• Title/Summary/Keyword: Mercury balance

Search Result 11, Processing Time 0.026 seconds

Preparation of Novel Sorbents for Gas-phase Mercury Removal

  • Lee, Si-Hyun;Rhim, Young-Jun;Park, Young-Ok
    • Carbon letters
    • /
    • v.3 no.4
    • /
    • pp.187-191
    • /
    • 2002
  • In the present research, we prepared the activated carbon (AC) sorbents to remove gas-phase mercury. The mercury adsorption of virgin AC, chemically treated AC and fly ash was performed. Sulfur impregnated and sulfuric acid impregnated ACs were used as the chemically treated ACs. A simulated flue gas was made of SOx, NOx and mercury vapor in nitrogen balance. A reduced mercury adsorption capacity was obtained with the simulated gas as compared with that containing only mercury vapor in nitrogen. With the simulated gas, the sulfuric acid treated AC showed the highest performance, but it might have the problem of corrosion due to the emission of sulfuric acid. It was also found that the high sulfur impregnated AC also released a portion of sulfur at $140^{\circ}C$. Thus, it was concluded that the low sulfur impregnated AC was suitable for the treatment of flue gas in terms of stability and efficiency.

  • PDF

High Efficiency Alternating Current Driver for Capacitive Loads Using a Current-Balance Transformer

  • Baek, Jong-Bok;Cho, Bo-Hyung;Park, Joung-Hu
    • Journal of Power Electronics
    • /
    • v.11 no.1
    • /
    • pp.97-104
    • /
    • 2011
  • This paper proposes a new alternating current driving method for highly capacitive loads such as plasma display panels or piezoelectric actuators, etc. In the proposed scheme, a current balance transformer, which has two windings with the same turn-ratio, provides not only a resonance inductance for energy recovery but also a current balance among all of the switching devices of the driver for current stress reduction. The smaller conduction loss than conventional circuits occurs due to the dual conduction paths which are parallel each other in the current balance transformer. Also, the leakage inductances of the transformer are utilized as resonant inductors for energy recovery by the series resonance to the capacitive load. Furthermore, the resonance contributes to the small switching losses of the switching devices by soft-switching operation. To confirm the validity of the proposed circuit, prototype hardware with a 12-inch mercury-free flat fluorescent lamp is implemented. The experimental results are compared with a conventional energy-recovery circuit from the perspective of luminance performances.

IDENTIFICATION OF POSSIBLE MERCURY SOURCES AND ESTIMATION OF MERCURY WET DEPOSITION FLUX IN LAKE ONTARIO FROM LAKE ONTARIO ATMOSPHERIC DEPOSITION STUDY (LOADS)

  • Han, Young-Ji
    • Environmental Engineering Research
    • /
    • v.10 no.6
    • /
    • pp.306-315
    • /
    • 2005
  • Total gas phase mercury (TGM) concentrations and event wet-only precipitation for Hg were collected for nine months (from April, 2002 to Dec., 2002) at Sterling, NY on the shoreline of Lake Ontario. TGM concentrations measured in this study ($3.02{\pm}2.14\;ng/m^3$) were in somewhat high range compared to other background sites. Using simplified quantitative transport bias analysis (SQTBA) possible sources affecting high Hg concentration in Sterling was identified, and they are coal-fired power plants located in southern NY and Pennsylvania. Wet deposition measured at Mercury Deposition Network (MDN) sites including Pt. Petre and Egbert, ON were compared with data obtained at the Sterling to estimate the total mercury wet deposition flux to Lake Ontario. The wet deposition flux was calculated to be the highest at the Sterling site ($7.94\;{\mu}g/m^2$ from April, 2002 to Dec. 2002) and the lowest at the Egbert ($3.92\;{\mu}g/m^2$), due to the both the difference in precipitation depth and Hg concentration in the precipitation. The deposition measured at the Sterling site is similar to Lake Michigan deposition of $6-14\;{\mu}g/m^2$ (converted for ninth months) measured for Lake Michigan Mass Balance Study (LMMBS).

A Study on the AC Arc Model of High Pressure Mercury Discharge (고압 수은방전의 교류 아아크 모델에 관한 연구)

  • Chee, Chol-Kon;Kim, Hoon;Lee, Sang-Woo
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.36 no.9
    • /
    • pp.655-659
    • /
    • 1987
  • This study presents a model of the electrical characteristics of the high-pressure mercury vapour arc discharge. Energy balance equation per unit volume of the arc tube is converted into the one per unit length by assuming the parabolic radial temperature distribution and integrating over the cross-section of the tube. Using this energy balance equation, together with the circuit equation and Ohm's law, the arc voltage and current variation for 1 cycle is numerically calculated and a good result is obtained. A simple method to calculate the axis temperature of the arc tube and the radiation output is also presented.

  • PDF

Effect of SO2 on the Simultaneous Removal of Mercury and NOx over CuCl2-loaded V2O5-WO3/TiO2 SCR Catalysts (CuCl2가 담지된 V2O5-WO3/TiO2 SCR 촉매에 의한 수은 및 NOx 동시 제거에서 SO2의 영향)

  • Ham, Sung-Won
    • Clean Technology
    • /
    • v.28 no.1
    • /
    • pp.38-45
    • /
    • 2022
  • CuCl2-loaded V2O5-WO3/TiO2 catalyst showed excellent activity in the catalytic oxidation of elemental mercury to oxidized mercury even under SCR condition in the presence of NH3, which is well known to significantly inhibit the oxidation activity of elemental mercury by HCl. Moreover, it was confirmed that, when SO2 was present in the reaction gas together with HCl, excellent elemental mercury oxidation activity was maintained even though CuCl2 supported on the catalyst surface was converted to CuSO4. This is thought to be because not only HCl but also the SO4 component generated on the catalyst surface promotes the oxidation of elemental mercury. However, in the presence of SO2, the total mercury balance before and after the catalytic reaction was not matched, especially as the concentration of SO2 increased. In order to understand the cause of this, further studies are needed to investigate the effect of SO2 in the SnCl2 aqueous solution employed for mercury species analysis and the effect of sulfate ions generated on elemental mercury oxidation. It was confirmed that SO2 also promotes NOx removal activity, which is thought to be because the increase in acid sites by SO4 generated on the catalyst surface by SO2 facilitates NH3 adsorption. The composition change and structure of the components present on the catalyst surface under various reaction conditions were measured by XRD and XRF. These measurement results were presented as a rational explanation for the results that SO2 enhances the oxidation activity of elemental mercury and the NOx removal activity in this catalyst system.

New calibration apparatus for a precise barometer (초정밀 기압계 교정을 위한 새로운 압력계 교정장치 개발)

  • 우삼용;이용재;최인묵;김부식;최종운
    • Journal of the Korean Vacuum Society
    • /
    • v.12 no.3
    • /
    • pp.157-161
    • /
    • 2003
  • Nowadays there are increasing demands for more accurate measurement of atmospheric pressure according to the development of environmental industries. One of the most important pressure gauges for satisfying these demands is a quartz resonance barometer. In order to calibrate such an accurate barometer, laser/ultrasonic mercury manometers have been used. However, complexity and cost of mercury manometers made it out of use gradually. As a substitute, a gas-operated pressure balance is used for calibration of precise barometers. In such a case, commercially available pressure balances cannot be entirely suitable because consequent exposure of the piston, cylinder and masses to the atmosphere causes the problem of contamination. In this paper a device for changing the masses in situ without breaking the vacuum is described. This device made it possible to add or remove weights in the absolute mode, thereby greatly reducing the time between observations. At the same time, we investigated the characteristics of a commercial precise barometer using this new apparatus.

Study on the Emission Characteristics of Heavy metals in sewage sludge Incinerator (하수슬러지 소각시설의 중금속 배출특성에 관한 연구)

  • Park, Jung-Min;Lee, Sang-Bo;Kim, Min-Jung;Kim, Jin-Pil;Kim, Jong-Chooun;Lee, Suk-Jo;Lee, Sang-Hak
    • Journal of environmental and Sanitary engineering
    • /
    • v.24 no.3
    • /
    • pp.28-36
    • /
    • 2009
  • We have closely examined the concentration change characteristics, emission amounts, and the material balance of hazardous air pollutants at both early and later stages of the prevention facilities. These results will be uses as the basic data when preparing for the regulatory and management plans for hazardous air pollutants. The results of the study on heavy metals illustrated that the content of heavy metals in sludge across five facilities were as follows: copper> zinc> chrome> nickel> cadmium> mercury. In terms of heavy metal content in swage sludge, the sludge in incinerating facilities other than the sludge in the D incinerating facility containing industrial water waste, was examined in order to satisfy the ocean contamination standard and fertilizer specifications. Most of the items were shown to have satisfied the emission tolerance standards in the latter part of the prevention facilities(The average elimination rate was over 90%). Therefore, it is concluded that swage sludge containing high-concentrate heavy metals needs to be incinerated rather than recycled as fertilizer.

A Study on the Analysis of Various Characteristics for the High Pressure are Discharge System (고압 아아크 방전시스템의 각종 특성 해석에 관한 연구)

  • 지철근;박왕열;이진우
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.5 no.4
    • /
    • pp.35-42
    • /
    • 1991
  • Recently, HID lamps have been considered as important in regard to the trend of energy saving, and increasingly and diversely used in various ways. This paper will show the simulating models concerning high-pressure arc discharge system directly applicable for its design and manufacture, and analyze its various characteristics. For warm-up characteristics, the evaporating process of inner atoms is described in terms of second-order differential equation: for the thermal conduction from are axis to discharge wall and outer bulb, its transfer process is introduced according to five first-order differential equations. Under the steady state satisfying LTE, the time-variant characteristics are suggested by means of time-dependent energy balance equation derived from fluid equations, approximation of radiation energy and material functions in the discharge tube. The simulating models concerning these equations are then applied for high-pressure mercury lamp.

  • PDF

Theoretical Prediction of AC Characteristics of Low Pressure Lamps (저압 방전등 교류 접등 특성의 이론적 예측)

  • 지철근;장우진;여인선;이진우
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.38 no.6
    • /
    • pp.470-476
    • /
    • 1989
  • In order to develop a mathematical model which can predict the operating voltage and current of a discharge lamp, the properties and the physical phenomena of a low pressure gas discharge are investigated. Fluorescent lamp which uses a low pressure mercury-argon gas discharge is used in the model development. In a low pressure mercur-argon gas discharge, the continuity equation for each excited atom and electron, and the electron energy balance equation can predict the physical quantities of discharge. By coupling these equations and the circuit equation, the electrical characteristics of the discharge lamp can be predicted. To verify the validity of the suggested model, we calculated the voltage and current of a fluorescent lamp operating with inductor ballast for source frequency of 5KHz, 8KHz, 10KHz, and 13KHz. The results show good agreements in wave forms between the measured voltage and current, and the difference between the measured and calculated one is less than 5%.

  • PDF

A New Current-Balancing Multi-Channel LED Driver for a Large Screen LCD Backlight Unit (대화면 LCD Backlight를 위한 새로운 전류평형 다채널 LED 구동회로)

  • Lee, Sang-Hyun;Cho, Sang-Ho;Roh, Chung-Wook;Hong, Sung-Soo;Han, Sang-Kyoo
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.15 no.2
    • /
    • pp.111-118
    • /
    • 2010
  • Recently, LCD TV using LED backlight has a great attention due to its low power consumption, slim construction, mercury free, wide color gamut and fast response. For the uniform brightness of the LCD panel, multi channel LEDs and DC/DC converter for each LED are required in conventional system. Therefore energy conversion efficiency is poor, the system size bulky and the cost of production high. To overcome these above mentioned drawbacks, a new current-balancing multi-channel LED driver is proposed in this paper. It can not only drive multi-channel LEDs with one DC/DC converter but also provide all LEDs with constant balanced current. To confirm the validity of the proposed driver, its operation and performance are verified on a prototype for 46" LCD TV.