• Title/Summary/Keyword: Mercury cathode

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Nickel Amalgamation by Electro-deposition Process Using Mercury Cathode and Its Properties (수은 음극 상 전착에 의한 니켈 아말감의 제조와 그 물성)

  • Kim, Ki-Ho
    • Journal of Surface Science and Engineering
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    • v.38 no.5
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    • pp.198-201
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    • 2005
  • Nickel amalgam was Prepared by the electro-deposition with mercury cathode in a modified Watts bath. Homogeneous nickel amalgam was obtained. The fluidity of the amalgam decreased gradually with increased nickel quantity and become solid finally. Nickel powders of sub-micron size were obtained by a distillation of mercury from the amalgam. The characterization of the nickel amalgam was studied by SEM and x-ray diffractometry.

On the Photoelectric Effects of the Various Kinds of Light Source influencing to the Starting Characteristics of the Cold Cathode Type Discharge Tube (냉음극방전관의 기동특성에 미치는 각종광원에 의한 광전효과)

  • Chee, Chol Kon;Won, Chong Soo
    • 전기의세계
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    • v.13 no.4
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    • pp.10-15
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    • 1964
  • It is well known that the starting characteristics of the cold cathode type discharge tube have photoelectric effects by the incident light from outside. After making the cold cathode type discharge tubes to be avaiable for popularizing, the present paper was devoted primaliry to a study of relations between the starting characterstics and photoelectric effects of discharge tube under the oight circumstances of day light, incandescent lamp, flouresent lamp, and mercury lamp we used frequently. The result of this investigation show that the photoelectric effects by flourescent lamp emitting short wave length having close ralation to the photoelectric effects is greater than incandescent lamp or day light, and also mercury lamp emitting shorter wave length than flourescent lamp indicates the greatest photoelectric effects.

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Decontamination of Mercury Contained in CCFLs (Cold Cathode Fluorescence Light) Disassembled from Waste LCDs (Liquid Crystal Display) (폐 LCD (Liquid Crystal Display) 해체 후 분리된 CCFL (Cold Cathode Fluorescence Light) 내 수은의 건식 제거 공정)

  • Park, Jae Layng;Lee, Sungkyu;Kang, Leeseung;Lee, Chan Gi;Cho, Sung-Su;Hong, Myung Hwan;Hong, Hyun Seon
    • Resources Recycling
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    • v.23 no.2
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    • pp.61-70
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    • 2014
  • LCD televisions and monitors use cold cathode fluorescence lamps (CCFLs) to illuminate the screen. Most CCFLs contain mercury and they have to be carefully handled at the end of their lives as per minimum treatment standards under the Waste Electrical and Electronic Equipment (WEEE) and Restriction of Hazardous Substances (RoHS) directives. CCFLs were carefully separated from mold frames of waste LCD units for primary decontamination of mercury/fluorescent compound mixture using CCFL decontamination system designed and fabricated in the present research. Residual mercury was further removed by employing a pyro-process, where crushed CCFL tubes transferred from primary decontamination process were subject to heat treatment at $550^{\circ}C$ in a box furnace: more than 99% of mercury was removable from waste CCFLs.

Analysis of Fabrication and Characterization of free-Hg fluorescent lamp for LCD Backlight (LCD Backlight 용 무수은 형광램프의 제작 및 특성 분석)

  • 이휘철;임성규
    • Proceedings of the IEEK Conference
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    • 2000.11b
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    • pp.237-240
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    • 2000
  • It is expected that there will be the regulation for limiting the amount of Hg content in cold cathode fluorescent lamp (CCFL) for LCD backlight system. Now it is necessary to develop mercury-free backlight system. The mercury-free CCFL coated with PDP phosphors was fabricated and evaluated. The CCFL filled with Xe and Ne showed 4500 ㏅/$m^2$ with efficiency of 13 lm/W.

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Uranium tetrafluoride production at pilot scale using a mercury electrode cell

  • Dides, Munir;Hernandez, Jose;Olivares, Luis
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1909-1913
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    • 2022
  • This work shows the technical feasibility to obtain uranium tetrafluoride through an electrochemical mercury cell. This technique represents a custom scaling-up methodology from our previous studies to obtain UF4 using the dropping mercury electrode cell. The UF4 products were obtained from natural UF6 gas, which was hydrolyzed to obtain a 50 g/L UO2F2 solution. The electrolysis cell was made using a mercury reservoir, to reach UF4 production rates of 1 Kg UF4/day. This custom design allowed a stable UF4 production thanks to the mercury cathode, which do not permit the accumulation of solid products in its surface. The cell was tested using current densities from 5.000 to 17.500 A/m2 and temperatures from 25 to 65 ℃. The maximum current efficiency achieved under these conditions was 80%. The UF4 powders possessed spherical morphology, with diameters between 20 and 80 ㎛. Compared to the SnCl2 precipitation, this process did not allow preferential growth of the precipitates. This improved the compaction of the UF4 - Mg powders mixtures, with densities between 3.0 and 3.5 g/cm3. The purity of the UF4 products was over 98%.

Fundamental Studies on the Development of On-line Monitoring of Trace Mercury in Drinking Water (음용수 중 수은 연속자동측정시스템의 개발에 관한 연구)

  • Chang, Soo-Hyun;Kim, Hyo-Jin;Kim, Sun-Tae;Kim, Young-Man
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.299-305
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    • 1999
  • The electrolyte cathode atomic glow discharge (ELCAD) is a new plasma source for direct determination of trace heavy metals in drinking and waste water. ELCAD has been successfully developed for on-line monitoring of heavy metals, however, shows difficulty to measure mercury. In this study, ELCAD has been modified to apply the atomic absorption spectrometry (AAS) for the direct determination of trace elements of mercury in flowing water.The fundamental characteristics of this new types of plasma source have been investigated and found that the pH of the solution, discharge voltage, and current are most important factors.The absorbance of 1.0 ppm Hg standard solution increases as pH of the solution increases from pH 1.0 to 3.0.However, % RSD of the absorbance also increases as the pH of solution increasesdue to plasma unstability.The detection limits of the standard solution of pH 1.5 and pH 3.0 are about 40 ppb and 10 ppb level, respectively.

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Pulse Density Modulated ZVS High Frequency Inverter with Reverse Blocking Single Switch for Dielectric Barrier Discharge Lamp Dimming

  • Sugimura Hisayuki;Yasui Kenji;Omori Hideki;Lee Hyun-Woo;Nakaoka Mutsuo
    • Proceedings of the KIPE Conference
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    • 2006.06a
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    • pp.206-209
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    • 2006
  • At present, the cold cathode fluorescent lamp (CCFL) using mercury lamp has been generally used far liquid crystal backlight source of personal computer and car navigation and so on. This kind of lamp is more excellent on luminance performance and cost. However, the requirements of liquid crystal backlight due to a light source without mercury have been strongly increased from a viewpoint of the actual influence on environmental preservation and environmental recycling. As fluorescent lamp without mercury, Dielectric Barrier Discharge based rare gas fluorescent lamp (DBD-FL) using xenon (Xe) gas has been studied so far. This DBD lamp has no influence on the human body and environmental recycle. Its operating life is long because electrode is out. In this paper, the simulation and experimental results of soft switching high frequency inverter with reverse blocking single switch as a high frequency power supply circuit for DBD-FL using Xe gas are comparatively evaluated and discussed from a practical point of view.

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Multi-color Optogalvanic spectroscopy of Mercury Atom (수은 원자의 다색 Optogalvanic Spectroscopy)

  • 정도영
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.06a
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    • pp.41-44
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    • 1991
  • 수은 원자의 6 1So - 6 3P1 - 6 2D2, 3D1, 2 - continuum 간의 다단계 광이온화 과정을 수은 hollow cathode lamp를 사용하여 optogalvanic 효과를 관찰하므로써 연구하였다. 단색 단일공명, 이색 단일공명, 이색 이중공명 및 삼색 이중공명 여기과정에 대한 optogalvanic 신호의 time profile 과 스펙트럼을 관측하여 분석했으며, optogalvanic 스펙트럼으로부터 6 3P1 - 61, 3D1 전이들의 상대적 진동차 세기를 측정하였다.

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A Study of Mercury-Cathode Membrane Cells for the Electrolytic Reduction of Uranyl Solutions (膈膜電解槽와 水銀陰極에 依한 Uranyl 溶液의 電解還元)

  • Kim, Jae-Won;Simard, R.
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.1-9
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    • 1962
  • Bench-scale horizontal cation-permeable membrane cells were constructed to study the effect of cell dimensions on the efficiency of electrolytic reduction of uranyl sulphate solutions flowing continuously over a mercury cathode. Current efficiencies were determined for various cells having length-to-width ratios of 10/1 to 40/1, and for catholyte solutions containing from 20 to 100g $U_3O_8/l$ in sulphuric acid. Optimum current density and solution flowrate were determined under these conditions. The effects of the nitrate and chloride ions were briefly examined.

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Chlor-alkali Membrane Process and its Prospects (클로알칼리 멤브레인법과 전망)

  • Park, In Kee;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.3
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    • pp.203-215
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    • 2015
  • Chlor-alkali (CA) membrane process is based on salined water electrolysis employing cation condutive polymer electrolytes, which has been used for the conventional production of both sodium hydroxide and chlorine gas. The CA membrane process has advantages such as relatively low environmental impacts and fairly reduced energy consumption, when compared with diaphragm and mercury process. In this review articles, basic concepts, fundamental characteristics, key technologies of CA membrane process are dealt with in detail. In addition, advanced technologies associated with CA membrane process are described. They include zerogap and oxygen depolarized cathode technologies to improve energy efficiency during the electrolysis. Carbon dioxide mineralization technology will also be introduced as an example of hybridization with different technologies. Finally, current market trend in CA membrane process will be presented.