• Title/Summary/Keyword: Materials science and engineering

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Characterization of Sun Spangle Formation in the Transparent Baltic Amber by Heat Treatment (열처리를 통한 발틱 호박의 Sun spangle생성에 관한 연구)

  • Chung, Hyo-Jin;Seo, Jin-Gyo;Park, Jong-Wan
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.4
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    • pp.395-405
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    • 2009
  • The maturity of amber matrix and inclusion was studied to explore the effect of heat treatment on the formation of the sun spangle in the transparent Baltic amber from Gdansk, Poland. Optical microscope revealed two types of inclusions in the original amber samples. The inclusions in the amber which had sun spangle were dramatically expanded by the heat treatment, comparing to those without sun spangle which contains fissure and shows different refractive index. The amber sample which didn't show sun spangle after the heat treatment showed a strong carbon related peak in TOF-SIMS spectra and weak oxygen related peak. it means that the maturity of this amber sample is comparatively higher than the one with spangle. The two amber samples show similar IR spectra before the heat treatment. However, the amber which had sun spangle exhibited an additional 1019 $cm^{-1}$ absorption peak and a more intense 887 $cm^{-1}$ peak. The different chemical compositions between the two types of amber is believed to be due to the different absorption spectra between 1000~600 $cm^{-1}$. According to the study of DSC analysis, the two samples show different DSC profiles. Although they have the same geological origin, their geological ages are different and have different chemical compositions. Thus, they exhibited different behavior after the heat treatment. The formation of sun spangle seemed to depend on the difference in the heat expansion rate of amber matrix with different maturity and chemical compositions.

Transparent Hydrophobic Anti-Reflection Coating with SiO2\TiO2 Thin Layers (SiO2\TiO2 박막에 의한 투명 발수 반사방지 코팅)

  • Noh, Yeoung-Ah;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.1-6
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    • 2017
  • Functional coatings, such as anti-reflection and self-cleaning, are frequently applied to cover glass for photovoltaic applications. Anti-reflection coatings made of mesoporous silica film have been shown to enhance the light transmittance. $TiO_2$ photocatalyst films are often applied as a self-cleaning coating. In this study, transparent hydrophobic anti-reflective and self-cleaning coatings made of $SiO_2/TiO_2$ thin layers were fabricated on a slide glass substrate by the sol-gel and dip-coating processes. The morphology of the functional coatings was characterized by field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). The optical properties of the functional coatings were investigated using an UV-visible spectrophotometer. Contact angle measurements were performed to confirm the hydrophobicity of the surface. The results showed that the $TiO_2$ films exhibit a high transmittance comparable to that of the bare slide glass substrate. The $TiO_2$ nanoparticles make the film more reflective and lead to a lower transmittance. However, the transmittance of the $SiO_2/TiO_2$ thin layers is 93.5% at 550 nm with a contact angle of $110^{\circ}$, which is higher than that of the bare slide glass (2.0%).

High-Resolution MRI Study on Mouse Brain Using Micro-Imaging (초고해상도 미세영상 기법을 이용한 Mouse 뇌의 자기공명영상 연구)

  • Han, Doug-Young;Yoon, Moon-Hyun;Choe, Bo-Young
    • Investigative Magnetic Resonance Imaging
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    • v.12 no.2
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    • pp.142-147
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    • 2008
  • Purpose : By using the micro-imaging unit modified from NMR spectrometer, the high resolution MRI protocols of finer than 100 micron in 5 minutes, is sought for mouse, which plays a central role in animal studies Materials and Methods : C57BL/6 mouse, lighter than 50 gram, is used for the experiments. The superconducting magnet is vertical type with 89 mm inner diameter at 4.9 Tesla. The diameter of rf-coil is 30 mm. Mostly used techniques are the fast spin echo and the gradient echo pulse sequence. Results : For 2D images, proton density and T2 weighted images are obtained and their optimum experimental variables were sought. Minute structure of mouse brain can be recognized and 3D brain image is also obtained additionally. 3D image will be useful particularly for the dynamic contrast study using various contrast agents. Conclusion : Like the case of human and other small animals, the high resolution of mouse brain is enough to recognize the minute structure of it. Recently, similar studies are reported domestically, but it seems only a beginning stage. Due to easiness of breeding/control, mouse MRI study will soon play a vital part in brain study.

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CFD Analysis on the Flow Uniformity of a $CO_2$ Enrichment System (CFD를 이용한 온실 $CO_2$ 시비 시스템의 유량 균일성 해석)

  • Yim, Kyungjin;Kim, Hongjip;Lee, Sangmin;Park, Kyoung-Sub
    • Journal of Bio-Environment Control
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    • v.22 no.2
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    • pp.123-130
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    • 2013
  • $CO_2$ enrichment systems have been recently used to shorten the growth period of plants and the improvement of harvest and its quality. To accomplish these goals, manifold should be designed to supply the same amount of $CO_2$. In this study, CFD approach has been used to understand the effects of geometric parameters, such as tube and hole diameters. An optimized geometry has been derived through pipe and tube part, respectively. As a result, the deviation of flow rate less than 0.1 g/s was expected at all holes of the $CO_2$ enrichment system.

Comparison of high molecular coating type dentine hypersensitivity desensitizers (고분자 기반 코팅형 상아질 지각 과민 처치제의 효과에 대한 비교 연구)

  • Roh, Young-Hoon;Lee, Joo-Yeon;Park, Hyun-Jung;Choi, Cha-Nam;Park, Yoon-Jeong;Koo, Ki-Tae;Kim, Tae-Il;Seol, Yang-Jo;Lee, Yong-Moo;Ku, Young;Rhyu, In-Chul;Chung, Chong-Pyoung
    • The Journal of the Korean dental association
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    • v.46 no.11
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    • pp.683-688
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    • 2008
  • Purpose : The aim of this study was to evaluate the clinical efficacy of two commercially available desensitizing agents over 3 weeks on patients with dentin hypersensitivity. Materials and Methods : An oxalate-based solution, Sensblok (NIBEC Inc. Seoul, Korea) & Superseal (Pheonix Inc. Michigan, USA), and a distilled water placebo were compared in a clinical setting. Seven volunteers exhibiting three or more teeth that were sensitive to tactile & air were enrolled in the study (35 teeth total). A visual analog scale (VAS) was used for recording each patient s level of sensitivity to tactile & air stimuli. A Florida probe was rubbed across the exposed dentin three times with a constant pressure 20 grams to measure the tactile stimulus. The air stimulus was generated by dental unit air syringe for 1-second blast from 1/2 inch distance. The desensitizing agents were applied according manufacture s guideline. VAS scores were recorded at baseline, 1 minute after treatment, at 1 week, 2weeks, 3weeks. VAS score were analyzed using a repeated measures ANOVA ( =0.05). Results : The Sensblok, Superseal, and distilled water placebo all decreased dentin sensitivity. A statistically significant difference existed between Sensblok and placebo when tactile stimulus was applied (P<0.05), but no significant difference was found among other desensitizing agents and tactile and air stimuli.

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Performance Analysis of Pressure-retarded Osmosis Power Using Biomimetic Aquaporin Membrane (생체모방형 아쿠아포린 분리막을 이용한 압력지연삼투 발전 성능분석)

  • Choi, Wook;Bae, Harim;Lee, Hyung-Keun;Lee, Jonghwi;Kim, Jong Hak;Park, Chul Ho
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.317-322
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    • 2015
  • Salinity gradient power is a system which sustainably generates electricity for 24 hrs, if the system is constructed at a certain place where both seawater and river water are consistently pumped. Since power is critically determined by the water flux and the salt rejection, a membrane of water-semipermeable aquaporin protein in cell membranes was studied for pressure-retarded osmosis. NaCl was used as a salt, and $NaNO_3$ was used as a candidate to check the ion selectivity. The water flux of biomimetic aquaporin membranes was negligible at a concentration below 2M. Also, there is no remarkable dependence of water flux and ion selectivity on concentrations higher than 3M. Therefore, the biomimetic aquaporin membrane could not be applied into pressure-retarded osmosis; however, if a membrane could overcome the current limitations, the properties shown by natural cells could be accomplished.

Study on the Recovery of Metallic Aluminum in Black Dross generated from the Used Beverage Cans (UBC) Recycling Process with Crushing Mechanism (파쇄 기구에 따른 알루미늄 캔 재자원화 공정 중 발생한 블랙 드로스 내 알루미늄 회수에 관한 연구)

  • Han, Chulwoong;Son, Seong Ho;Ahn, Byung-Doo;Kim, Dae-Guen;Lee, Man Seung;Kim, Yong Hwan
    • Resources Recycling
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    • v.26 no.4
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    • pp.71-78
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    • 2017
  • This study investigated the recovery of metallic aluminium in the black dross generated from used beverage can recycling process with crushing mechanism such as compression and impact. The as-received Al black dross had a spherical shape, and its size was about 10~40 mm. Also, The X-ray diffraction pattern showed that the main contents of black dross are composed of halite (NaCl), sylvite (KCl), spinel ($MgAl_2O_4$) and corundum ($Al_2O_3$). A metallic aluminium recovery test was performed using jaw crusher and hammer mill having different crushing mechanism. It was analysed that Jaw crushing process can separate into metallic aluminium and non metallic constituents. However, hammer milling process shows significant difference on the separation results. It was found that jaw crushing process was effective for recovery of metallic aluminium in the black dross than that of hammer milling process.

A Study on Tensile Property due to Stacking Structure by Fiber Design of CT Specimen Composed of CFRP (CFRP로 구성된 CT시험편의 섬유설계에 의한 적층구조에 따른 인장 특성 연구)

  • Hwang, Gue-Wan;Cho, Jae-Ung
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.11
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    • pp.447-455
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    • 2017
  • At the modern industry, the composite material has been widely used. Particularly, the material of carbon fiber reinforced plastic hardened with resin on the basis of fiber is excellent. As the specific strength and rigidity are also superior, it receives attention as the light material. Among these materials, the carbon fiber reinforced plastic using carbon fiber has the superior mechanical property different from another fiber. So, it is utilized in vehicle and airplane at which high strength and light weight are needed at the same time. In this paper, the tensile property due to the fiber design is investigated through the analysis study with CT specimen composed of carbon plastic reinforced plastic. At the stress analysis of CFRP composite material with hole, the fracture trend at the tensile environment is examined. Also, it is shown that the lowest stress value happens and the deformation energy of the pre-crack becomes lowest at the analysis model composed of the stacking angle of 60° through the result due to the stacking angle. On the basis of this study result, it is thought to apply the foundation data to anticipate the fracture configuration at the structure applied with the practical experiment.

A Study of Factors Influencing on Digital Textbook Satisfaction of Elementary School (초등학생의 디지털교과서 활용 만족도에 영향을 미치는 변인 분석)

  • Song, Moonhyeon;Kim, Jamee;Kim, Hyeoncheol
    • Journal of The Korean Association of Information Education
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    • v.19 no.3
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    • pp.287-298
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    • 2015
  • Digital textbook is noted as a new education materials to realize a new education paradigm with changes in digitalized society. The purposes of this study is investigation of key factors on digital textbook satisfaction by selecting of the three factors(domestic environment factor, teachers factor, school environment factor), analysis of awareness of effect factors on digital textbook satisfaction, and verification for each effect factors' influence on elementary school. 201 elementary school students, 201 their parents, and 12 teachers in Chung-nam were surveyed and factors which influenced on digital textbook satisfaction were analyzed. According to the results, firstly, there was a statistical significant difference in domestic internet environment, device owned environments, the utilization of the internet for the purpose of education and using time, device type of teachers, lesson time of digital textbook used in class and time ratio. Secondly, multiple regression analysis was conducted to find out the influence on digital textbook, the Awareness of parents about digital textbook, The lesson time using digital textbook by teacher, The utilization of the internet for the purpose of education affected satisfactions significantly in the order. This study has significant implications about which we have provided the effort needed to use digital textbook.

Nitrided LATP Solid Electrolyte for Enhanced Chemical Stability in Alkaline Media (질화 처리된 LATP 고체전해질의 알칼라인 용액내에서의 내화학특성 개선 연구)

  • Seong, Ji Young;Lee, Jong-Won;Im, Won Bin;Kim, Sung-Soo;Jung, Kyu-Nam
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.45-50
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    • 2015
  • In the present work, to increase the chemical stability of the lithium-ion-conducting ceramic electrolyte ($Li_{1+x+y}Al_xTi_{2-x}Si_yP_{3-y}O_{12}$, LATP) in the strong alkaline solution, the surface of LATP was modified by the nitridation process. The surface and structural properties of nitride LATP solid electrolyte were characterized by X-ray diffraction, X-ray photoelectron spectrometer and scanning electron microscopy and ac-impedance spectroscopy, which were correlated to the chemical stability and electrochemical performance of LATP. The nitrided LATP immersed in the alkaline solution for 30 days exhibits the enhanced chemical stability than the pristine LATP. Moreover, a rechargeable hybrid Li-air battery constructed with the nitrided LATP solid electrolyte shows considerably reduced discharge-charge voltage gaps (enhanced the round-trip efficiency) in comparison to the cell constructed with pristine LATP, which indicate that the surface nitridation process can be the efficient way to improve the chemical stability of solid electrolyte in alkaline media.