• Title/Summary/Keyword: Materials property

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Study on Anti-Washout Properties and Shear-Thickening Behaviors of Surfactant Added Cement Grouts (계면활성제 혼화제를 첨가한 시멘트 그라우트의 수중 불분리 특성 발현과 점도 증가 효과 연구)

  • Jang, In-Kyu;Seo, Seung-Ree;Park, Seung-Kyu
    • Applied Chemistry for Engineering
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    • v.23 no.5
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    • pp.480-484
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    • 2012
  • Concrete, the mixture of cement, sand, gravel and water, is a suspension substance extensively used to construct building materials. When a concrete mortar is applied to the underwater construction, the rheology of concrete is of great importance to its flow performance, placement, anti-washout and consolidation. In this research, the anti-washout and rheological properties of concrete have been investigated with concrete admixtures prepared by adding anionic surfactants, cationic surfactants, and polymeric thickeners. The concrete mortar formulated by pseudo-polymeric systems with the electrostatic association of anionic and cationic surfactants, showed high viscosities and suitable anti-washout properties, but poor pumpabilities. The addition of poly methyl vinyl ether to the mixed surfactant system exhibits synergistic effects by improving the concrete mortar properties of the concrete mortar such as fluidity, visco-elastic property, self-leveling, and anti-washout.

Physical Property Change of the Gapless Semiconductor $PbPdO_2$ Thin Film by Ex-situ Annealing

  • Choo, S.M.;Park, S.M.;Lee, K.J.;Jo, Y.H.;Park, G.S.;Jung, M.H.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.371-372
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    • 2012
  • We have studied lead-based gapless semiconductors, $PbPdO_2$, which is very sensitive to external parameters such as temperature, pressure, electric field, etc[1]. We have fabricated pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films using the pulsed laser deposition. Because of the volatile element of Pb, it is very difficult to grow the films. Note that in case of $MgB_2$, Mg is also volatile element. So in order to enhance the quality of $MgB_2$, some experiments are carried out in annealing with Mg-rich atmosphere [2]. This annealing process with volatile element plays an important role in making smooth surface. Thus, we applied such process to our studies of $PbPdO_2$ thin films. As a result, we found the optimal condition of ex-situ annealing temperature ${\sim}650^{\circ}C$ and time ~12 hrs. The ex-situ annealing brought the extreme change of surface morphology of thin films. After ex-situ annealing with PbO-rich atmosphere, the grain size of thin film was almost 100 times enlarged for all the thin films and also the PbO impurity phase was smeared out. And from X-ray diffraction measurements, we determined highly crystallized phases after annealing. So, we measured electrical and magnetic properties. Because of reduced grain boundary, the resistivity of ex-situ annealed samples changed smaller than no ex-situ sample. And the carrier densities of thin films were decreased with ex-situ annealing time. In this case, oxygen vacancies were removed by ex-situ annealing. Furthermore, we will discuss the transport and magnetic properties in pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films in detail.

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Reaction Path Modeling of Granitic Cultural Properties and Its Implication for Preservation (화강암질 석조문화재의 풍화반응경로 특성과 보존에 대한 제언)

  • Park Maeng-Eon;Sung Kyu-Youl
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.83-92
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    • 2005
  • Dissolution rate of minerals may differ from climates configuration, but weathering rate of feldspars is generally proved to be relatively higher The result of geochemical reaction modeling indicates the acid water of pH 4.5 excluding any other variables, was 2.3 times higher than that in ordinary rain of pH 5.7. This result proved that pH is very important factor in preservation of granite cultural properties. To prevent the weathering of stone cultural properties, weathering characteristics of stones should be studied first and constitution of dry environments, using water repellent or oil coating, isolating water which cause chemical weathering reaction like hydration and oxidization should be considered. Considering the long-term reactions between granite and rain, selection of materials, which can bring neutralization and non-oxidization conditions, are very important in using cleaning agents and biological controls.

Evaluation of Probabilistic Fracture Mechanics for Reactor Pressure Vessel under SBLOCA (소규모 냉각재 상실사고하의 원자로 압력용기에 대한 확률론적 파괴역학 평가)

  • Kim, Jong Wook;Lee, Gyu Mahn;Kim, Tae Wan
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.4 no.2
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    • pp.13-19
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    • 2008
  • In order to predict a remaining life of a plant, it is necessary to select the components that are critical to the plant life. The remaining life of those components shall be evaluated by considering the aging effect of materials used as well as numerous factors. However, when evaluating reliability of nuclear structural components, some problems are quite formidable because of lack of information such as operating history, material property change and uncertainty in damage models. Accordingly, if structural integrity and safety are evaluated by the deterministic fracture mechanics approach, it is expected that the results obtained are too conservative to perform a rational evaluation of plant life. The probabilistic fracture mechanics approaches are regarded as appropriate methods to rationally evaluate the plant life since they can consider various uncertainties such as sizes and shapes of cracks and degradation of material strength due to the aging effects. The objective of this study is to evaluate the structural integrity for a reactor pressure vessel under the small break loss of coolant accident by applying the deterministic and probabilistic fracture mechanics. The deterministic fracture mechanics analysis was performed using the three dimensional finite element model. The probabilistic integrity analysis was based on the Monte Carlo simulation. The selected random variables are the neutron fluence on the vessel inside surface, the content of copper, nickel, and phosphorus in the reactor pressure vessel material, and initial RTNDT.

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Study on the Mechanical Properties of Polyketone Fiber according to Coating Process for Technical Textile (산업용 폴리케톤 섬유의 코팅 가공에 따른 기계적 물성에 관한 연구)

  • Kim, Sang Yong;Jeon, Jae Woo;Kwak, Dong Sub;Lee, Won;Lee, Deuk Jin;Whang, Sun Dong;Do, Sung Jun
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.334-339
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    • 2015
  • Polyketone fiber, a newly developed high strength fiber, has a tenacity and modulus similar to the paramid fiber, and can be used for reinforcing mechanical rubber goods(MRG), such as tires, hoses, and technical textiles. In addition, aliphatic polyketone, which has excellent strength, modulus, chemical stability and reasonable price, is being developed only in South Korea. It will be expected for replacement of super fiber such as aramids and increasing the technical textile market share. This paper surveys the mechanical properties of polyketone fiber yarn for technical textiles. For this purpose, two kinds of yarns are prepared, mechanical properties of coated and uncoated polyketone yarns such as tensile strength, elongation and modulus were examined before and after weather resistance test(temperature $60^{\circ}C$, humidity 60%, amount of power $0.67w/m^2$). The differences of mechanical properties between uncoated and coated yarns for high functional technical textiles and composite materials are estimated through this study.

Hydrophilic Finish of Polyester Fabrics using Sericin Finishing Agents (세리신 가공제에 의한 폴리에스터 직물의 친수화 가공)

  • Park, In-Woo;Hwang, Gye-Soon;Hong, Young-Ki;Bae, Han-Soo;Bae, Kie-Seo
    • Textile Coloration and Finishing
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    • v.21 no.1
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    • pp.38-45
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    • 2009
  • First of all, the properties imparted to PET fabrics are resistance to and recovery from creasing or wrinkling when wet or dry; high resistance to stretch in the filament yarns but not in the staple; high abrasion resistance; good texture and appearance; resistance to heat ageing; good chemical resistance and good resistance, behind glass, to sunlight. But, the low moisture regain of PET fabric conduces to static troubles in textile processing. Furthermore, garments made from PET may, during wear, develop electric charges which attract to the fabric particles of soil(dirt, swarf, dust) flying in the air, so that the cuffs of shirts, for example, become soiled quickly and are not easily laundered clean. The sericin constitutes 25$\sim$30% of silk protein and surrounds the fibroin fiber with sticky layer that supports the formation of a cocoon. The useful biochemical properties of sericin protein are oxidation resistant, antibacterial, UV resistant, hydrophilic property, and good affinity with hydrophobic material. These properties can be used as an improving reagent or a coating agent for natural and synthetic fibers, fabrics, and other intermediate products. The sericin is also applied to cross-link, and can be blended with other materials. In this study, we modified the surface of PET fabric by mixture of sericin finishing agent; sericin, polyuretane binder and 1,2,3,4-butanetetracarboxylic acid (BTCA) cross-link agent. Also, we investigated the finshing effect; moisture regain, stiffness, handle, drape and electrostatic. The moisture regain of PET fabric treated with sericin finishing agent was higher than that of untreated PET fabric. As a result of evaluating influence about handle of PET fabrics treated with sericin finishing agent, it was confirmed that the sericin finishing agent could be use as a linen like finishing agent.

A Study on the Geotechnical Property caused by Contact Volume between Weathered Soils and Moisture Sensor for Application of Field Monitoring (현장 모니터링 적용을 위한 풍화토와 함수비센서의 접촉체적에 따른 지반물성 연구)

  • Kim, Man-Il;Chae, Byung-Gon
    • The Journal of Engineering Geology
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    • v.18 no.3
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    • pp.311-319
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    • 2008
  • Evaluation of an amplitude domain reflectometry (ADR) type soil moisture sensor as ThetaProbe ML2x using the response of frequency impedance was performed in a variety of soil porous media such as Jumunjin standard sand, weathered granite soil at Sangju area, and weathered gneiss soil at Jangsu area. The tested soils were classified with a dried condition and a wetted condition for comparing with soil volumetric water content under different installed depths of the measurement sensor. In the results the part of measurement rod including one signal rod and three shield rod 6cm in length was found to decrease the variation of measurement output voltage with insert 5cm over into the soil porous media. The measurement output voltage was verified to more stable output voltage under weathered granite soils and weathered gneiss soils contained the fine grain materials such as clay and silt minerals than the gradual grain material like as the standard sands. Therefore, measurement values by soil moisture sensor can be offered the more stable values when an contact volume between soil porous media and measurement sensor increase.

The Development of Textile Design by Using Prototype of Hwasun Unjusa (화순 운주사의 문화원형을 활용한 텍스타일 디자인개발)

  • Jung, Hyung-Ho;Bae, Soo-Jeong
    • Journal of Fashion Business
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    • v.13 no.2
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    • pp.100-114
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    • 2009
  • In Honam province, the cultural prototype are largely unknown to the people, also the research on this subject are scarce, the artistic excellence, somewhat under evaluated, both in our country and internationally. It is imperative that we develop the modern design using this prototype. thereby apply it to many areas of cultural products. We should extend the dimension not only to the local festival but also to the mass production resulting in the commercial gains. The Unjusa Buddha festival for promoting the public relation would be greatly benefited by using the concept of the temple, the local prototype, by which we expect to create a ingenious textile design pattern, coinciding with the main purpose of this study. The ancient material around Unjusa come to be the subject of our textile design by way of selecting the most remarkable ones of heritage among the materials of Unjusa. In the long run, the harmonious contrast of both traditional and modern image were sought in this study. Designed patterns were edited using Adobe Photoshop CS3, a multi-purpose graphic program and were simulated in the towel for visual presentation. The design is of two kinds, the one is of the free style using combinations of reclining Buddha, stone Buddha, stone pagoda, and geometric patterns freely not to be standardized. The other one is mixing of lotus pattern, reclining Buddha, and geometric patterns. These designs were applied delicately on the towel, necktie and handkerchief, and the various colors were suggested by the 6 color ways. The brilliance of our traditional cultural property should be noted by these designs and I hope that this study would be a help to develop our cultural prototype and make a product of using the outstanding heritage.

Study on the Conditioning of Brown Rice (I) -Property variation and predicted model of brown rice after Conditioning- (현미 조질에 관한 연구 (I) -조질 후 현미의 물성 변화와 예측모델-)

  • 한충수;연광석;강태환;전홍영;고학균
    • Journal of Biosystems Engineering
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    • v.26 no.1
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    • pp.39-46
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    • 2001
  • This research conducted to investigate the variation of the moisture content, crack ratio, and hardness of the whole and cracked brown rice after conditioning at the initial moisture content of 13, 14, and 15% with time lapse. The conditioning was conducted by increasing the moisture content of the sample to 0.4 and 0.8%. For basic information and conditioning characteristics for the development of a conditioning machine for the brown rice, predicted models of above three properties were developed using a nonlinear regression analysis of SAS with Gauss-Newton, Gradient, and DUD methods. Results of this research could be summarized as follows. 1. No moisture variation occurred after 0.5 hour conditioning. 2. The increasement of the crack ratio was 7.6 and 17.5% with the sample increased the moisture content of 0.4 and 0.8%, respectively, after 8 hours conditioning. 3. The hardness of the conditioned whole grain of the brown rice decreased 0.82 and 1,000kg$\_$f/ with the sample increased moisture content 0.4 and 0.8%, respectively, after 8 hours conditioning with respect to the non-conditioned sample. 4. The hardness of the conditioned cracked grain of the brown rice decreased 0.54 and 0.81kg$\_$f/ with the sample increased moisture content 0.4 and 0.8%, respectively, after 8 hours conditioning with respect to the non-conditioned sample. The hardness of the broken grain was about 0.81∼1.88kg$\_$f/ lower than whole grain. 5. The moisture content variation, increasing rate of the crack ratio, and hardness of the cracked and whole grain was predicted as a negative exponential function. 6. Each predicted model with the nonlinear regression analysis, which was very accurate and had a very small amount of sum of square of error between experimental value and predicted value, which could be used for predicting the physical variation after conditioning.

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Complex Compliance of Rough Rice Kernel under Cyclic Loading (주기적(週期的) 반복하중(反復荷重)을 받는 벼의 복소(複素)컴프라이언스)

  • Kim, M.S.;La, W.J.;Park, J.M.
    • Journal of Biosystems Engineering
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    • v.17 no.1
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    • pp.79-90
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    • 1992
  • Viscoelastic characteristics of agricultural products may be determined through three basic tests ; stress relaxation, creep, and dynamic test. Considering the changeability of living materials, dynamic test in which information is derived in a relatively short time appears to be highly desirable, in which either cyclic stress or cyclic strain is imposed and the remaining quantity (strain or stress) is measured. The periodically varying stress will also result in periodically varying strain which in a viscoelastic material should theoretically be out of phase with the stress, because part of the energy subjected to sample is stored in the material as potential energy and part is dissipated as heat. This behavior results in a complex frequency-dependent compliance denoted by J($i{\omega}$). The complex compliance and therefore the storage compliance, the loss compliance, the phase angle, and percent energy loss for the sample should be obtainable with a given static viscoelastic property of the material under static load. The complex compliance of the rough rice kernel were computed from the Burger's model describing creep behavior of the material which were obtained in the previous study. Also, the effects of cyclic load and moisture content of grain on the dynamic viscoelastic behavior of the samples were analyized. The results obtained from this study were summarized as follows ; 1. The storage compliance of the rough rice kernel slightly decreased with the frequency applied but at above the frequency of 0.1 Hz it was nearly constant with the frequency, and the loss compliance of the sample very rapidly decreased with increase in the frequency on those frequency ranges. 2. It was shown that the storage compliance and the loss compliance of the sample increased with increase in grain moisture content. Effect of grain moisture content on the storage compliance of the sample was highly significant than effect of the frequency applied, but effect of the frequency on the loss compliance of the sample was more significant than effect of grain moisture content. 3. In low moisture content, the percent energy loss of Japonica-type rough rice was much higher than that of Indica-type rough rice, but, in high moisture content, vice versa.

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