• Title/Summary/Keyword: Membrane separation

Search Result 1,433, Processing Time 0.022 seconds

Development of blend membrane by sulfonated polyethersulfone for whey ultrafiltration

  • Esfandian, Fatemeh;Peyravi, Majid;Qoreyshi, Ali Asqar;Jahanshahi, Mohsen
    • Membrane and Water Treatment
    • /
    • v.7 no.2
    • /
    • pp.155-173
    • /
    • 2016
  • The present work has been focused on the development of polysulfone (PSf) ultrafiltration membrane via blending by sulfonated polyethersulfone (SPES) in order to permeability enhancement for ultrafiltration of cheese whey. In this regards, sulfonation of polyethersulfone was carried out and the degree of sulfonation was estimated. The effect of blend ratio on morphology, porosity, permeation and fouling of PSf / SPES membranes was investigated. Filtration experiments of whey were conducted for separation of macromolecules and proteins from the lactose enrichment phase. The morphology and performance of membranes were evaluated using different techniques such SEM, AFM, and contact angle measurements. The contact angle measurement showed that the hydrophilicity of membrane was increased by adding SPES. According to AFM images, PSf / SPES membranes exhibited lower roughness compared to neat PSf membrane. The water and whey flux of these membranes were higher than neat membrane. However, flux was decreased when the PSf / SPES blend ratio was 0/100. It can be attributed to pore size and morphology changes. Further, fouling parameters of PSf membrane were improved after blending. The blend membranes show a great potential to be used practically in proteins separation from cheese whey.

Preparation of activated carbon incorporated polysulfone membranes for dye separation

  • Ingole, Pravin G.;Sawant, Sandesh Y.;Ingole, Neha P.;Pawar, Radheshyam R.;Bajaj, Hari C.;Singh, Kripal;Cho, Moo Hwan;Lee, Hyung Keun
    • Membrane and Water Treatment
    • /
    • v.7 no.6
    • /
    • pp.477-493
    • /
    • 2016
  • Immediate use of activated carbon incorporated polysulfone membrane application for dye separation was reported in this work. Dimethylformamide (DMF) was used as the solvent for the membrane preparation. The membrane thus prepared were characterized in terms of surface morphology, ATR-FTIR, AFM, experimental results as membrane performance. The resultant nanofiltration (NF) membranes were tested with Congo red dye concentration 200 mg/L. The water permeability was found to be considerably higher than that reported in literature. Experimental results show that the real rejection of the Congo red is 99.57% over the transmembrane pressure 100 psi using 30% activated carbon incorporated membrane. Prepared NF membranes shows the corresponding permeates fluxes were $40Lm^{-2}h^{-1}$ to $82Lm^{-2}h^{-1}$ with different activated carbon percentage incorporated in polysulfone membrane. The present study demonstrated that dye rejection enhanced NF may be a feasible method for the dye wastewater treatment. The overall observations thus indicated that toxic residual dyes can be appreciably separated from the membrane technology, provided that the accompanying polymeric membrane, activated carbon as binding agents and the process parameter levels are astutely selected.

Cr (VI) separation by PolyHIPE membrane immobilized with Aliquat 336 by solvent-nonsolvent method

  • Chen, Jyh-Herng;Mai, Le Thi Tuyet;Hsu, Kai-Chung
    • Membrane and Water Treatment
    • /
    • v.8 no.6
    • /
    • pp.575-590
    • /
    • 2017
  • PolyHIPEs membrane prepared with styrene (St), divinylbenzene (DVB), and ethylhexyl acrylate (EHA) can yield a unique pore structure provided by large voids highly interconnected by many small window throats. With the advantageous pore structure, PolyHIPE presents a potential as a support for carrier facilitated transport membrane. Tricaprylmethylammonium chloride (Aliquat 336) can be efficiently incorporated into the PolyHIPE membrane by a two-step solvent-nonsolvent method to obtain an Aliquat 336-immobilized PolyHIPE membrane with good stability. The study of Cr (VI) transport through Aliquat 336-immobilized PolyHIPE membrane indicates that the membrane has high initial flux and maxima stripping flux ($J_f^o=15.01({\mu}mol/m^2s)$, $J_s^{max}=6.15({\mu}mol/m^2s)$). The reusability study shows that the Aliquat 336-immobilized PolyHIPE membrane can maintain high Cr(VI) recovery efficiency even after 15 cycles of operations. The developed membrane was also used in the separation of Cr (VI) from other anions (i.e., $SO_4{^{2-}}$ and $NO_3{^-}$) and other cations (i.e., Ni (II), Mg (II) and Cu (II)) with good selectivity.

A Study on Separation Mechanisms in Tangential Flow Membranes (접선류 방식의 막분리 공정에 있어서 분리기구 해석에 관한 연구)

  • 이기정;허병기목영일
    • KSBB Journal
    • /
    • v.4 no.3
    • /
    • pp.281-287
    • /
    • 1989
  • The experimental study reported herein was to investigate to separation characteristics of a tangential flow membrane in a continuous recycle situation. Physical and dynamic analyses are performed on the membrane system in order to relate relevant variables to the capacity of separation. The results of separation process may be summarized by a proposed equation:Sh=A(Re.Sc.dh/L)1/3. It was shown also by the analyses that effective separation of sugar and cell was attainable by means of tangential membranes, thereby enhancing ethanol productivity in fermentation with continuous cell and substrate recycle.

  • PDF

Preparation of a ultrathin hollow fiber ceramic microfiltration membrane (초극세 중공사형 세라믹 정밀여과막 제조)

  • Park, In-Hwan;Kim, In-Chul;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2004.05b
    • /
    • pp.144-146
    • /
    • 2004
  • Various polymeric hollow fiber membranes have been prepared and been used widely due to their high surface area per unit volume and high permselectivity. However, the organic materials are only limited to mild operating conditions because of their weak thermal stability and ease of fouling.(omitted)

  • PDF

연속공정에 의한 UF용 폴리이미드 분리막의 제조

  • 김완주;전종영;탁태문
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1995.04a
    • /
    • pp.45-45
    • /
    • 1995
  • Filtration, one of the most important process in the various industrials, is defined as the separation of two or more compounds from a fluid by passing the mixture refers to the separation of solid, immisible particles from liquid or gaseous mixture. Membrane filtration which is a type of filtration extends it's application further to include the separation, concentration, and filtration. The main objective of this investigation is the preparation of organic solvents-resistant polyimide membranes by using phase inversion technique and their application as a UF membrane. Specially, the dope solution was prepared from the newly developed method. The newly developed method is that the dope solution was directly prepared from the polyimide solution which was prepared by the modified one-step polymerization. The effects of the parameters for membrane preparation such as the casting solution composition and the casting conditions were investigated and the performance and chemical stabfiity of membrane are going to be tested.

  • PDF

The comparison of stability among three types of emulsions in the emulsion liquid membrane separation processes

  • Liu, Hongjing;He, Gaohong;Chen, Guohua
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2004.05a
    • /
    • pp.47-50
    • /
    • 2004
  • Since emulsion liquid membrane (ELM) was found by Li in the late 1960s$^{[1]}$ , a great amount of work has been conducted on the research and application of ELM$^{[2-8]}$ . Generally, during a process of ELM separation, three types of emulsions will be shown in turn. They are primary emulsion, multiple emulsion, namely ELM, and recovered emulsion respectively. Those three types of emulsions inevitably share some common properties, and at the same time, because those three types of emulsions emerge in different stages of ELM separation, some differences will be observed.(omitted)

  • PDF

Multicomponent Nanostructured Materials for Separation Membranes

  • Peinemann, Klaus-Viktor
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2004.05a
    • /
    • pp.11-11
    • /
    • 2004
  • Under the coordination of GKSS a new European project in the field of membrane development started recently. This project focuses on the development of novel nanostructured materials for selective material transport and separation. Two classes of materials will be developed in this project: nanostructured organic/inorganic hybrid materials and functional self-organized supramolecular copolymers.(omitted)

  • PDF

Thends in Membrane Contactors (분리막 접촉기의 기술 동향)

  • Lee Kew-Ho;Kim Min-Joung;Sea Bongkuk;Park You-In;Lee Ki-Sub
    • Membrane Journal
    • /
    • v.15 no.3
    • /
    • pp.187-197
    • /
    • 2005
  • A membrane contactor is a device that achieves liquid/liquid or gas/liquid mass transfer without dispersion of one phase within another. This is accomplished by passing the fluids on opposite sides of a microporous membrane. This approach offers a number of important advantages over conventional dispersed phase contactors, including absence of emulsions, no flooding at high flow rates, no unloading at low flow rates, and high interfacial area. This article provides a general review of membrane contactors, including operating principles and applications.