• Title/Summary/Keyword: Membrane Contactors

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Membrane Contactors for Water Carbonation

  • Alessandra Criscuoli;Enrico Drioli
    • Membrane Journal
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    • v.1 no.1
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    • pp.59-59
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    • 1991
  • A theoretical and experimental study made in order to determine the performance of mem-brane contactors in water carbonation is presented. In particular on the basis of experimental results pre-viously obtained it has been derived an expression in which the effect of some parameters as temprera-ture water and CO₂ flow rate CO₂ pressure trans-membrane pressure on the performance of the process is taken into account. The study refers to hollow fiber membrane contactors used for the experimental tests. The main scope has been to verify if by membrane contactors it is possible to reach the same de-gree of water carbonation as by trditional methods (1-5 g/1) and to derive for the module used a cor-relation able to describe the performance of the process at several operating conditions. The high CO₂ removal observed confirms the interesting potentialties of membrane contactors also in gas streams purification.

Membrane Contactors for Water Carbonation

  • Alessandra Criscuoli;Enrico Drioli
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.59-64
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    • 1999
  • A theoretical and experimental study made in order to determine the performance of mem-brane contactors in water carbonation is presented. In particular on the basis of experimental results pre-viously obtained it has been derived an expression in which the effect of some parameters as temprera-ture water and {{{{{CO }_{2 } }}}}} flow rate {{{{{CO }_{2 } }}}}} pressure trans-membrane pressure on the performance of the process is taken into account. The study refers to hollow fiber membrane contactors used for the experimental tests. The main scope has been to verify if by membrane contactors it is possible to reach the same de-gree of water carbonation as by trditional methods (1-5 g/1) and to derive for the module used a cor-relation able to describe the performance of the process at several operating conditions. The high {{{{{CO }_{2 } } }}}} removal observed confirms the interesting potentialties of membrane contactors also in gas streams purification.

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The Computer Simulation and Estimation of Membrane Mass Transfer Coefficients of Hollow Fiber Membrane G-L Contactors for SO2 Removal (SO2 제거를 위한 중공사막 기-액 접촉기의 모사 및 분리막 물질 전달 계수 추정)

  • Kim, Yong Kuk;Song, Hee Ouel;Lee, Hyung Keun;Kim, In-Won
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.81-86
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    • 2007
  • Hollow fiber membrane G-L contactors are widely used to remove $SO_2$ emitted from industrial facilities. In this work, the mathematical modeling and computer simulation for hollow membrane G-L contactors is carried out to analyze $SO_2$ absorption behavior in hollow fiber membranes. The model is solved with the finite element method using a commercial software. Investigated is the dependency of $SO_2$ removal efficiency and mass transfer characteristics on gas velocities, membrane mass transfer coefficients and physical properties of contactors. The membrane mass transfer coefficients are estimated by fitting the experimental data with the simulated $SO_2$ removal efficiencies. In addition, a design methodology of membrane contactors is suggested.

MEMBRANE CONTACTORS IN INTEGRATED SYSTEMS

  • Criscuoli, Alessandra;Drioli, Enrico
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.52-54
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    • 1999
  • In the present work, results of simulation studies carried out for the water carbonation process are presented and compared with experimental data obtained for the same system. Furthermore, the use of membrane contactors in integrated membrane operations is proposed and discussed as a mean to enhance the performance of processes.

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Advanced Membrane Systems for Seawater Desalination. Kinetics of Salts Crystallization from RO Brines Promoted by Polymeric Membranes

  • Curcio, Efrem;Obaidani, Sulaiman Al;Macedonio, Francesca;Profio, Gianluca Di;Gualtieri, Silvia;Drioli, Enrico
    • Membrane Journal
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    • v.17 no.2
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    • pp.93-98
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    • 2007
  • The reliability of innovative membrane contactors technology (i.e. Gas/Liquid Membrane Contactors, Membrane Distillation/Crystallization) is today increasing for seawater desalination processes, where traditional pressure-driven membrane separation units are routinely operated. Furthermore, conventional membrane operations can be integrated with membrane contactors in order to promote possible improvements in process efficiency, operational stability, environmental impact, water quality and cost. Seawater is the most abundant aqueous solution on the earth: the amount of dissolved salts covers about 3% of its composition, and six elements (Na, Mg, Ca, K, Cl, S) account for more than 90% of ionic species. Recent investigations on Membrane Distillation-Crystallization have shown the possibility to achieve significant overall water recovery factors, to limit the brine disposal problem, and to recover valuable salts (i.e. calcium sulphate, sodium chloride, magnesium sulphate) by combining this technology with conventional RO trains. In this work, the kinetics of $CaSO_4{\cdot}2H_2O,\;NaCl\;and\;MgSO_4{\cdot}7H_2O$ crystallization is experimentally investigated in order to improve the design of the membrane-based crystallization unit.

Effect of Membrane Material and Absorbent Type on $SO_2$ Removal Using Microporous Hollow-fiber Membrane G-L Contactors (다공성 중공사막 기액 접촉기틀 이용한 $SO_2$ 제거에서 막재질과 흡수제의 영향)

  • Song Hee-Ouel;Kim In-Won;Park Hyun-Hee;Lim Chun-Won;Jo Hang-Dae;Lee Hyung-Keun
    • Journal of the Korean Institute of Gas
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    • v.10 no.2 s.31
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    • pp.14-21
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    • 2006
  • An experimental apparatus for the removal of $SO_2$ gas using microporous hollow-fiber membrane G-L contactors was setup. Various performance experiments were carried out with commercial membrane modules and the membrane modules made by KIER. The $SO_2$ removal efficiency was outstanding. When the hollow-fiber membrane was used for the removal of $SO_2$, the selection of absorbers and additives, membrane material, operating conditions of membrane manufacture were significant variables to develop optimal G-L contactors. More experiment works will be done for the development of compact, cost-effective and better G-L contactors.

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Thends in Membrane Contactors (분리막 접촉기의 기술 동향)

  • Lee Kew-Ho;Kim Min-Joung;Sea Bongkuk;Park You-In;Lee Ki-Sub
    • Membrane Journal
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    • v.15 no.3
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    • pp.187-197
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    • 2005
  • A membrane contactor is a device that achieves liquid/liquid or gas/liquid mass transfer without dispersion of one phase within another. This is accomplished by passing the fluids on opposite sides of a microporous membrane. This approach offers a number of important advantages over conventional dispersed phase contactors, including absence of emulsions, no flooding at high flow rates, no unloading at low flow rates, and high interfacial area. This article provides a general review of membrane contactors, including operating principles and applications.

Mathematical modeling of humidification process by means of hollow fiber membrane contactor

  • Marjani, Azam;Baghdadi, Ali;Ghadiri, Mehdi
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.297-311
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    • 2016
  • Modeling and simulation of air humidification by hollow fiber membrane contactors are investigated in the current study. A computational fluid dynamic model was developed by solving the k-epsilon turbulence 2D Navier-Stokes equations as well as mass conservation equations for steady-state conditions in membrane contactors. Finite element method is used for the study of the air humidification under different operating conditions, with a focus on the humidity density, total mass transfer flux and velocity field. There has been good agreement between simulation results and experimental data obtained from literature. It is found that the enhancement of air stream decreases the outlet humidity from 0.392 to 0.340 (module 1) and from 0.467 to 0.337 (module 2). The results also indicated that there has been an increase in air velocity in the narrow space of shell side compared with air velocity wide space of shell side. Also, irregular arrangement has lower dead zones than regular arrangement which leads to higher water flux.

Evaluation of Propylenecarbonate/water Physical Absorbents and its Application in Membrane Contactors for CO2/CH4 Separation (CO2/CH4 분리를 위한 프로필렌카보네이트/물 흡수제 특성 평가 및 막접촉기의 적용)

  • Park, Ahrumi;Kim, Seong-Joong;Lee, Pyung Soo;Nam, Seung Eun;Park, You In
    • Membrane Journal
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    • v.26 no.2
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    • pp.126-134
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    • 2016
  • To produce renewable biomethane from biogas, the properties of physical absorbents such as water, methanol, 1-methyl-2-pyrrolidone (NMP), poly(ethylene glycol) dimethylether (PEGDME), and propylene carbonate (PC) were studied, and PC was applied to membrane contactor systems. Among physical absorbents, PC exhibited a high contact angle of $58.3^{\circ}$ on polypropylene surface, and a PC/water mixture (5 wt%) increased the contact angle to $90^{\circ}$. Furthermore, the PC/water mixture presented higher $CO_2$ absorption capacities (0.148-0.157 mmol/g) than that of water (0.121 mmol/g), demonstrating a good property as an absorbent for membrane contactors. Actual operations in membrane contactors using the PC/water mixture resulted in $CO_2$ removal of 98.0-97.8% with biomethane purities of 98.5-98.3%, presenting a strong potential for biogas treatment. However, the PC/water mixture yielded moderate improved in $CO_2$ removal and methane recovery, as compared with water in the membrane contactor operation. This is originated from insufficient desorption processes to reuse absorbent and low $CO_2$ flux of the PC/water absorbent. Thus, it is requiring optimizations of membrane contactor technology including development of absorbent and improvement of operation process.