• Title/Summary/Keyword: Materials property

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A study on the Damping Properties of NR Vulcanizates. (천연(天然)고무의 Damping Property에 관(關)한 연구(硏究))

  • Choi, Jae-Woon;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.20 no.3
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    • pp.189-204
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    • 1985
  • The purpose of this study is to examine the dynamic properties, especially the damping and fatigue properites, of NR vulcanizates and to find out the vulcanizate which can be used as damping materials in industry. The results of this study can be summarized as follows: 1. In the ODR test, the S-2 vulcanizate was the fastest one in terms of having reached to optimum cure times($t_{90}$) and, with the same formula, when 50phr of HAF carbon black loaded, the shortest optimum cure times has shown. 2. The S - 2 vulcanizate was the best than the others in the physical properties. In aging properties, however, the E - 1 vulcanizate appeared to be better than the other vulcanizates. 3. The results of the RDS test for the NR vulcanization system under the condition of 0.1% strain amplitude and 1 Hz frequency showed no connection between Tg and the the nature of the crosslinking system, but 50phr loading of HAF carbon black increased Tg. The damping values of vulcanizates in the elastic region showed a strong relations the damping values and the crosslinking system. The S - 2 vulcanizate with higher crosslink density had lower damping values than other vulcanizates, and furthermore, the SH - 2 vulcanizates with 50phr loading of HAF carbon black increased the damping values. 4. The Goodrich Flexometer test showed that the heat buildup for the gum NR vulcanizates was less than for those which contained 50phr of HAF carbon black. In particular, the fatigue life of the vulcanizate with lower damping values appeared to be longer than that of the vulcanizates with higher damping values. In the fatigue test, the increasment of the loading or the temperature, applied to the vulcanizates, appeared to be shorten their fatigue life.

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Interfacial Charge Transport Anisotropy of Organic Field-Effect Transistors Based on Pentacene Derivative Single Crystals with Cofacial Molecular Stack (코페이셜 적층 구조를 가진 펜타센 유도체 단결정기반 유기트랜지스터의 계면 전하이동 이방성에 관한 연구)

  • Choi, Hyun Ho
    • Journal of Adhesion and Interface
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    • v.20 no.4
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    • pp.155-161
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    • 2019
  • Understanding charge transport anisotropy at the interface of conjugated nanostructures basically gives insight into structure-property relationship in organic field-effect transistors (OFET). Here, the anisotropy of the field-effect mobility at the interface between 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS-pentacene) single crystal with cofacial molecular stacks in a-b basal plane and SiO gate dielectric was investigated. A solvent exchange method has been used in order for TIPS-pentacene single crystals to be grown on the surface of SiO2 thin film, corresponding to the charge accumulation at the interface in OFET structure. In TIPS-pentacene OFET, the anisotropy ratio between the highest and lowest measured mobility is revealed to be 5.2. By analyzing the interaction of a conjugated unit in TIPS-pentacene with the nearest neighbor units, the mobility anisotropy can be rationalized by differences in HOMO-level coupling and hopping routes of charge carriers. The theoretical estimation of anisotropy based on HOMO-level coupling is also consistent with the experimental result.

Effect of carbon and boron addition on sintering behavior and mechanical properties of hot-pressed SiC (카본 및 보론 첨가가 탄화규소 열간 가압 소결거동 및 기계적 특성에 미치는 영향)

  • Ahn, Jong-Pil;Chae, Jae-Hong;Kim, Kyoung-Hun;Park, Joo-Seok;Kim, Dae-Gean;Kim, Hyoung-Sun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.1
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    • pp.15-21
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    • 2008
  • SiC has an excellent resistance to oxidation and corrosion, high temperature strength and good thermal conductivity. However, it is difficult to density because of its highly covalent bonding characteristics. Hot-press sintering process was applied to fabricate fully densified SiC ceramics with carbon and boron addition as a sintering additive. The addition of carbon improved the mechanical properties of SiC because it could induce a fine and homogeneous microstructure by the suppression of abnormal growth of SiC grain. Also, the addition of carbon could control the phase transformation of SiC. The phase transformation of 6H to 4H increased with sintering temperature but the addition of carbon decreased that kind of phase transformation.

Effect of the additive gas on the bonding structure and mechanical properties of the DLC films deposited by RF-PECVD (RF-PECVD법에 의해 증착된 DLC 박막의 결합구조와 기계적 특성에 관한 보조가스의 영향)

  • Choi, Bong-Geun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.145-152
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    • 2015
  • In this work, we were investigated the effect of the additive gases on the relationship between bonding structure and mechanical properties of the deposited films when the DLC films were deposited on Si-wafer by the rf-PECVD method with the addition of small amounts of carbon dioxide and nitrogen to the mixture gas of methane and hydrogen. The deposition rate of the films increased as the rf-power increased, while it decreased with increasing the amount of additive gases. Also, as the carbon dioxide gas increased, the hydrogen content in the films decreased but the $sp^3/sp^2$ ratio of the films increased. In case of nitrogen gas, the hydrogen content decreased, however the $sp^3/sp^2$ ratio and nitrogen gas flow rate did not show a specific tendency.

Interfacial Durability and Electrical Properties of CNT or ITO/PVDF Nanocomposites for Self-Sensor and Micro Actuator (자체-센서와 미세 작동기를 위한 CNT/PVDF 및 ITO/PVDF 나노복합재료의 전기적 및 계면 내구성 비교 평가)

  • Gu, Ga-Young;Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.24 no.6
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    • pp.12-17
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    • 2011
  • Interfacial durability and electrical properties of CNT or ITO coated PVDF nanocomposites were investigated for self-sensor and micro actuator applications. Electrical resistivity of nanocomposites for the durability on interfacial adhesion was measured using four points method via fatigue test under cyclic loading. CNT/PVDF nanocomposite exhibited lower electrical resistivity and good self-sensing performance due to inherent electrical property. Durability on the interfacial adhesion was good for both CNT and ITO/PVDF nanocomposites. With static contact angle measurement, surface energy, work of adhesion, and spreading coefficient between either CNT or ITO and PVDF were obtained to verify the correlation with interfacial adhesion durability. The optimum actuation performance of CNT or ITO coated PVDF specimen was measured by the displacement change using laser displacement sensor with changing frequency and voltage. The displacement of actuated nanocomposites decreased with increasing frequency, whereas the displacement increased with voltage increment. Due to nanostructure and inherent electrical properties, CNT/PVDF nanocomposite exhibited better performance as self-sensor and micro actuator than ITO/PVDF case.

Characterizations on the Thermal Insulation of SiC Coated Carbon-Carbon Composites (탄화규소로 코팅된 탄소-탄소 복합재료의 단열 특성)

  • Seo, Hyoung-IL;Lim, Byung-Joo;Sihn, Ihn Cheol;Bae, Soobin;Lee, Hyung-Ik;Choi, Kyoon;Lee, Kee Sung
    • Composites Research
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    • v.33 no.3
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    • pp.101-107
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    • 2020
  • This study investigates the characterization on the thermal insulation properties of silicon carbide coating on the Cf-C composites. The silicon carbide coatings by chemical vapor deposition on the C/C composites are prepared to evaluate thermal resistance. Firstly, we perform the basic insulation test by thermal shock at 1350℃ in air on the C/C composite and SiC-coated C/C composite. We also performed the burner tests on the surface of the composites at high temperatures such as 1700 and 2000℃, and the weight change after burner tests are measured. The damages on the surface of C/C composite and SiC-coated composite are observed. As a result, the SiC coating is beneficial to protect the C/C composite from high temperature even though damages such as defoliation, crack and voids are observed during burner test at 2000℃.

Thermal Resistance Characteristics of the Backfill Material with Bottom Ash (저회 되메움재의 열저항 특성)

  • Jung, Hyuksang;Cho, Sam-Deok;Kim, Ju-Hyong;Park, Jongsik;Kong, Jin-Young
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.6
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    • pp.5-12
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    • 2016
  • This paper deals with the result of thermal resistance test with backfill materials as bottom ash by using backfill material. Bottom ash, one of coal ashes, can be reused to replace sand because of its similar engineering properties. But without considering the thermal property, the abuse of bottom ash resulted in damage for existing structures. To investigate the thermal conductivity of bottom ash, laboratory tests for thermal resistance of that were carried out in this study. Thermal properties of bottom ash was compared with those of in-situ soil, sand, backfill material which can be applied as filling material. The tests were classified by water contents defined as the major influence factor. The beneficial use method of bottom ash was suggested as backfilling material.

Evaluation of DNA Damage Using Microwave Dielectric Absorption Spectroscopy

  • Hirayama, Makoto;Matuo, Youichirou;Sunagawa, Takeyoshi;Izumi, Yoshinobu
    • Journal of Radiation Protection and Research
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    • v.41 no.4
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    • pp.339-343
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    • 2016
  • Background: Evaluation of deoxyribonucleic acid (DNA)-strand break is important to elucidate the biological effect of ionizing radiations. The conventional methods for DNA-strand break evaluation have been achieved by Agarose gel electrophoresis and others using an electrical property of DNAs. Such kinds of DNA-strand break evaluation systems can estimate DNA-strand break, according to a molecular weight of DNAs. However, the conventional method needs pretreatment of the sample and a relatively long period for analysis. They do not have enough sensitivity to detect the strand break products in the low-dose region. Materials and Methods: The sample is water, methanol and plasmid DNA solution. The plasmid DNA pUC118 was multiplied by using Escherichia coli JM109 competent cells. The resonance frequency and Q-value were measured by means of microwave dielectric absorption spectroscopy. When a sample is located at a center of the electric field, resonance curve of the frequency that existed as a standing wave is disturbed. As a result, the perturbation effect to perform a resonance with different frequency is adopted. Results and Discussion: The resonance frequency shifted to higher frequency with an increase in a concentration of methanol as the model of the biological material, and the Q-value decreased. The absorption peak in microwave power spectrum of the double-strand break plasmid DNA shifted from the non-damaged plasmid DNA. Moreover, the sharpness of absorption peak changed resulting in change in Q-value. We confirmed that a resonance frequency shifted to higher frequency with an increase in concentration of the plasmid DNA. Conclusion: We developed a new technique for an evaluation of DNA damage. In this paper, we report the evaluation method of DNA damage using microwave dielectric absorption spectroscopy.

An Experimental Study on Material Property of Parking Zone Flooring Occupancy Surface Finishing Used to Environment-friendly.High-liquidity Ceramic Resin Mortar (친환경.고유동 세라믹 수지 모르타르를 이용한 주차장 바닥용 표면 마감의 재료적 특성에 관한 실험적 연구)

  • Lee, Sun-Gyu;Moon, You-Seok;Lee, Hyung-Jun;Lee, Wan-Hwi;Oh, Sang-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.829-832
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    • 2008
  • Since the early 1980s, the building is dramatically higher increases. Therefore, the shortage of parking spaces as a social problem has been pointed out. The parking lot utilization of underground space is increasing by like this problem solving countermeasure. However, Most of the organic material is used for construction in the parking lot on the floor. The existing parking zone flooring occupancy surface finishing is harmful gases and environmental hormones cause of the worker. The study on the safety of the worker consider using environment-friendly?high-liquidity ceramic resin mortar materials to evaluate the characteristics and physical properties.

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Environment Deterioration Characteristics of Polypropylene / Glass Fiber Composites under Moisture Absorption Environment (흡습 환경 하의 폴리프로필렌/유리 섬유 강화 복합재료의 환경 열화 특성)

  • Kim, Yun-Hae;Park, Chang-Wook;Jung, Gyung-Seok;Shin, Seok-Jin
    • Journal of Ocean Engineering and Technology
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    • v.30 no.6
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    • pp.520-525
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    • 2016
  • In this study, a mixture of polypropylene fibers and glass fibers were used to weave polypropylene/glass fiber-reinforced composite panels with characteristics such as highly elongated short fibers, high ductility, anti-fouling, and hydrophobicity as a result of a directional property. Mechanical and environmental tests were carried out with specimens fabricated with this composite panel, and its applicability to shipbuilding and ocean leisure industries was evaluated through a comparison with existing glass fiber-reinforced composite materials. The results of this experiment verified the excellence of the polypropylene/glass-mixed woven fiber-reinforced composite material compared to the existing glass fiber-reinforced composite material. However, the forming process needs to be changed to improve the weak interfacial bonding, and the properties of the composite material itself could be improved through mixed weaving with other fibers after development. Maximizing of the advantages of the polypropylene fibers and overcoming their shortcomings will improve their applicability to the shipbuilding, ocean leisure, and other industries, and increase the value of polypropylene fibers in the composite material market.