• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.13 no.12
• /
• pp.1266-1274
• /
• 2001

Heat transfer phenomena during melting process of the phase change material (ice) was studied by numerical analysis and experiments. In a horizontal ice storage tube, the natural convection caused an increase in melting rate. However, the reduction of the heating surface area caused a decrease in melting rate. Therefore, during the melting process of ice in a horizontal cylinder, the reduction of the heating surface area should be considered. Under the same heating wall and initial water temperature condition, the melting rate became higher for $V_s/V_tot/=0.545 \;than \;that\; for\; V_s/V_tot$/=1.00 due to the difference in the reduction of heating surface area. A modified melting model considering the equivalent thermal conductivity of liquid phase and volume reduction was proposed. The results of the model were compared with the measured values and found to be in good agreement.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.7 no.4
• /
• pp.547-555
• /
• 1995

Melting process of ice in a rectangular cavity with different temperature walls has been studied experimentally. Front shape of ice and melting rate were affected by initial temperature of ice and variation of temperature distribution and density gradient. When the hot wall temperature was below $8^{\circ}C$, the melting rates were higher at the bottom than those of at the top due to the density inversion, but with increasing the hot wall temperature the melting rates at the top were affected by hot wall and were higher than those of at the bottom. When the initial temperature of ice was low, melting rates were low, but with increasing the time melting rates were almost the same with those of each initial temperature of ice.

• Journal of Korea Foundry Society
• /
• v.7 no.3
• /
• pp.184-191
• /
• 1987

In this study the principles of melting phenomena of compacted vermicular graphite cast iron are discussed by considering the effects of the variation of phosphorus content and heating rate on the quenched microstructure of the specimens. In compacted vermicular graphite cast iron containing little phosphorus, the melting phenomena are found initially at the outer region of austenite shell and subsequently progressed with the diffusion of carbon through the austenite shell without regard to heating rate. But as the phosphorus content was increased over than 0.12wt.%, the melting phenomena initiated at the boundary of eutectic shell and progressed along the contact area between the melt and graphite tips at higher heating rate. At lower heating rate, the melt of steadite dissolved at the lower temperature than that of eutectic was moved toward the graphite through the austenite grain-boundary and promoted melting of graphite and matrix.

• International Journal of Air-Conditioning and Refrigeration
• /
• v.9 no.2
• /
• pp.1-7
• /
• 2001

One of the important applications of a contact melting process is a latent thermal energy storage system owing to its high heat flux and small temperature variation. In some previous works, the split fins have been employed in order to enhance the melting rate. In the present work, the direct contact melting was experimentally investigated using an ice as specimen for both split and non-split fins. It was shown that the contact melting by split fins increases the melting rate compared to that of non-split ones.

• Solar Energy
• /
• v.13 no.1
• /
• pp.39-48
• /
• 1993

This empirical paper addresses the phenomena of the contact melting of PCM in horizontal capsules of circular and rectangular cross sections with various aspect ratio. The melting-rate tends to increase as the Stefan number increases. The case of rectangular tube displays larger melting-rate than that of circular tube, and the melting-rate increases as the aspect ratio decreasws for rectangular tubes. In case of circular tube, the effect of natural convection on the melting-rate is 6.1%, 8.6% and 11.2% according to Stefan number 0.0772, 0.1287 and 0.1802 respectively.

• Journal of Pharmaceutical Investigation
• /
• v.37 no.1
• /
• pp.1-5
• /
• 2007

Solid dispersions of piroxicam were prepared by melting method using poloxamer as a carrier. The results of DSC and XRD studies showed that the amorphous farm of piroxicam coexisted with the crystalline form in the solid dispersions. However, the ratio of crystalline form of piroxicam in the solid dispersion prepared by melting method decreased in comparison with the same ratio of the solid dispersion prepared by solvent method. As the ratio of poloxamer in the solid dispersion increased, the ratio of the amorphous form of piroxicam in the solid dispersion increased. The dissolution rate of piroxicam from the solid dispersions was significantly higher than that from piroxicam powder. In comparison to the solid dispersion prepared by solvent method, the dissolution rate of piroxicam from the solid dispersion prepared by melting method was higher. As the ratio of poloxamer in the solid dispersion prepared by melting method increased, the initial dissolution rate decreased, however, the total amount dissolved at the end of the study increased.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.12 no.1
• /
• pp.67-74
• /
• 2000

One of the important application of a contact melting process is a latent thermal energy storage owing to its high heat flux. In some previous works, the split fins have been employed in order to enhance the melting speed. In the present work, the close contact melting was experimentally investigated using an ice as specimen for both split and non-split fins. It was shown that the contact melting by split fins increases the melting rate compared to that of non-split ones.

• Solar Energy
• /
• v.12 no.3
• /
• pp.60-69
• /
• 1992

Heat transfer characteristics and heat storage rate for vertical cylinder packed with paraffin as a latent heat storage material were theoretically studied. Conduction and convection mechanism were applied to the solid and liquid phase, respectively, and the results were compared with that of pure conduction model. The effects of heating temperature, initial solid temperature and aspect ratio on rate of storage were also studied. In the initial stage of melting, the natural convection is nearly restricted by the friction at the wall and the phase boundary. But it is generated when about 40% of solid melts and again it shrinks by the hot liquid situated on the upper part of the cylinder. So overall melting rate is higher then that for pure conduction model. The increase in heating temperature and aspect ratio activates the natural convection, so melting rate becomes higher. And the larger the aspect ratio, the greater the difference between upper and lower size of the solid. In the initial stage of melting, the initial temperature of solid paraffin has great effect on the melting rate, but as melting proceeds its effect lessens gradually.

• Journal of Korean Society of Water and Wastewater
• /
• v.22 no.4
• /
• pp.413-420
• /
• 2008

In order to utilize cinder melting slag as a filter media to control the quality of early rainwater, its environmental stability was verified by heavy metal elution experiment and improved by pre-treatment. Possibilities of improving its function as an absorbent was considered. Absorption characteristics of melting slag before and after the pre-treatment were analyzed by heavy metal equilibrium and stationary-phase column experiments, which in turn were analyzed by comparison experiment with activated carbon. As a result of heavy metal elution experiment, every metal item existed in a much lower amount than the criteria or was not detected, implying that there is no problem recycling it. Absorption equilibrium experiment showed that the time for pre-treatment melting slag to reach the equilibrium was reduced, while the absorbed amount was greatly increased. Stationary-phase column experiment assures us that the elimination rate was not changed much by influx rate, pH and the change in packing volume rate, indicating that this melting slag can be used not only as a filter media to control the quality of early rainwater but also in many areas of water-processing.

• Korean Journal of Microbiology
• /
• v.28 no.1
• /
• pp.19-26
• /
• 1990

To examine the effects of sequence variations near the transcriptional start site on the rate of formation of the open complexes at bacteriophage $\lambda P_{R}$ promoter, two mutant promoters were created by site-specific mutagenesis using synthetic oligonucleotides. Mutant I coatains changes at positions -3 and -4 from TT to CC, thus having a 6-bp long G/C stretch between -10 region and transciptional start site (+1). Mutant II has changes at positions -5 and -6 from GG to AA, thereby having a 9-bp long A/T stretch between positions -11 and -3. Selective filter binding assays were performed to measure the rate of formation of the open complexes between the wild-type or two mutant $P_{R}$ promoters on 664 bp fragments and E. coli RNA polymerase at two temperatures. At 37.deg.C, the wild-type and two mutants showed similar rates for the formation of open complex. The second order rate constant $k_{a}$ and $\tau _{int}$, as determined from the .tau.-plot analysis, were $(6.0\pm0.4)\times10^{6}M^{-1}sec^{-1}$ and $11\pm5$sec, respectively. At 18.deg.C, however, the wild-type and two mutant promoters showed differences in the kinetic parameters. k for the wild-type promoter was (2.2$\pm$0.1)\times 10^{6}M^{-1}sec^{-1}$ and $\tau _{int}$ was 76$\pm$sec. Mutant I and II exhibited differences mainly in the rate of isomerization ($\tau_{int,I}=91\pm$10 sec, int,II=34$\pm$ sec), whereas the second order rate constant $k_{a}$ was similar to the wild type value. This result implies that at $18^{\circ}C$, the isomerization rate is determined by both protein conformational change and DNA melting, which are separable kinetically according to the 3-step mechanism of Roe et al.(1984,1985), and that the base changes affected mainly the rate of DNA melting as predicted.lting as predicted.