which can imbibe pore solution and swell to generate cracks that are visible In affected concrete. In general, crushed stones are tested by petrograptuc examination, chemical method and mortar-bar method, but the most reliable method Is mortar-bar test. This study tested alkali-silica reactivity of crushed stones of various rock types using ASTM C 227 and C 1260, and compared the results of two test methods. This study also analyzed effects of particle size and grading of reactive aggregate on alkali-silica reaction expansion of mortar-bar. The effectiveness of mineral admixtures to reduce detrimental expansion caused by alkali-silica reaction was investigated through the ASTM C 1260 method. The mineral admixtures used were nv ash, silica fume, metakaolin and ground granulated blast furnace slag. The replacement ratios of 0, 5, 10, 15, 25 and $35\%$ were commonly applied for all the mineral admixtures and the replacement ratios of 45 and $55\%$ were additional applied for the admixtures that could maintain workability. The results indicate that replacement ratios of $25\%$ for ay ash, $10\%$ for silica fume, $25\%$ for metakaolin or $35\%$ for ground granulated blast furnace slag were most effective to reduce alkali-silica reaction expansion under the experimental conditions.

A Study on the Optimization of the Mix Proportions of High Strength Concrete Fire-Resistant Reinforcement Using Orthogonal Array Table (직교배열표를 이용한 고강도콘크리트 내화성능 보강재의 배합 최적화 연구)

  • Lee, Mun-Hwan
    • Journal of the Korea Concrete Institute
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    • v.21 no.2
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    • pp.179-186
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    • 2009
  • The peculiarity pointed out for high strength concrete is the occurrence of spalling during a fire. Recently, there are many efforts such as development of all types of spalling reducing materials and other innovative materials in various fields. Need is now to examine the adequate mixing proportions of these materials. This study intended to derive experimentally and statistically mix proportions that can represent the basic quality requirements as well as the optimal effects on the fire-resistance for 4 types of functional materials that are metakaolin, waste tire chip, polypropylene fiber and steel fiber. Here, the tests were planned through an optimal test method using an orthogonal array table with 4 parameters and 3 levels. The statistical analysis adopted the response surface analysis method. Results verified mutual complementary contribution between the materials when using a combination of the functional materials selected as parameters for the strengthening of the fire-resistance of 80 MPa-class high strength concrete. Besides, the optimal conditions of the fire-resistance strengthening materials derived through response surface analysis were a volumetric replacement of silica fume by 80% of metakaolin, a volumetric replacement of fine aggregates by 3% of tire waste chip, and an addition of 0.2% of the whole volume by polypropylene fiber without mixing of steel fiber. In such cases, the basic characteristics as well as the fire-resistant characteristics of high strength concrete were also satisfied.

Preparation and Properties of Geopolymer for Cultural Asset Restoration (문화재 복원용 무기계 수지의 합성 및 특성)

  • Hwang, Yeon;Hwang, Sun-Do;Kang, Dae-Sik;Park, Mi-Hye
    • Journal of Conservation Science
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    • v.25 no.1
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    • pp.17-24
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    • 2009
  • The feasibility of the geopolymer as a cultural asset restoration material was studied by investigating compressive strength and chromaticity change. Metakaolin that was synthesized by calcination of the kaolin at $750^{\circ}C$ for 6 hours was used as a geopolymeric starting material. Kaolin lost its crystallinity and changed into non-crystalline phase during calcination. NaOH solution and water glass were used as an initiator for the geopolymeric reaction. As the concentration of NaOH solution and water glass increased the compressive strength increased. When alumina was substituted with metakaolin, the compressive strength decreased at a small amount of alumina, but increased at a large substitution. For the most composition of geopolymers, the change of chroma values remained within the limit of slight variation after exposure to sunlight for 8 and 100 days. However, even small amount of organic pigment addition increased chroma values of metakaoline. It was shown that geopolymer had excellent chroma value change over epoxy resins.

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Phenomenological Model to Re-proportion the Ambient Cured Geopolymer Compressed Blocks

  • Radhakrishna, Radhakrishna;Madhava, Tirupati Venu;Manjunath, G.S.;Venugopal, K.
    • International Journal of Concrete Structures and Materials
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    • v.7 no.3
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    • pp.193-202
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    • 2013
  • Geopolymer mortar compressed blocks were prepared using fly ash, ground granulated blast furnace slag, silica fume and metakaolin as binders and sand/quarry dust/pond ash as fine aggregate. Alkaline solution was used to activate the source materials for synthesizing the geopolymer mortar. Fresh mortar was used to obtain the compressed blocks. The strength development with reference to different parameters was studied. The different parameters considered were fineness of fly ash, binder components, type of fine aggregate, molarity of alkaline solution, age of specimen, fluid-to-binder ratio, binder-to-aggregate ratio, degree of saturation, etc. The compressed blocks were tested for compression at different ages. It was observed that some of the blocks attained considerable strength within 24 h under ambient conditions. The cardinal aim was to analyze the experimental data generated to formulate a phenomenological model to arrive at the combinations of the ingredients to produce geopolymer blocks to meet the strength development desired at the specified age. The strength data was analyzed within the framework of generalized Abrams' law. It was interesting to note that the law was applicable to the analysis of strength development of partially saturated compressed blocks when the degree of saturation was maintained constant. The validity of phenomenological model was examined with an independent set of experimental data. The blocks can replace the traditional masonry blocks with many advantages.