• 제목/요약/키워드: Mechanical activation

검색결과 545건 처리시간 0.027초

Pd-based metallic membranes for hydrogen separation and production

  • Tosti, Silvano;Basile, Angelo
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
    • /
    • pp.25-28
    • /
    • 2003
  • Low cost composite metallic membranes for the hydrogen separation and production have been prepared by using thin Pd-Ag foils reinforced by metallic (stainless steel and nickel) structures. Especially, “supported membranes” have been obtained by a diffusion welding procedure in which Pd-Ag thin foils have been joined with perforated metals (nickel) and expanded metals (stainless steel): in these membranes the thin palladium foil assures both the high hydrogen permeability and the perm-selectivity while the metallic support provides the mechanical strength. A second studied method of producing "laminated membranes" consists of coating non-noble metal sheets with very thin palladium layers by diffusion welding and cold-rolling. Palladium thin coatings over these metals reduce the activation energy of the hydrogen adsorption process and make them permeable to the hydrogen. In this case, the dense non-noble metal has been used as a support structure of the thin Pd-Ag layers coated over its surfaces: a proper thickness of the metal assures the mechanical strength, the absence of defects (cracks, micro-holes) and the complete hydrogen selectivity of the membrane. membrane.

  • PDF

Curcumin의 신경병증성 통증 억제효과 (Curcumin Attenuates Chronic Constriction Nerve Injury-Induced Neuropathic Pain in Rats)

  • 김채은;박은성;전영훈
    • 한국약용작물학회지
    • /
    • 제16권3호
    • /
    • pp.183-187
    • /
    • 2008
  • Nerve injury can lead to neuropathic pain, which is often resistant to current analgesics and interventional therapeutic methods. Extracellular signal-regulated kinase (ERK) plays important role in the induction of neuropathic pain. We explored the antinociceptive effect of curcumin and its effect on ERK in the spinal cord in the neuropathic pain model of rats induced by chronic constriction injury (CCI) of the sciatic nerve. In injured rats, mechanical allodynia, which is one of characteristics of neuropathic pain developed and the activation of ERK in spinal cord significantly increased compared with control group. However, administration of curcumin (50 mg/kg/day p.o) for 7 days started from one day before the injury prevented the development of mechanical allodynia and increase of ERK phosphorylation. These results indicate that curcumin can be a new therapeutic agent in the treatment of neuropathic pain.

가솔린기관의 냉시동시 촉매 가열 촉진을 위한 점화시기 영향에 대한 실험적 연구 (An Experimental Study on Spark Timing Effect for Fast warmup of Catalyst to Cold Start Operation of an SI Engine)

  • 권영웅;함성훈
    • 한국기계기술학회지
    • /
    • 제13권4호
    • /
    • pp.101-108
    • /
    • 2011
  • On cold start operation of an SI engine, a catalyst shows poor performance before it reaches activation temperature. Therefore, fast warmup of the catalyst is very crucial to reduce harmful emissions. In this study, an appropriate control strategy is investigated to increase exhaust gas temperature through changes of spark timing. Combustion stability is also considered at the same time. Exhaust gas temperature and pressure of combustion chamber are measured to investigate the effects of spark timings on cold start and idle performance. Experiments showed that retarded spark timing promotes the combustion at the end of expansion stroke and increases exhaust gas temperature during cold start.

A Study on $\mu$BGA Solder Joints Reliability Using Lead-free Solder Materials

  • Shin, Young-Eui;Lee, Jun-Hwan;Kon, Young-Wook;Lee, Chong-Won;Yun, Jun-Ho;Jung, Seug-Boo
    • Journal of Mechanical Science and Technology
    • /
    • 제16권7호
    • /
    • pp.919-926
    • /
    • 2002
  • In this study, the numerical prediction of the thermal fatigue lie? of a $\mu$BGA (Micro Ball Grid Array) solder joint was focused. Numerical method was performed using the three-dimensional finite element analysis for various solder alloys such as Sn-37%Pb, Sn-3.5%Ag, Sn-3.5%Ag-0.7%Cu and Sn-3.5%Ag-3%In-0.5%Bi during a given thermal cycling. Strain values obtained by the result of mechanical fatigue tests for solder alloys, were used to predict the solder joint fatigue life using the Coffin-Manson equation. The numerical results showed that Sn-3.5%Ag with the 50-degree ball shape geometry had the longest thermal fatigue life in low cycle fatigue. A practical correlation for the prediction of the thermal fatigue life was also suggested by using the dimensionless variable γ. Additionally Sn-3.5Ag-0.75Cu and Sn-2.0Ag-0.5Cu-2.0Bi were applied to 6$\times$8$\mu$BGA obtained from the 63Sn-37Pb Solder. This 6$\times$8$\mu$BGA were tested at different aging conditions at 130$\^{C}$, 150$\^{C}$, 170$\^{C}$ for 300, 600 and 900 hours. Thickness of the intermetallic compound layer was measured thor each condition and the activation energy thor their growth was computed. The fracture surfaces were analyzed using SEM (Scanning Electron Microscope) with EDS ( Energy Dispersive Spectroscopy).

앉았다 일어서기 동작 수행 시 발목 관절 각도에 따른 근 활성도 및 역학적 부하량의 비교 (A Comparison of Muscle Activation and Mechanical Loading according to the Degree of Ankle Joint Motion during a Sit-to-stand Task)

  • 이명모;박대성
    • 대한물리의학회지
    • /
    • 제12권4호
    • /
    • pp.113-122
    • /
    • 2017
  • PURPOSE: The purpose of this study was to investigate the comparison of muscle activity and mechanical loading according to the angle of ankle joint during a sit-to-stand (STS) task. METHODS: Thirty-four young participants performed the STS in a randomized trial with the ankle joint at a neutral, 15 degrees dorsiflexion and 15 degrees plantarflexion angle in a fixed sitting posture with the knee in 105 degrees flexion. Muscle activity of the tibialis anterior (TA), rectus femoris (RF), biceps femoris (BF), and gastrocnemius medialis (GCM) was measured, and the parameters calculated in relation to mechanical loading were the STS-time, maximum peak, minimum peak, and total sum of mechanical loading. RESULTS: In the dorsiflexion position, the muscle activity of the TA and GCM showed a significant increase (p<.05), and the STS time, maximum peak and total sum of mechanical loading showed a significant difference compared to that in the neutral position (p<.05). In the plantarflexion position, the muscle activity of the RF and GCM showed a significant increase (p<.05), while that of the TA showed a significant decrease (p<.05) compared to that in the neutral position. And the minimum peak was significantly increased than the neutral position (p<.05), and the maximum peak and total sum of mechanical loading were showed significant difference compared with dorsiflexion position (p<.05). CONCLUSION: These results show that there is a difference in muscle activity and mechanical loading when performing the STS movement according to the change in the ankle joint angle.

Siloxane을 포함한 ETSO-DDM/BPH계 에폭시 시스템의 경화동력학 및 기계적 특성 분석 (Curing Kinetics and Mechanical Properties for Siloxane Contained ETSO-DDM/BPH Epoxy System)

  • 김효미;김종민;한중근;김주헌
    • 폴리머
    • /
    • 제33권4호
    • /
    • pp.364-370
    • /
    • 2009
  • 본 연구에서는 ETSO-DDM(epoxy terminated siloxane-diaminodiphenylmethane) 복합 경화제상 siloxane 함량 변화에 따른 bisphenol계 레진(BPH)과의 경화 특성 변화와 이에 따른 기계적 특성 변화를 고찰해 보았다. ETSO-DDM/BPH 복합재료의 경화 특성 변화는 DSC를 통해 관찰하였으며, 만능 물성기의 인장 시험과 굴곡 시험을 통해 기계적 특성 변화를 측정하였다. ETSO-DDM/BPH 시스템의 경화 활성화 에너지는 ETSO의 함량이 감소함에 따라 지속적으로 증가하는 경향을 보였다. 이는 ETSO 함량이 감소함에 따라 합성된 ETSO-DDM 공단량체의 사슬길이가 짧아지게 되고 이로 인해 ETSO-DDM/BPH간의 가교거리 역시 짧아지게 되어 결국 가교밀도를 증가시켰기 때문으로 판단된다. ETSO 함량이 감소할수록 인장강도, 인장탄성률, 굴곡강도 및 굴곡탄성률 등의 기계적 특성은 증가를 보이는데 이는 짧은 사슬길이의 ETSO-DDM 공단량체가 rigid한 구조를 형성하여 공간상 존재하는 분자구조의 에너지 상태가 최소가 되도록 packing하였기 때문으로 사료된다.

기계적인 합금화에 의한 Mg-18wt.%Ni 수소저장합금의 개발 (Development of Mg-18wt.%Ni-Hydrogen-Storage Alloy by Mechanical Alloying)

  • 송명엽;안동수;권익현;안효준
    • 한국재료학회지
    • /
    • 제10권1호
    • /
    • pp.15-20
    • /
    • 2000
  • 기계적으로 합금처리한 Mg-18wt.%Ni 혼합물의 수소저장특성이 조사되었다. 1h, 3h, 그리고 6h 동안 기계적으로 합금처리한 혼합물들 중에서 6h동안 기계적으로 합금처리한 혼합물(MA 6h sample)이 가장 좋은 활성화, 수소화물 형성.분해 특성을 보인다. 수소화물 형성.분해 cycling을 시킴에 따라 $Mg_2$Ni상이 형성된다. MA 6h sample은 비교적 쉽게 활성화되며, 순수한 Mg나 Mg-10wt.%Ni 합금보다 수소화물 형성속도가 높으나, $Mg_2$Ni 합금보다는 수소화물 형성속도가 약간 낮다. MA 6h sample은 $Mg_2$Ni 합금에 비해 낮은 수소화물 분해속도를 보이지만, 순수한 Mg나 Mg-25wt.%Ni 합금보다는 높은 수소화물 분해속도를 보인다. MA 6h sample은 순수한 Mg나 다른 합금들보다 큰 수소저장용량을 가지고 있다.

  • PDF

소형펀치-크리프 시험에 대한 응력해석과 일축 크리프 시험과의 상관성에 관한 연구 (A Study on Stress Analysis of Small Punch-Creep Test and Its Experimental Correlations with Uniaxial-Creep Test)

  • 이송인;백승세;권일현;유효선
    • 대한기계학회논문집A
    • /
    • 제26권12호
    • /
    • pp.2565-2573
    • /
    • 2002
  • A basic research was performed to ensure the usefulness of Small Punch-creep(SP-creep) test for residual life evaluation of heat resistant components effectively. This paper presents analytical results of initial stress and strain distributions in SP specimen caused by constant loading for SP-creep test and its experimental correlations with uniaxial creep(Ten-creep) test on 9Cr1MoVNb steel. It was shown that the initial maximum equivalent stress, ${\sigma}_{eq{\cdot}max}$ from FE analysis was correlated with steady-state equivalent creep strain rate, ${\epsilon}_{qf-ss'}$ rupture time, $t_r$, activation energy, Q and Larson-Miller Parameter, LMP during SP-creep deformation. The simple correlation laws, ${\sigma}_{sp}-{\sigma}_{TEN}$, $P_{sp}-{\sigma}_{TEN}\; and\; Q_{sp}-Q_{TEN}$ adopted to established a quantitative correlation between SP-creep and Ten-creep test data. Especially, the activation energy obtained from SP-creep test is linearly related to that from Ten-creep test at $650^{\circ}C$ as follows : $Q_{SP-P}\;{\risingdotseq}\;1.37 \;Q_{TEN},\; Q_{SP-{\sigma}}{\risingdotseq}1.53\; Q_{TEN}$.

HSLA-100강 및 HY-100강의 응력제거처리 균열에 관한 연구 (A Study on the Stress Relief Cracking of HSLA-100 and HY-100 steels)

  • 박태원;심인옥;김영우;강정윤
    • Journal of Welding and Joining
    • /
    • 제14권3호
    • /
    • pp.48-57
    • /
    • 1996
  • A study was made to examine the characteristics of base metal and stress relief cracking(SRC) of heat affected zone(HAZ) for HY-100 and Cu-bearing HSLA-100 steels. The Gleeble thermal/mechanical simulator was used to simulate the SRC/HAZ. The details of mechanical properties of base plate and SRC tested specimens were studied by impact test, optical microscopy and scanning electron microscopy. The specimens were aged at $650^{\circ}C$ for HSLA-100 steel and at $660^{\circ}C$ for HY-100 steel and thermal cycled from $1350^{\circ}C$ to $25^{\circ}C$ with a cooling time of $\Delta$t_${800^{circ}C/500^{circ}C}$=21sec. corresponds to the heat input of 30kJ/cm. The thermal cycled specimens were stressed to a predetermined level of 248~600MPa and then reheated to the stress relief temperatures of $570~620^{\circ}C$. The time to failure$(t_f)$ at a given stress level was used as a measure of SRC susceptibility. The strength, elongation and impact toughness of base plate were greater in HSLA-100 steel than in HY-100 steel. The time to failure was decreased with increasing temperature and/or stress. HSLA-100 steel was more susceptible to stress relief cracking than HY-100 steel under same conditions. It is thought to be resulted from the precipitation of $\varepsilon$-Cu phase by dynamic self diffusion of solute atoms. By the precipitation of $\varepsilon$-Cu phase, the differential strengthening of grain interior relative to grain boundary may be greater in the Cu-bearing HSLA-100 steel than in HY-100 steel. Therefore, greater strain concentration at grain boundary of HSLA-100 steel results in the increased SRC susceptibility. The activation energies for SRC of HSLA-100 steel are 103.9kcal/mal for 387MPa and 87.6kcal/mol for 437MPa and that of HY-100 steel is 129.2kcal/mol for 437MPa.

  • PDF