• Title/Summary/Keyword: Material separation

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Technology Trend on Commercial Polymeric Membranes for Water Treatment (수처리용 상용 고분자 분리막 제품 기술동향)

  • Jang, Haenam
    • Membrane Journal
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    • v.29 no.1
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    • pp.11-17
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    • 2019
  • In the field of water treatment membranes, polymers are used together with ceramics as the most important materials. In this review, I tried to analyze the technology trends of polymer membrane materials based on commercial products. For this purpose, according to the types of water treatment membranes such as MF (Microfiltration), UF (Ultrafiltration) and NF (Nanofiltration), the trends of polymer membrane products were investigated by countries, materials, and companies. Through this, we were able to classify the types of materials that are mainly used for each type of membrane, and at the same time, identify the companies that are dominant in the market, and analyze which materials constitute the product portfolio. Based on these results, we have presented the characteristics of the material market according to each type of membrane, and proposed a technology development strategy to enter each market based on these characteristics.

The effect of UV-C irradiation and EDTA on the uptake of Co2+ by antimony oxide in the presence and absence of competing cations Ca2+ and Ni2+

  • Malinen, Leena;Repo, Eveliina;Harjula, Risto;Huittinen, Nina
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.627-636
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    • 2022
  • In nuclear power plants and other nuclear facilities the removal of cobalt from radioactive liquid waste is needed to reduce the radioactivity concentration in effluents. In liquid wastes containing strong organic complexing agents such as EDTA cobalt removal can be problematic due to the high stability of the Co-EDTA complex. In this study, the removal of cobalt from NaNO3 solutions using antimony oxide (Sb2O3) synthesized from potassium hexahydroxoantimonate was investigated in the absence and presence of EDTA. The uptake studies on the ion exchange material were conducted both in the dark (absence of UV-light) and under UV-C irradiation. Ca2+ or Ni2+ were included in the experiments as competing cations to test the selectivity of the ion exchanger. Results show that UV-C irradiation noticeably enhances the cobalt sorption efficiency on the antimony oxide. It was shown that nickel decreased the sorption of cobalt to a higher extent than calcium. Finally, the sorption data collected for Co2+ on antimony oxide was modeled using six different isotherm models. The Sips model was found to be the most suitable model to describe the sorption process. The Dubinin-Radushkevich model was further used to calculate the adsorption energy, which was found to be 6.2 kJ mol-1.

Testing the Consistency of Unified Scheme of Seyfert Galaxies

  • Iyida, Evaristus U.;Eya, Innocent O.;Eze, Christian I.
    • Journal of Astronomy and Space Sciences
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    • v.39 no.2
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    • pp.43-50
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    • 2022
  • The unified scheme of Seyfert galaxies hypothesizes that the observed differences between the two categories of Seyfert galaxies, type 1 (Sy1) and type 2 (Sy2) are merely due to the difference in the orientation of the toroidal shape of the obscuring material in the active galactic nuclei. We used in this paper, a sample consisting of 120 Seyfert galaxies at 1.40 × 109 Hz in radio, 2.52 × 1017 Hz in X-ray and 2.52 × 1023 Hz in γ-ray luminosities observed by the Fermi Large Area Telescope (Fermi-LAT) in order to test the unified scheme of radio-quiet Seyfert galaxies. Our main results are as follows: (i) We found that the distributions of multiwave luminosities (Lradio, LX-ray, and Lγ-ray) of Sy1 and Sy2 are completely overlapped with up to a factor of 4. The principal component analysis result reveals that Sy1 and Sy2 also occupy the same parameter spaces, which agrees with the notion that Sy1 and Sy2 are the same class objects. A Kolmogorov-Smirnov test performed on the sub-samples indicates that the null hypothesis (both are from the same population) cannot be rejected with chance probability p ~ 0 and separation distance K = 0.013. This result supports the fact that there is no statistical difference between the properties of Sy1 and Sy2 (ii) We found that the coefficient of the best-fit linear regression equation between the common properties of Sy1 and Sy2 is significant (r > 0.50) which plausibly implies that Sy1 and Sy2 are the same type of objects observed at different viewing angle.

Content Comparative Analysis and Classification for Piniellia ternate, P. pedatisecta and Typhonium flagelliforme by HPLC-PDA analysis (HPLC-PDA를 이용한 반하, 호장남성, 수반하의 분류 및 함량분석)

  • Jo, Ji Eun;Lee, A Yeong;Kim, Hyo Seon;Moon, Byeong Cheol;Choi, Goya;Ji, Yunui;Kim, Ho Kyoung
    • The Korea Journal of Herbology
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    • v.28 no.5
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    • pp.95-101
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    • 2013
  • Objectives : A quantitative method using high performance liquid chromatography with a photodiode array detector(HPLC-PDA) was established for the quantitative analysis of the four main compound and pattern analysis to classification Piiellia ternate, P. pedatisecta and Typhonium flagelliforme. Methods : The analytical procedure for the determination of P. ternata, together with the known main compounds uracil, uridine, guanosine and adenosine was established. Optimum HPLC-PDA separation of these P. ternata was possible on Luna C18(2) column material, using water and acetonitrile as mobile phase. The method was validated according to regulatory guidelines. In addition, this assay method were analyzed for the content of four main compound in P. ternata, P. pedatisecta and T. flagelliforme and by data obtained from the HPLC-PDA analysis was performed principal component analysis(PCA). Results : Validation results indicated that the HPLC method is well suited for the determination of the roots of P. ternata with a good linearity ($r^2$ > 0.999), precision and recovery rates. Analysis of HPLC-PDA, the average content of uracil, uridine, guanosine and adenosine was significantly higher in P. ternate>P. pedatisecta> T. flagelliforme order. The application of PCA to main compound data by HPLC-PDA permitted the effective discrimination among the three species. Conclusions : Analysis of both HPLC-PDA and PCA confirmed the fact that four main compound and pattern profiles of P. ternata, P. pedatisecta and T. flagelliforme were different from each other.

Cryopreservation of Siberian tiger (Panthera tigris altaica) epididymal spermatozoa: pilot study of post-thaw sperm characteristics

  • Ibrahim, Saddah;Talha, Nabeel Abdelbagi Hamad;Kim, Jeongho;Jeon, Yubeol;Yu, Iljeoung
    • Journal of Animal Reproduction and Biotechnology
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    • v.37 no.2
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    • pp.130-135
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    • 2022
  • Epididymal sperm cryopreservation provides a potential method for preserving genetic material from males of endangered species. This pilot study was conducted to develop a freezing method for tiger epididymal sperm. We evaluated post-thaw sperm condition using testes with intact epididymides obtained from a Siberian tiger (Panthera tigris altaica) after castration. The epididymis was chopped in Tyrode's albumin-lactate-pyruvate 1x and incubated at 5% CO2, 95% air for 10 min. The Percoll separation density gradient method was used for selective recovery of motile spermatozoa after sperm collection using a cell strainer. The spermatozoa were diluted with modified Norwegian extender supplemented with 20 mM trehalose (extender 1) and subsequent extender 2 (extender 1 with 10% glycerol) and frozen using LN2 vapor. After thawing at 37℃ for 25 s, Isolate® solution was used for more effective recovery of live sperm. Sperm motility (computerized assisted sperm analysis, CASA), viability (SYBR-14 and Propidium Iodide) and acrosome integrity (Pisum sativum agglutinin with FITC) were evaluated. The motility of tiger epididymal spermatozoa was 40.1 ± 2.0%, and progressively motile sperm comprised 32.7 ± 2.3%. Viability was 56.3 ± 1.6% and acrosome integrity was 62.3 ± 4.4%. Cryopreservation of tiger epididymal sperm using a modified Norwegian extender and density gradient method could be effective to obtain functional spermatozoa for future assisted reproductive practices in endangered species.

Optimization of fish oil extraction from Lophius litulon liver and fatty acid composition analysis

  • Hu, Zhiheng;Chin, Yaoxian;Liu, Jialin;Zhou, Jiaying;Li, Gaoshang;Hu, Lingping;Hu, Yaqin
    • Fisheries and Aquatic Sciences
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    • v.25 no.2
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    • pp.76-89
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    • 2022
  • The Lophius litulon liver was used as raw material for the extraction of fish oil via various extraction methods. The extraction rate by water extraction, potassium hydroxide (KOH) hydrolysis and protease hydrolysis were compared and the results revealed the protease hydrolysis extraction had a higher extraction rate with good protein-lipid separation as observed by optical microscope. Furthermore, subsequent experiments determined neutrase to be the best hydrolytic enzyme in terms of extraction rate and cost. The extraction conditions of neutrase hydrolysis were optimized by single-factor experiment and response surface analysis, and the optimal extraction rate was 58.40 ± 0.25% with the following conditions: enzyme concentration 2,000 IU/g, extraction time 1.0 h, liquid-solid ratio 1.95:1, extraction temperature 40.5℃ and pH 6.5. The fatty acids composition in fish oil from optimized extraction condition was composed of 19.75% saturated fatty acids and 80.25% unsaturated fatty acids. The content of docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA) were 8.06% and 1.19%, respectively, with the ratio (6.77:1) surpassed to the recommendation in current researches (5:1). The results in this study suggest protease treatment is an efficient method for high-quality fish oil extraction from Lophius litulon liver with a satisfactory ratio of DHA and EPA.

Development of Lithium Lanthanum Titanate (LLTO) Membrane Manufacturing Process for Selective Separation of Lithium Ion (리튬이온의 선택적 투과를 위한 Lithium Lanthanum Titanate계 분리막 제조 공정 개발)

  • Young Il Kim;Sang Cheol Park;Kwang Ho Shin;InYeong Kim;Kee-Ahn Lee;Sung-Kyun Jung;Bin Lee
    • Journal of Powder Materials
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    • v.30 no.1
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    • pp.22-28
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    • 2023
  • The global demand for raw lithium materials is rapidly increasing, accompanied by the demand for lithiumion batteries for next-generation mobility. The batch-type method, which selectively separates and concentrates lithium from seawater rich in reserves, could be an alternative to mining, which is limited owing to low extraction rates. Therefore, research on selectively separating and concentrating lithium using an electrodialysis technique, which is reported to have a recovery rate 100 times faster than the conventional methods, is actively being conducted. In this study, a lithium ion selective membrane is prepared using lithium lanthanum titanate, an oxide-based solid electrolyte material, to extract lithium from seawater, and a large-area membrane manufacturing process is conducted to extract a large amount of lithium per unit time. Through the developed manufacturing process, a large-area membrane with a diameter of approximately 20 mm and relative density of 96% or more is manufactured. The lithium extraction behavior from seawater is predicted by measuring the ionic conductivity of the membrane through electrochemical analysis.

Analysis of Positive Bias Temperature Instability Degradation Mechanism in n+ and p+ poly-Si Gates of High-Voltage SiO2 Dielectric nMOSFETs (고전압 SiO2 절연층 nMOSFET n+ 및 p+ poly Si 게이트에서의 Positive Bias Temperature Instability 열화 메커니즘 분석)

  • Yeohyeok Yun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.16 no.4
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    • pp.180-186
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    • 2023
  • Positive bias temperature instability (PBTI) degradation of n+ and p+ poly-Si gate high-voltage(HV) SiO2 dielectric nMOSFETs was investigated. Unlike the expectation that degradation of n+/nMOSFET will be greater than p+/nMOSFET owing to the oxide electric field caused by the gate material difference, the magnitude of the PBTI degradation was greater for the p+/nMOSFET than for the n+/nMOSFET. To analyze the cause, the interface state and oxide charge were extracted for each case, respectively. Also, the carrier injection and trapping mechanism were analyzed using the carrier separation method. As a result, it has been verified that hole injection and trapping by the p+ poly-Si gate accelerates the degradation of p+/nMOSFET. The carrier injection and trapping processes of the n+ and p+ poly-Si gate high-voltage nMOSFETs in PBTI are detailed in this paper.

Race and Politics in Brazil: Occurrence, Development, Characteristics (브라질의 인종과 정치: 발생, 전개, 특징)

  • Kim, Dal-Kwan
    • Iberoamérica
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    • v.21 no.1
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    • pp.1-55
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    • 2019
  • In Brazil, racism exists without the clear definition of race. In other words, because there is racism without a clear concept of race, racial issues are complicated in Brazil. Racism is not just a social problem. It is, above all, a political problem that arises from economic separation, exclusion, and marginalization. From the enlargement process of European colonialism, racism has been the most profound and efficient way of governance of social, material, psychological and political domination of Brazil. From this perspective, this study seeks to research racism in Brazil as a race politics. In conclusion, racial discrimination and racial inequality exist in Brazil. Thus, to study the racial discrimination and racial inequalities in Brazil, Chapter 2 examines the origins of racial politics in Brazil. Chapter 3 explores the relations of Brazilian society and races. Chapter 4 examines Black's resistance to racism as a black movement in Brazil. The first half of Chapter 5 looks at 'racial inequality in Brazil' and the latter sees 'racism in Brazil'. Chapter 6, as a conclusion, discusses the challenges and limitations of racial politics in Brazil.

Mechanism of Tungsten Recovery from Spent Cemented Carbide by Molten Salt Electrodeposition

  • Hongxuan Xing;Zhen Li;Enrui Feng;Xiaomin Wang;Hongguang Kang;Yiyong Wang;Hui Jin;Jidong Li
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.75-84
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    • 2023
  • The accumulation of spent carbide (YG8), not only pollutes the environment but also causes waste of tungsten, cobalt and other rare metal resources. To better address this issue, we proposed a combined electrochemical separation process of low-temperature aqueous solution and high-temperature molten salt for tungsten and cobalt. H2WO4 was obtained from spent carbide in an aqueous solution, and we calcined it to obtain WO3, which was used as a raw material to obtain tungsten by using molten salt electrodeposition. The influence of the current efficiency and the electrochemical behavior of the discharge precipitation of W(VI) were also studied. The calcination results showed that the morphology of WO3 was regular and there were no other impurities. The maximum current efficiency of 82.91% was achieved in a series of electrodeposition experiments. According to XRD and SEM analysis, the recovered product was high purity tungsten, which belongs to the simple cubic crystal system. In the W(VI) reduction mechanism experiments, the electrochemical process of W(VI) in NaCl-Na2WO4-WO3 molten salt was investigated using linear scanning voltammetry (LSV) and chronoamperometry in a three-electrode system. The LSV showed that W(VI) was reduced at the cathode in two steps and the electrode reaction was controlled by diffusion. The fitting results of chronoamperometry showed that the nucleation mechanism of W(VI) was an instantaneous nucleation mode, and the diffusion coefficient was 7.379×10-10 cm2·s-1.