• Journal of Korean Society on Water Environment
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• v.24 no.5
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• pp.563-568
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• 2008

In petroleum refining industry, caustic (NaOH) solution is used to remove $H_2S$ from hydrocarbon streams in naphtha cracking process. Once $H_2S$ is absorbed in caustic solution, the solution becomes known as spent sulfidic caustic (SSC), which contains high concentrations of hydrogen sulfide and alkalinity. This study was focused on the evaluation of autotrophic denitrification by SSC in a hybrid Bardenpho process. SSC was injected to the anoxic (1) and anoxic (2) tank at different S/N ratio. In a previous lab-scale study, as we operated a modified Ludzack-Ettinger process, it was observed that the COD increment of effluent and nitrification failure happened because of non-biodegradable matters in SSC and high pH, respectively. Thus cilia media was packed at 2.4%(v/v) in all aerobic tanks and the pH of SSC was neutralized from 13.3 to 11.5 with addition of sulphuric acid ($H_2SO_4$). Consequently, these strategies were successful because no COD increment of effluent was observed and nitrification failure did not happen. The maximum TN removal efficiency was 77.5% when SSC was injected to both the anoxic (1) and anoxic (2) tanks. The mean TN concentration of effluent in this condition was 5.8 mg/L.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.3
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• pp.299-312
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• 2013

This study investigated the contaminant loading and characteristics of particle size distributions(PSDs) in the rainfall runoff from two different sources, the pavement road and the ancillary parking lot, and then evaluated four different types of filter media(i.e., EPP, EPS, Zeolite, and Perlite) to treat runoff water. The results showed that runoff from the pavement road contains 5.6 and 20 times higher SS and Pb concentrations, respectively, than that from the parking lot. The particles smaller than $100{\mu}m$ occupied 89.8 % of runoff from the pavement road and 81.4 % of that from the parking lot by volume. The effect of the hydraulic loading, at 950 m/day filtering linar velocity and 40 cm head loss, was largest for Zeolite, followed by Perlite, EPS, and EPP. The return period of tested media calculated by the regression equation for head loss indicated that EPP has the longest life time. The average SS removal rate was similar for all media at between 84.9 % and 89 %, while the effect of various filter column heights was different, showing minimal for EPP and maximum for EPS. All filter media tested demonstrated over 95 % of SS treatment efficiency for the particles bigger than $100{\mu}m$, while for the ones smaller than $100{\mu}m$ the efficiency was in order of EPP(82.4%) > Perlite(76.1 %) > EPS(66.2 %) > Zeolite(65.2 %). The results in conclusion implies that EPP is most effective filter media for the highly contaminated fine particles from road runoff.

• Journal of the Korean Wood Science and Technology
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• v.37 no.3
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• pp.222-230
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• 2009

This study was to investigate the effect of alkali treatment for long kenaf fiber to improve fiber surface characterics by removal of wax, lignin and hemicellulose which affect adversely for matrix union. SEM observation was also studied to check out the interface adhesion improvement by the alkali pre-treatment. From the result, interface coherence increased by 3% alkali pre-treatment and reached a maximum by 5% alkali pre-treatment. However, the 3% the bio-composites treated with 3% alkali was highest tensile and flexural strength than other.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.7
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• pp.770-775
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• 2006

Biofilters packed with various materials commonly show problems such as low performance and clogging in a long-term operation. Recently, a bioactive foam reactor(BFR) using surfactants has been suggested to ensure efficient and stable VOCs removal performance. This study was mainly conducted to investigate the feasibility of the BFR system using styrene as a model compound. An abiotic md a biotic tests were conducted to estimate a mass transfer coefficient($K_La$) and a specific substrate utilization coefficient(k) for the BFR, showing the rate of mass transfer was greater in the BFR than in other diffuser systems. A dynamic loading test also indicated that the performance of the BFR was stable under a shock loading condition. Furthermore, the maximum elimination capacity of the BFR was determined to be 109 $g/m^3/hr$ for styrene, which was much higher than those for biofilter systems generally reported in the literature. Overall, the experimental results suggest that the BFR be a potential alternative to the conventional packed-bed biofilters.

• Journal of Industrial Technology
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• v.27 no.A
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• pp.195-202
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• 2007

Milled Korean pine (Pinus densiflora) wood was used to evaluate its adsorption capacity of Cu(II) ions from aqueous solution by running a series of batch experiments. Prior to the tests, the milled woods were pretreated with 1N NaOH, 1N $HNO_3$, and distilled water, respectively, to examine the effect of pretreatment. Within the tested pH range between 3 and 6, copper adsorption efficiency of NaOH-treated wood(96~99%) was superior to the $HNO_3$-treated wood(19~31%) and distilled water-treated wood(18~35%). The efficiency of copper removal by wood enhanced with increasing solution pH and reached a maximum copper ion uptake at pH 5~6. Adsorption behavior of copper onto both raw and $HNO_3$-treated woods was mainly attributed to interaction with carboxylic acid group. For NaOH-treated wood, carboxylate ion produced by hydrolysis or saponification was a major functional group responsible for Cu sorption. NaOH treatment of wood changed the ester and carboxylic acid groups into carboxylate group, whereas $HNO_3$ treatment did not affect the production of functional groups which could bind copper. A pseudo second-order kinetic model fitted well for the sorption of copper ion onto NaOH-treated wood. A batch isotherm test using NaOH-treated wood showed that equilibrium sorption data were better represented by the Langmuir model than the Freundlich model.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.1 no.1
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• pp.19-33
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• 1997

The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorological processes. In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification process through observation is emphasized.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.5
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• pp.714-720
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• 2011

Ethanol was used as reducing agent to remove $NO_x$ exhaust from the stationary source. Pre-treatment with sulfuric acid over $Ag/Al_2O_3$ catalyst was dedicated to overcome the $SO_2$ poisoning effect. The $NO_x$ reduction experiment was performed under the simulated condition of power plant The increased surface area with higher CPSI devoted to increase de-$NO_x$ yield. De-$NO_x$ yield of the $NO_x$ exhaust containing 20 ppm of $SO_2$ increased after acid treatment with 0.7% $H_2SO_4$ over 4.0% $Ag/Al_2O_3$, where the increased dispersion of Ag found from the results of XRD and XPS was the dominant factor for the increased de-$NO_x$ yield. However, the reason for the decreased de-$NO_x$ yield with the acid treatment of higher concentration (1.0% and 2.0%) of $H_2SO_4$ was found to be due to the formation of $Ag_2SO_4$ crystallites found from XRD result. Acid-treated $Ag/Al_2O_3$ catalyst showed maximum de-$NO_x$ yield at higher temperature than non-treated $Ag/Al_2O_3$ catalyst did.

• Journal of Digital Contents Society
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• v.11 no.4
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• pp.553-559
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• 2010

By applying the various reformation techniques by using a circle raw data of after computed tomography image in the patient enforcing the spine screw fixation, this research tried to look into the various information including the exact location of the position of the screw spike and accuracy of an operation. In a clinical, by applying the or multi planar reformatting(MPR), that is the re-composition technique used mainly, maximum intensity projection (MIP), and volume rendering technique(VRT) and transformation removal from a register modifying VRT, video data were compared and were analyzed by the quantitative method and qualitative method. It is judged as the transformation volume rendering technique of the re-composition technique which is most useful in minimizing the artifact shadow by the exact location of the position of a screw and metal among the analysis and evaluation result computed tomography image reformation technique of the reformation image after the spine screw fixation.

• Membrane and Water Treatment
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• v.9 no.4
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• pp.255-262
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• 2018

This study attempted to evaluate the process of self-forming dynamic membrane formation on mesh filter in membrane bioreactor with a two-stage method of batch (agitation) and continues (aeration) stage at different sludge concentrations. Four concentrations of activated sludge including $6{\pm}0.4$, $8{\pm}0.5$, $10{\pm}0.3$, $14{\pm}0.3g/L$ were used to demonstrate the optimal concentration of sludge for treating municipal wastewater and reducing fouling in dynamic membrane bioreactor. The formation time and effluent turbidity were decreased in the batch stage when increasing the activated sludge concentration. The minimum values of formation time and effluent turbidity were 14 min and 43 NTU for the optimum mixed liqueur suspended solids of $8{\pm}0.5g/L$, respectively. To improve operational condition and fouling reduction in the aeration stage, critical fluxes were measured for all concentrations by flux-step method. With increasing the sludge concentration, the relevant critical fluxes reduced. The optimum subcritical flux of $30L/m^2/h$ was applied as operating flux in the second stage. The maximum COD removal efficiency of 98% was achieved by the concentration of $8{\pm}0.5g/L$. Compressibility index of self-forming dynamic membrane and transmembrane pressure trend remained somewhat constant until the optimal concentration of $8{\pm}0.5g/L$ and thereafter they increased steeply.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.3
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• pp.254-261
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• 2006

The effect of enhanced geometry (pore diameter, gap width) is investigated on the pool boiling of R-123/oil mixture for the enhanced tubes having pores with connecting gaps. Tubes with different pore diameters (and corresponding gap widths) are specially made. Significant heat transfer degradation by oil is observed for the present enhanced tubes. At 5% oil concentration, the degradation is 26 to 49% for $T_{sat}=4.4^{\circ}C$. The degradation increases 50 to 67% for $T_{sat}=26.7^{\circ}C$. The heat transfer degradation is significant even with small amount of oil (20 to 38% degradation at 1% oil concentration for $T_{sat}=4.4^{\circ}C$), probably due to the accumulation of oil in sub-tunnels. The pore size (or gap width) has a significant effect on the heat transfer degradation. The maximum degradation is observed for $d_p$ = 0.20 mm tube at $T_{sat}=4.4^{\circ}C$, and for $d_p$=0.23 mm tube at $T_{sat}=26.7^{\circ}C$. The minimum degradation is observed for $d_p$=0.27 mm tube for both saturation temperatures. It appears that the oil removal is facilitated for the larger pore diameter (along with larger gap) tube. The highest heat transfer coefficient with oil is obtained for $d_p$ =0.23 mm tube, which yielded the highest heat transfer coefficient for pure R-123. The heat transfer degradation increases as the heat flux decreases.