• 한국재료학회지
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• 제14권11호
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• pp.780-785
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• 2004

The degradation mechanism of soft magnetic properties of $Fe-Hf-N/Cr/SiO_2$ thin films reacted with a bonding glass was investigated. When $Fe-Hf-N/Cr/SiO_2$ films were annealed under $600^{\circ}C$ without the bonding glass, the compositions and the soft magnetic properties of Fe-Hf-N layers were not changed. However, after reaction with the bonding glass at $550^{\circ}C$, the soft magnetic properties of the film were degraded. At $600^{\circ}C$, the saturation magnetization of the reacted film decreased to 13.5 kG, and its coercivity increased to 4 Oe, and its effective permeability decreased to 700. It was founded that O diffused from the glass into the Fe-Hf-N layers during the reaction and generated $HfO_2$ phases. It was considered that the soft magnetic properties of the $Fe-Hf-N/Cr/SiO_2$ films reacted with the bonding glass were primarily degraded by the formation of the Fe-Hf-O-N layer of which the Fe content was below 60 $at\%$, and secondarily degraded by the Fe-Hf-O-N layer above 70 $at\%$.

• 폴리머
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• 제32권5호
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• pp.440-445
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• 2008

정수압 상태의 선형저밀도 폴리에틸렌 튜빙의 파손 메커니즘과 파손 모폴로지를 연구하였다. 비디오현미경과 주사전자현미경을 이용한 관찰 결과, 선형저밀도 폴리에틸렌 튜빙의 파손모드는 내면에서 외면으로 진전되는 크랙을 수반하는 취성파괴임을 확인하였다. 또한 산화유발시간과 적외선분광분석을 통하여, 파손된 선형저밀도 플리에틸렌 튜빙의 단면상에 열화에 의한 발열 피크와 카르보닐 피크의 증가를 관찰하였다. 열 가속에 의한 음력과 수명특성 사이의 관계를 고려한 선형저밀도 폴리에틸렌 튜빙의 가속수명시험법 및 시험장치를 개발하였다. 선형저밀도 폴리에틸렌 튜빙의 장기 정수압 상태의 수명을 예측하기 위해 아레니우스 모델과 와이블 분포를 적용한 통계학적 기법을 도입하였다. 그 결과, 사용온도 $25^{\circ}C$에서의 선형저밀도 폴리에틸렌 튜빙의 장기수명을 평가/분석하였다.

• 한국전기전자재료학회논문지
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• 제30권10호
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• pp.631-636
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• 2017

The degradation mechanism of $Mo_xW_{1-x}Si_2$ ultrahigh-temperature heating elements fabricated by self-propagating high-temperature synthesiswas investigated. The $Mo_xW_{1-x}Si_2$ specimens (with and without post-annealing) were subjected to ADTs (accelerated degradation tests) at temperatures up to $1,700^{\circ}C$ at heating rates of 3, 4, 5, 7, and $14^{\circ}C/min$. The surface loads of all the specimen heaters were increased with the increase in the target temperature. For the $Mo_xW_{1-x}Si_2$ specimens without annealing, many pores and secondary-phase particles were observed in the microstructure; the surface load increased to $23.9W/cm^2$ at $1,700^{\circ}C$, while the bending strength drastically reduced to 242 MPa. In contrast, the $Mo_xW_{1-x}Si_2$ specimens after post-annealing retained $single-Mo_xW_{1-x}Si_2$ phases and showed superior durability after the ADT. Consequently, it is thought that the formation of microcracks and coarse secondary phases during the ADT are the main causes for the degraded performance of the $Mo_xW_{1-x}Si_2$ heating elements without post-annealing.

• E2M - 전기 전자와 첨단 소재
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• 제8권5호
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• pp.551-557
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• 1995

For the observation of treeing, a visual measurement with an optical microscope has been used to explain breakdown mechanism in high-voltage systems. The conventional directed visual method of tree aging observation is difficult to measure in short time processing, and it is impossible to analyze on tree degradation area, progressed direction, tree pattern, etc. By using an image processing technique, the tree features which appear immediately after the tree initiation as well as changes in the configuration of the tree can be easily measured and observed than using the conventional visual methods. In this paper, we have developed a tree observating system by using image processing for tree growth, degradation area and other treeing progress. As an experimental result, it can be concluded that the image processing method is a more effective alternative than directed visual observation method. As a matter of fact, it is possible to record the image of tree propagation immediately after its first appearance and explain the characteristics of tree growth froth the computer processing image.

• 한국추진공학회지
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• 제19권5호
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• pp.84-90
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• 2015

티타늄 합금은 고온 추진체의 부품에 사용될 경우, 고온의 화염에서 순간적으로 노출될 수 있음으로, 고온의 화염하에서의 내산화특성을 평가할 필요가 있다. 본 연구에서는 Ti64 합금 (Ti-6%Al-4%V) 및 코팅된 Ti64 합금을 고온화염하에서 산화손상 및 내산화 특성을 평가하고자 하였다. Ti64 합금의 코팅은 알루미늄 확산코팅법을 사용하여 코팅을 수행하였다. 표면에 알루미나이드층이 코팅되지 않은 Ti64 합금은 고온의 화염 노출시에 표면 박리현상이 발생하였으나, 코팅된 시험편은 표면박리현상이 나타나지 않았고 알루미나이드 층의 산화물 생성으로 인하여 표면이 보호됨을 관찰할 수 있었다. 화염노출시 코팅층의 역할을 고찰하기 위하여 코팅층을 분석하였으며, 조직의 변화를 고찰하고 논의하였다.

• 한국수소및신에너지학회논문집
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• 제23권3호
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• pp.256-263
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• 2012

We studied the degradation phenomenon of Pt catalyst in PEMFC. We used the electron microscope analysis technique including the ultra-microtome pretreatment method, FEG-SEM and TEM analysis methods for analysis of Pt nanoparticles. The Pt catalyst degradation is observed not only in electrode site but also in membrane site. We investigated these various degradation phenomena. The cathode electrode layer thickness is reduced. The size of the catalyst is increased much larger than initial size in membrane site. The catalyst moved from electrode layer to the electrolyte membrane. The rounded shape of catalyst was changed to the polygon. As a result, we found that the catalyst degradation processes of migration and coarsening occurred by the followings mechanisms; (1) dissolution of Pt ; (2) diffusion of Pt ion ; (3) Pt ion chemical reduction in membrane; (4) Coarsening of Pt particles (Ostwald ripening) ; (5) polygon shape change of Pt by {111} plane growth.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.49.2-49.2
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• 2011

$PbMoO_4$ nanoparticles were successfully obtained in the presence of ethylene glycol (EG) with the assistance of a prolonged sonication process. The nanoparticles were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS) and adsorption-desorption $N_2$ isotherms (BET). The catalyst prepared sonochemically showed higher photocatalytic activity than $PbMoO_4$ prepared by solid-state reaction in the degradation reactions of rhodamine B (rhB), indigo carmine (IC), orange G (OG), and methyl orange (MO) under UV-Vis light radiation. In order to elucidate aspects of the degradation mechanism of the organic dyes, some experimental variables were modified such as pH, $O_2$ level in solution, and radiation source. In general, the photocatalytic activity for the degradation of organic dyes followed the sequence IC>OG>rhB>MO.

• 한국정보통신학회논문지
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• 제21권1호
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• pp.82-89
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• 2017

본 연구에서는 소스 및 드레인 전극 재료에 따른 소자 열화를 분석하기 위해 Ni, Al, 및 ITO를 소스 및 드레인 전극 재료로 사용하여 InGaZnO 박막 트랜지스터를 제작하였다. 전극 재료에 따른 소자의 전기적 특성을 분석한 결과 Ni 소자가 이동도, 문턱전압 이하 스윙, 구동전류 대 누설전류 비율이 가장 우수하였다. 소스 및 드레인 전극 재료에 따른 소자 열화 측정결과 Al 소자의 열화가 가장 심한 것을 알 수 있었다. InGaZnO 박막 트랜지스터의 소자 열화 메카니즘을 분석하기 위하여 채널 폭과 스트레스 드레인 전압을 다르게 하여 문턱전압 변화를 측정하였다. 그 결과 채널 폭이 넓을수록 또 스트레스 드레인 전압이 높을수록 소자 열화가 많이 되었다. 측정결과로부터 InGaZnO 박막 트랜지스터의 소자 열화는 큰 채널 전계와 주울 열의 결합 작용으로 발생함을 알 수 있었다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.21-24
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• 2003

The understanding of the mechanism of device degradation has been accomplished recently, for devices using $AlQ_3$ electron transport and emitter molecule. In this presentation the experimental evidence for the degradation mechanism of $AlQ_3$ based devices will be reviewed, showing that the hypothesis of an unstable $AlQ_3^+$ cation explains a large amount of experimental data. This hypothesis, however, explains not only the room temperature device degradation in time but also sheds light on temperature stability of OLEDs. Dependence of half-life of a series of devices with an emitter layer composed of a mixture of $AlQ_3$ and different hole transport molecules (mixed emitter layer) will be discussed when they are operated at elevated temperatures. These results can also be explained in the framework of an unstable $AlQ_3^+$ species. An OLED structure containing a doped mixed emitter layer will be described, which shows extraordinary stability, half-life of 1200 hours at operating temperature of 70 C and initial luminance of 1650 $cd/m^2$. We will also discuss a novel Black $Cathode^{TM}$ OLED with reduced optical reflectivity, which is also stable at elevated temperatures. The new cathode utilizes a conductive light-absorbing layer made of a mixture of metals and organic materials.

• 소성∙가공
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• 제32권3호
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• pp.129-135
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• 2023

The use of engineering plastic products in internal combustion engine and electric cars to improve stiffness and reduce weight is increasing significantly. Among various lightweight materials, engineering plastics have significant advantages such as cost reduction, improved productivity, and weight reduction. In particular, engineering plastics containing glass fibers are used to enhance stiffness. However, the stiffness of glass fibers can increase or decrease depending on their orientation. Before developing plastic products, optimal designs are determined through injection molding and structural analysis to enhance product reliability. However, reliable analysis of products with variable stiffnesses caused by anisotropy cannot be achieved via the conventional isotropic structural analysis, which does not consider anisotropy. Therefore, based on the previously reported study "the Effect of Impacted Fracture in Glass Fiber Orientation with Injection Molding & Structural Coupled Analysis," this study aims to investigate the structural analysis and degradation mechanisms of various polymers. In particular, this study elucidates the actual mechanism of plastic fracture by analyzing various fracture conditions and their corresponding simulations. Furthermore, the objective of this study is to apply the injection molding and structural coupled analysis mechanism to develop engineering plastic products containing glass fibers. In addition, the study aims to apply and improve the plastic fracture mechanism in actual products by exploring anisotropy and stiffness reduction owing to the unfilled polymer weld line.