• Title/Summary/Keyword: Maximum removal

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Characteristics of Lead Removal by Methanotrophic Biomass (메탄자화균에 의한 납의 제거 특성)

  • 이무열;양지원
    • KSBB Journal
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    • v.15 no.5
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    • pp.444-451
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    • 2000
  • Nonliving methanotrophic biomass was used as biosorbent to remove lead which is one of representative pollutants in metal-bearing wastewater. Solution pH, maximum uptake, biosorbent dose and ionic strength were considered as major factors for adsorption experiments. The optimum pH range for lead removal was increased 3.8∼11.0 for methanotrophic biomass compared to biosorbent-free control, pH of 8.4∼11.2. Removal efficiency of lead by methanotrophic biomass was pH dependent, but less sensitive than that of control. In isotherm experiments with 0.2g biosorbent/L at initial solution pH 5.0, methanotrophic biomass took up lead from aqueous solutions to the extent of 1085 mg/g biomass. Removal amount of lead increased with an increase of biomass dose. According to biomass dose for initial 1000 mg Pb/L at initial pH 5.0, the optimum amount of biomass for maximum lead removal per unit methanotrophic biomass was 0.2 g biomass/L. As a result of scanning electron microscope (SEM) micrographs equipped with energy dispersive spectroscopy (EDS), lead removal by methanotrophic biomass seemed to be through adsorptions on the surface of methanotrophic biomass and exopolymers around the biomass. EDS spectra confirmed that lead adsorption appeared on the biomass and exopolymers that may be effective to lead removal comparing before and after contact with lead. Removal efficiency of lead was slightly affected by ionic strength up to 2.0 M of NaCl and NaNO$_3$respectively.

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Nitrate reduction by iron supported bimetallic catalyst in low and high nitrogen regimes

  • Hamid, Shanawar;Lee, Woojin
    • Advances in environmental research
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    • v.4 no.4
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    • pp.263-271
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    • 2015
  • In this study, the effect of initial nitrate loading on nitrate removal and byproduct selectivity was evaluated in a continuous system. Nitrate removal decreased from 100% to 25% with the increase in nitrate loading from 10 to $300mg/L\;NO_3-N$. Ammonium selectivity decreased and nitrite selectivity increased, while nitrogen selectivity showed a peak shape in the same range of nitrate loading. The nitrate removal was enhanced at low catalyst to nitrate ratios and 100% nitrate removal was achieved at catalyst to nitrate ratio of ${\geq}33mg\;catalyst/mg\;NO_3-N$. Maximum nitrogen selectivity (47%) was observed at $66mg\;catalyst/mg\;NO_3-N$, showing that continuous Cu-Pd-NZVI system has a maximum removal capacity of 37 mg $NO_3{^-}-N/g_{catalyst}/h$. The results from this study emphasize that nitrate reduction in a bimetallic catalytic system could be sensitive to changes in optimized regimes.

Parametric study of brewery wastewater effluent treatment using Chlorella vulgaris microalgae

  • Choi, Hee-Jeong
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.401-408
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    • 2016
  • The aim of this study was to evaluate the biomass and lipid production of Chlorella vulgaris and its nutrient removal capability for treatment of brewery wastewater effluent. The results indicate that the maximum biochemical oxygen demand (BOD) (91.43%) and chemical oxygen demand (COD) (83.11%) were removed by C. vulgaris with aeration in the absence of light. A maximum of 0.917 g/L of dry biomass was obtained with aeration in the dark conditions, which also demonstrated the highest amount of unsaturated fatty acids at 83.22%. However, the removal of total nitrogen (TN) and total phosphorus (TP) with these aeration and light conditions was 9.7% and 11.86% greater than that of other conditions. The removal of BOD and COD and the production of biomass and lipids with aeration in the dark and the TN and TP removal with aeration and light were more effective than other conditions in the brewery wastewater effluent in the presence of C. vulgaris.

Sensitivity Analyses for Maximum Heat Removal from Debris in the Lower Head

  • Kim, Yong-Hoon;Kune Y. Suh
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.395-409
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    • 2000
  • Parametric studies were performed to assess the sensitivity in determining the maximum in-vessel heat removal capability from the core material relocated into the lower plenum of the reactor pressure vessel (RPV)during a core melt accident. A fraction of the sensible heat can be removed during the molten jet delivery from the core to the lower plenum, while the remaining sensible heat and the decay heat can be transported by rather complex mechanisms of the counter-current flow limitation (CCFL) and the critical heat flux (CHF)through the irregular, hemispherical gap that may be formed between the freezing oxidic debris and the overheated metallic RPV wall. It is shown that under the pressurized condition of 10MPa with the sensible heat loss being 50% for the reactors considered in this study, i.e. TMI-2, KORI-2 like, YGN-3&4 like and KNGR like reactors, the heat removal through the gap cooling mechanism was capable of ensuring the RPV integrity as much as 30% to 40% of the total core mass was relocated to the lower plenum. The sensitivity analysis indicated that the cooling rate of debris coupled with the sensible heat loss was a significant factor The newly proposed heat removal capability map (HRCM) clearly displays the critical factors in estimating the maximum heat removal from the debris in the lower plenum. This map can be used as a first-principle engineering tool to assess the RPV thermal integrity during a core melt accident. The predictive model also provided ith a reasonable explanation for the non-failure of the test vessel in the LAVA experiments performed at the Korea Atomic Energy Research Institute (KAERI), which apparently indicated a cooling effect of water ingression through the debris-to-vessel gap and the intra-debris pores and crevices.

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Effect of the Organic and Nitrogen Removal and Electricity Production on Changing the External Resistor and the Inflow Loading in the Biocathode Microbial Fuel Cell (생물환원전극 미생물연료전지에서 외부저항 및 유입부하에 따른 유기물 및 질소 제거와 전기생산에 미치는 영향)

  • Kim, Jiyeon;Kim, Byunggoon;Kim, Hongsuck;Yun, Zuwhan
    • Journal of Korean Society on Water Environment
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    • v.31 no.5
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    • pp.556-562
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    • 2015
  • In order to remove the organic substances and the nitrate-nitrogen contained in wastewater, some researchers have studied the simultaneous removal of organics and nitrogen by using different biocathode microbial fuel cells (MFCs). The operating conditions for removing the contaminants in the MFCs are the external resistances, HRTs, the concentration of the influent wastewater, and other factors. This study aimed to determine the effect of the external resistors and organic loading rates, from the changing HRT, on the removal of the organics and nitrogen and on the production of electric power using the Denitrification Biocathode - Microbial Fuel Cell (DNB-MFC). As regards the results of the study, the removal efficiencies of $SCOD_{Cr}$ did not show any difference, but the nitrate-nitrogen removal efficiencies were increased by decreasing the external resistance. The maximum denitrification rate achieved was $129.2{\pm}13.54g\;NO_3{^-}-N/m^3/d$ in the external resistance $1{\Omega}$, and the maximum power density was $3,279mW/m^3$ in $10{\Omega}$. When the DNB-MFC was operated with increasing influent organic and nitrate loading by reducing the HRTs, the $NO_3{^-}-N$ removal efficiencies were increased linearly, and the maximum nitrate removal rate was $1,586g\;NO^3{^-}-N/m^3/d$ at HRT 0.6 h.

Preliminary Study on The Development of Phosphorous Removal Process by Converter and Furnace Slags (제강 전로 및 고로 슬래그를 이용한 인제거 기법에 관한 기초연구)

  • Lee, Seung-hwan;Jang, Jeong-hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.137-144
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    • 2004
  • In this study, several series of experiments were conducted to investigate the phosphorus (P) removal process in slag-containing solution using furnace and converter slags. High amount of $OH^-$, $Ca^{2+}$ and alkalinity were discharged from the slags and hydroxyapatites [$Ca_5(PO_4)_3(OH)$] were kept accumulated on the surface of slag. P removal capacity of the slag decreased with the increase of slag dosage. The maximum capacity was found to be 11.25 mg/g at the converter slag. Converter slag adsorbed P more than furnace slag(about four times in average). An experimental study on the effect of pH shows that the percentage removal of P increased upto 30% at the pH range of 56 than that of above pH 8. Langmuir isotherm constants gave a better correlation than Freundlich ones. P removal amount in the presence of $NH^+_4$ was less compared to the one in the absence of $NH^+_4$. Maximum percentage reduction was 23%.

Removal of Hydrogen Sulfide Using Porous Ceramic Biofilter Inoculated with Sulfur Oxidizing Bacteria (황산화 균주가 부착된 다공성 세라믹 biofilter를 이용한 $H_2S$ 제거)

  • 박상진;조경숙
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.649-655
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    • 1999
  • Biofiltration of polluted gas streams contained $H_2S$ was studied. The experiments were performed in a laboratory-scale reactor with a porous ceramic media inoculated with sulfur oxidizing bacterium, TAS which was isolated from activiated sludge. The concentration of $H_2S$ in the inlet gas varied from 109 to 3,841 ppm, at the various space velocities(SV) of 50 $h^{-1}$ to 250 $h^{-1}$. Various tests have been conducted to evaluate the effects of such parameters as pH, concentration of sulfate ion and retention time on the pressure drop and maximum elimination capacity. The removal efficiency of $H_2S$ decreased as the $H_2S$ concentration or gas velocity increased in the inlet gas. Pressure drop was insignificant in this system. The maximum elimination capacity could reach up to 16.35g-S/kg-dry packing material/day.

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Removal Efficiency of the Heavy Metals Zn(II), Pb(II) and Cd(II) by Saprolegnia delica and Trichoderma viride at Different pH Values and Temperature Degrees

  • Ali, Esam H.;Hashem, Mohamed
    • Mycobiology
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    • v.35 no.3
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    • pp.135-144
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    • 2007
  • The removal efficiency of the heavy metals Zn, Pb and Cd by the zoosporic fungal species Saprolegnia delica and the terrestrial fungus Trichoderma viride, isolated from polluted water drainages in the Delta of Nile in Egypt, as affected by various ranges of pH values and different temperature degrees, was extensively investigated. The maximum removal efficiency of S. delica for Zn(II) and Cd(II) was obtained at pH 8 and for Pb(II) was at pH 6 whilst the removal efficiency of T. viride was found to be optimum at pH 6 for the three applied heavy metals. Regardless the median lethal doses of the three heavy metals, Zn recorded the highest bioaccumulation potency by S. delica at all pH values except at pH 4, followed by Pb whereas Cd showed the lowest removal potency by the fungal species and vice versa in case of T. viride. The optimum bio-mass dry weight production by S. delica was found when the fungus was grown in the medium treated with the heavy metal Pb at pH 6, followed by Zn at pH 8 and Cd at pH 8. The optimum biomass dry weight yield by T. viride amended with Zn, Pb and Cd was obtained at pH 6 for the three heavy metals with the maximum value at Zn. The highest yield of biomass dry weight was found when T. viride treated with Cd at all different pH values followed by Pb whilst Zn output was the lowest and this result was reversed in case of S. delica. The maximum removal efficiency and the biomass dry weight production for the three tested heavy metals was obtained at the incubation temperature $20^{\circ}C$ in case of S. delica while it was $25^{\circ}C$ for T. viride. Incubation of T. viride at higher temperatures ($30^{\circ}C\;and\;35^{\circ}C$) enhanced the removal efficiency of Pb and Cd than low temperatures ($15^{\circ}C\;and\;20^{\circ}C$) and vice versa in case of Zn removal. At all tested incubation temperatures, the maximum yield of biomass dry weight was attained at Zn treatment by the two tested fungal species. The bioaccumulation potency of S. delica for Zn was higher than that for Pb at all temperature degrees of incubation and Cd bioaccumulation was the lowest whereas T. viride showed the highest removal efficiency for Pb followed by Cd and Zn was the minor of the heavy metals.

Estimates on appropriate storage for deicing materials for the 2018 Pyeongchang Winter Olympic Games (평창 동계올림픽을 대비한 적정 제설제 비축량 추정)

  • Kim, Jin Guk;Yang, Choong Heon
    • International Journal of Highway Engineering
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    • v.18 no.6
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    • pp.51-59
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    • 2016
  • OBJECTIVES : The objective of this study is to estimate the appropriate storage required for deicing materials in Gangwon-do for successful snow removal operations during the 2018 Pyeongchang Winter Olympic Games. The final estimates of the deicing chemicals can be used by public agencies to aid decision making. METHODS : First, the database that exists in the road snow-removal management system (RSMS) of the Ministry of Land, Infrastructure, and Transport, South Korea was used to determine historical characteristics of snow removal experiences in Gangwon-do. The database includes historical information, including regional and road weather data and number of snow-removal works. Second, both the maximum and the actual amount of storages used for deicing materials in the past three years were analyzed. Lastly, the final estimates of the deicing materials were evaluated using an additional equation. It considers frequency of salt spray application, total administrative road length estimated by road agencies, and number of days required for snow removal works in Gangwon-do. Consequently, the results show that significant differences were not observed between the final estimates and the maximum amount used during the past three years. RESULTS : The final estimates of the deicing materials are almost similar to the maximum amount used during the past three years in Gangwon-do. CONCLUSIONS : The study shows that the estimates of deicing chemicals can be useful when decision making is required for the snow-removal policy.

Anaerobic Treatment of Nitrate in Landfill Leachate (쓰레기 매립장 침출수 중 질소저감방안)

  • Kwon, Young Ho;Kim, Ho Ju
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.4
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    • pp.70-77
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    • 1998
  • On this study, removal ability of nitrate was researched in the anaerobic zone arounding collection pipes in landfill. Stability state time of column was after 20 days and 20~90ml/day in flux. In this time, removal rate of phosphate was about 80%. Removal ability and average removal rate of CODCr is $36g/m^3{\cdot}d$, 25.3%, respectively. It was that reactor is able to remove more nitrate. Maximum nitrate removal ability was $4.83g/m^3{\cdot}d$.

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