• Journal of Sensor Science and Technology
• /
• v.31 no.4
• /
• pp.238-243
• /
• 2022

In this study, a pyrene-core single molecule with amino (-NH₂) functional group material was hybridized using ZnO quantum dots (QDs). The suppressed performance of the 1-aminopyrene (1-PyNH₂) single molecule as an emissive layer (EML) in light-emitting diodes (LEDs) was exploited by adopting the ZnO@1-PyNH₂ core-shell structure. Unlike pristine 1-PyNH₂ molecules, the ZnO@1-PyNH₂ hybrid QDs formed energy proximity levels that enabled charge transfer. This result can be interpreted as an improvement in surface roughness. The uniform and homogeneous EML alleviates dark-spot degradation. Moreover, LEDs with the ITO/PEDOT:PSS/TFB/EML/TPBi/LiF/Al configuration were fabricated to evaluate the performance of two emissive materials, where pristine-1-PyNH₂ molecules and ZnO@1-PyNH₂ QDs were used as the EML materials to verify the improvement in electrical characteristics. The ZnO@1-PyNH₂ LEDs exhibited blue luminescence at 443 nm (FWHM = 49 nm), with a turn-on voltage of 4 V, maximum luminance of 1500 cd/m², maximum luminous efficiency of 0.66 cd/A, and power efficiency of 0.41 lm/W.

• Applied Chemistry for Engineering
• /
• v.24 no.1
• /
• pp.99-103
• /
• 2013

An emzymatic bioanode for a glucose/oxygen biofuel cell was prepared by the sequential coating of carbon nanotube (CNT), charge transfer complex (CTC) based on tetracyanoquinodimethane (TCNQ) and tetrathiafulvalene (TTF), glucose oxidase (GOx), and polyion complex (mixture of poly-L-lysine hydrobromide and poly (sodium 4-styrenesulfonate)) on a glassy carbon electrode. A biocathode was also prepared by the sequential coating of CNT, bilirubin oxidase (BOD), 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS), and polyion complex. The effect of CNT and CTC on the electrochemical performance was investigated. The biofuel cell exhibited a promising performance with maximum power densities of 3.6, 10.1, and $46.5{\mu}W/cm^2$ at 5, 20, and 200 mM of glucose concentration, respectively. The result indicates that the biofuel cell architecture prepared in this study can be used in the development of biofuel cells and biosensors.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.23 no.5
• /
• pp.545-552
• /
• 2015

The heat generation in PEMFC is proportional to the electrical power output. Therefore, when the fuel cell produced the maximum output, the maximum heat was generated. In order to maintain the performance of the fuel cell, thermal management is as important as pressure and humidity conditions of the reactive gas. In this study, considering the thermal management for the maximum output operation, the optimal cooling channel design specifications of bipolar plate are found for the highest cooling performance. In the current bipolar plate research, many studies focused on analyzing various factors individually but there is no more study on the interaction between design factors. In this study, the heat transfer was simulated by COMSOL Multiphysics with the main design factors which are designated shape, width and rib length. One of the experimental design methods, general full factorial design method, was used to analyze the main factor and interaction on average temperature and maximum temperature for the design specification of fuel cell bipolar plate. When analysis result shows that all of these three factors are highly important, it can confirm that the interaction occurs between the factors.

• Macromolecular Research
• /
• v.17 no.2
• /
• pp.91-98
• /
• 2009

Conjugated PPV-derived block copolymers containing 2-ethylhexyloxynaphthalene unit were synthesized and characterized in this study. The resulting polymers were soluble in common organic solvents and showed good thermal stabilities, The weight-average molecular weights ($M_w$) of the copolymers ranged from 246,000 to 475,000 with PDIs of $1.3{\sim}2.1$. The optical properties of these polymers, measured both in a chloroform solution and on a film, showed a maximum absorption at $405{\sim}476\;nm$ for Copolymers $I{\sim}VIII$. In the PL spectra, Copolymers $I{\sim}VIII$ showed maximum peaks at $510{\sim}566\;nm$. The HOMOs, LUMOs and band gaps of the PPV derivatives of Copolymers $I{\sim}VIII$ were $5.30{\sim}5.77$, $3.04{\sim}3.24$, and $2.5{\sim}2.2\;eV$, respectively, The multi-layered, light-emitting diodes of ITO/PEDOT/copolymers/LiF/Al exhibited turn-on voltages of $6{\sim}2.5\;V$ Copolymer VIII exhibited the maximum brightness of $3.657\;cd/m^2$. Particularly, Copolymer VII, with an identical composition of MEH-PPV and naphthalene-PPV, showed a maximum luminance efficiency and power efficiency of 2,63 cd/A and 1.06 lm/W, respectively.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
• /
• v.14 no.1
• /
• pp.56-69
• /
• 2021

In this paper, the PV system with a link to the commercial system needs some advantages like small capacity, high power factor, high reliability, low harmonic output, maximum power operation of solar cell, and low cost, etc. as well as the properties of inverter. To transfer the PV energy of photovoltaic power generation system to the system and load, it requires PCS in both directions. The purpose of this paper is to confirm the stable power supply through the load leveling by presenting the PCS considering ESS of photovoltaic power generation. In order to achieve these purpose, 5 step process of operation mode algorithm were used according to the solar insolation amount and load capacity and the controller for charging/ discharging control was designed. For bidirectional and effective energy transfer, the bidirectional converter and battery at DC-link stage were connected and the DC-link voltage and inverter output voltage through the interactive inverter were controlled. In order to prove the validity of the suggested system, the simulation using PSIM was performed and were reviewed for its validity and stability. The 3[kW] PCS was manufactured and its test was conducted in order to check this situation. In addition, the system characteristics suggested through the test results was verified and the PCS system presented in this study was excellent and stronger than that of before system.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2360-2365
• /
• 2007

A new microemitter (microcombustor) configuration for a micro thermophotovoltaic system in which thermal energy is directly converted into electrical energy through thermal radiation was investigated experimentally and computationally. The microemitter as a thermal heat source was designed for a few watt power-generating micro thermophotovoltaic system. In order to satisfy the primary requirements for designing the microemitter, i.e., stable burning in the small confinement and maximum heat transfer through the emitting walls but uniform distribution of temperature along the walls, the present microemitter is cylindrical with an annular-type shield for heat recirculation to apply for the excessive enthalpy concept. Results show that the heat recirculation substantially improves the performance of the microemitter: the observed and predicted thermal radiation from the microemitter walls indicated that heat generated in the microemitter is uniformly emitted.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1219-1224
• /
• 2004

The objective of this study is to propose an experimental calibration facility in which a heat flux sensor can be calibrated under conductive condition by using helium gas. The heat flux calibration facility was designed, simulated and manufactured for use in a high heat transfer condition. It delivers heat fluxes up to a maximum of 35 KW $m^{-2}$. A copper block heated electrically with 3.5 KW power is designed to produce uniform temperature up to 600 K across its face. High heat fluxes are provided between hot plate and cold plate by 1 mm height helium filled gap. A cold plate is maintained around 300 K through pool boiling using a refrigerant and water-cooled heat exchanger. A simulation was conducted to verify the design of the main test section. To verify the performance of calibration facility, a heat flux sensor was examined. The measured heat fluxes were compared to the calculated one.

• The Transactions of the Korean Institute of Electrical Engineers P
• /
• v.58 no.4
• /
• pp.557-562
• /
• 2009

Recently, researchers are developing a new, clean, renewable and sustainable energy to the industrial areas and the residential areas. Solar cell and fuel cell energy are presented in this paper. The paper shows the P-I and I-V characteristics of fuel cells which are connected in parallel and series. And the voltage drop of internal resistance of the fuel cell decreases with the increasing of the current of the fuel cell. A voltage drop at the internal resistance is increased according to the current, thus the terminal voltage is decreased. The internal resistance is calculated $0.3[\Omega]$ from maximum power transfer condition.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.4
• /
• pp.318-323
• /
• 2004

When a strong electric field is applied between a sharply curved electrode and a blunt surface, the corona may result in a gas movement in the electrode gap which is directed toward the blunt surface. That is called the corona wind. It enhances heat and mass transfer between the surface and the surrounding gas. Moreover such enhancement causes no noise or vibration, which can be applied in complex, isolated geometries, and allows simple control of surface temperatures. This paper examines the relationship between the corona wind and the relative humidity. The facility consists of high voltage power supply thin tungsten wire, plate electrode, multimeter, microammeter and flow meter. Gas velocity is a linear function of voltage, relative humidity and is proportional to the square root of the current. The maximum velocities for the positive and negative corona discharge are 1.9 m/s (2.74 CMM/m), 1.5 m/s(2.15 CMM/m), respectively.

• Proceedings of the IEEK Conference
• /
• 2001.06a
• /
• pp.417-420
• /
• 2001

In this paper, a transceiver using waveguide modules for 60 GHz band wireless LAN is implemented and analyzed. The characteristics of millimeter-wave transmitter are 0 dbm output power, 10.5 dB gain and 38 dBc spurious emition. The receiver's are 3.16 dB noise figure, 8.8 dB gain, -86dBm sensitivity. Maximum communication distance is more than loom. Intermediate frequency comply with IEEE 802.11b. The transfer of multimedia files is performed. The transceiver's data rate can vary with intermediate frequency bandwidth and the transceiver is designed more than 200 Mbps.