• Title/Summary/Keyword: Material separation

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Propylene/Nitrogen Separation Membranes Based on Amphiphilic Copolymer Grafted from Poly(1-trimethylsilyl-1-propyne) (양친성 고분자가 그래프팅된 Poly(1-trimethylsilyl-1-propyne) 기반의 프로필렌/질소 분리막)

  • Park, Cheol Hun;Lee, Jae Hun;Park, Min Su;Kim, Jong Hak
    • Membrane Journal
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    • v.29 no.2
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    • pp.88-95
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    • 2019
  • Hydrocarbons containing carbon double bonds are generally called olefins and it is extensively used in petro-chemical industry as essential base material. Especially, olefins are essential in polymer synthesis and thus the effective separation and purification of olefins from gas mixture are very important and it gives significant positive effect on the future industrial development. In this study, we fabricated polymeric composite membrane based on poly(1-trimethylsilyl-1-propyne) (PTMSP) for propylene/nitrogen separation and enhancement of its separation performance by grafting amphiphilic copolymer. Furthermore, to accelerate facilitated transport for propylene molecules, Ag salt ($AgBF_4$) and ionic liquid ($EMIM-BF_4$) was incorporated to polymer composite membranes. The neat PTMSP membrane exhibited extremely high gas permeance and low gas selectivity due to its high free volume. To address this issue, PTMSP was grafted with poly(oxyethylene glycol methacrylate) (POEM) and poly(ethylene glycol) behenyl ether methacrylate (PEGBEM). Additionally, the additives such as $AgBF_4$ and $EMIM-BF_4$ further increased the propylene permeance, resulting in increment of propylene/nitrogen selectivity.

Behavior of Closely-Spaced Tunnel According to Separation Distance Using Scaled Model Tests (축소모형실험을 통한 이격거리에 따른 근접터널의 거동)

  • Ahn, Hyun-Ho;Choi, Jung-In;Shim, Seong-Hyeon;Lee, Seok-Won
    • Journal of the Korean Geotechnical Society
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    • v.24 no.7
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    • pp.5-16
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    • 2008
  • Most of roadway tunnels have been constructed in the form of parallel twin tunnel in Korea. If parallel twin tunnel does not have a sufficient separation distance between tunnels, the problem of tunnel stability can occur. Generally, it is reported that tunnels are not influenced by each other when a center distance between tunnels is two times longer than tunnel diameter under the complete elastic ground and five times under the soft ground. In this study, the scaled model tests of closely-spaced parallel twin tunnel using homogeneous material are performed and induced displacements are measured around the tunnel openings during excavation. The influence of separation distance between tunnels on the behavior of closely-spaced tunnel is investigated. The experimental results are expressed by the induced displacement vector and progress of crack during construction and at failure. The results show that based on the analysis of induced displacement at the crown during construction, the additional displacement of the preceding tunnel induced by the excavation of following tunnel decreases as the separation distance between twin tunnel increases until the center to center distance is two times of tunnel diameter. Beyond this point, however, the additional displacement has become stabilized.

Review on Reprocessing Techniques for Mineral Wastes (광산폐기물의 재활용 기술 동향과 전망)

  • 최우진
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.113-119
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    • 2004
  • Mineral wastes are generated by the minerals, mining, and metal industries. These are generally inorganic waste streams of mainly waste rock or residues from refining during extraction of metals or minerals from the ore. There are many plants where minerals are recovered in secondany circuits, treating tailings, where the feed grades are much lower than would be economic on a mined ore. The world is now becoming aware of the finite nature of its resources at a price, and of the ever-increasing development costs of large new mines. Reprocessing of old tailings on a large scale must be worth examining very seriously by those with access to sufficient material of this type. In the present paper, mineral separation techniques to recover valuable metals and resources from the old tailings are reviewed, and new trends for future developments are also discussed.

HgTe/Cdte superlattices grown on CdZnTe(211)B by MBE

  • Kang, T.W.;Jeong, C.S.;Leem, J.H.;Ryu, Y.S.;Hyun, J.K.;Jeon, H.C.;Lee, H.Y.;Han, M.S.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.34-42
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    • 1997
  • Hg-Te-CdTe superlattices have received much interests over the last several years as a potential material for its applications for detecting devices and optoelectronics. We have grown the HgTe-CdTe superlattice using MBE. in our lab. We have carried out DCRC spectroscopy after growth of HgTe-CdTe superlattice with varying the superlattice periods and controlling the barrier thickness and we have that the presence of the main peak and the satellite peaks. We obtained 20 arcsec of FWHM over 100 periods of superlattice. We also note that high peak intensity shows the high quality of the sample and each layer of superlattice has abrupt interfaces. The angular separation between the main peak(m=0) and the first satellite peak(m=$\pm$1) is increased when the barrier layer thickness in superlatice layers are decreased. The separation between the first setellite peak(m=$\pm$1) and the second satellite peak(m$\pm$2) is increased similarly. The number of the satellite peak is a qualitative measure of the interfacial abruptness of the superlattice.

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A Study on the Clamping Force of an Automotive Air-conditioning Hose according to the Friction Coefficient (마찰계수를 고려한 자동차용 에어컨 호스의 체결력에 관한 연구)

  • Baek, Jae-Kwon;Kim, Byung-Tak
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.3
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    • pp.39-46
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    • 2011
  • The automotive air conditioning hose is used for connecting the components of air conditioner in a vehicle. The hose is usually manufactured by the swaging process to connect the rubber hose with the metal fitting at the end of the hose. In case that the clamping force is small, the refrigerant gas in the hose can leak locally under the severe operating circumstances. The practical test of clamping force is performed by means of the measurement of separation force. In this study, the swaging process of a hose is simulated with the finite element method, to investigate the effect of friction coefficient on the clamping force. The contact condition is used in consideration of real manufacturing process, and the material properties for the Mooney-Rivlin model is obtained by the experimental results. The result interpretations are focused on the contact forces, which is displayed graphically with respect to friction coefficient, on the surfaces between the hose and the metal fittings.

Development Trend of Composite Materials for Membrane Hosuing (분리막 하우징용 복합소재의 연구개발 동향)

  • Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.26 no.1
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    • pp.14-25
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    • 2016
  • The membrane separation process is growing very fast because of the high efficiency and low cost compared with other traditional process. The membrane process consists of various components such as membrane, module and mechanical part. The requirements for materials used in the membrane separation are becoming more and more demanding for achievement of high efficiency. Membrane module is also considered as the one of the key component in the membrane system. Recently composite materials have been considered as the membrane housing due to their excellent property and low cost compared with stainless module. In this review, a various types of glass fiber and composite material are summarized and their potential for the application of membrane system is discussed.

Concept Design of High Altitude Simulation Test Facility (고공환경모사 시험설비 구축을 위한 개념설계)

  • Kim, Sang-Heon;Kim, Yong-Wook;Lee, Jung-Ho;Yu, Byung-Il;Cho, Sang-Yeon;Oh, Seung-Hyub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.75-81
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    • 2006
  • The propulsion system of KSLV-I second stage is engine with high expansion ratio and its starting altitude is high. To verify the performance of engine before the launch in the ground, high altitude test facility to simulate its operating condition is necessary. This material is about the concept design of high altitude simulation test facility for second stage engine. And it will be the basis for the construction of test facility and the test of engine.

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Fabrication of Li2ZrO3 Membrane and Evaluation on the Mechanical Properties Before and After CO2 Separation (Li2ZrO3 분리막의 제조와 이산화탄소 선택투과 전후의 기계적 특성 평가)

  • Park, Sang-Hyun;Lee, Shi-Woo;Yu, Ji-Haeng;Woo, Sang-Kuk;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.58-64
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    • 2007
  • In this study, we investigated $Li_2ZrO_3$ membrane as a candidate material for high-temperature $CO_2$ separation and evaluated mechanical property. $Li_2ZrO_3$ powder was synthesized by solid state reaction of $Li_2CO_3\;and\;ZrO_2$. Then we fabricated $Li_2ZrO_3$ tape using tape casting method. Dense $Li_2ZrO_3$ membrane prepared by sintering at $1600^{\circ}C$ for 2 h after pressing $Li_2ZrO_3$ tape using lamination machine. Mechanical properties before and after $CO_2$ absorption of fabricated $Li_2ZrO_3$ membrane such as Hertzian indentation, Victors hardness and 3-point bending testing were evaluated.

The Replication Protein Cdc6 Suppresses Centrosome Over-Duplication in a Manner Independent of Its ATPase Activity

  • Kim, Gwang Su;Lee, Inyoung;Kim, Ji Hun;Hwang, Deog Su
    • Molecules and Cells
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    • v.40 no.12
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    • pp.925-934
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    • 2017
  • The Cdc6 protein is essential for the initiation of chromosomal replication and functions as a licensing factor to maintain chromosome integrity. During the S and G2 phases of the cell cycle, Cdc6 has been found to inhibit the recruitment of pericentriolar material (PCM) proteins to the centrosome and to suppress centrosome over-duplication. In this report, we analyzed the correlation between these two functions of Cdc6 at the centrosome. Cdc6 depletion increased the population of cells showing centrosome over-duplication and premature centrosome separation; Cdc6 expression reversed these changes. Deletion and fusion experiments revealed that the 18 amino acid residues (197-214) of Cdc6, which were fused to the Cdc6-centrosomal localization signal, suppressed centrosome over-duplication and premature centrosome separation. Cdc6 mutant proteins that showed defective ATP binding or hydrolysis did not exhibit a significant difference in suppressing centrosome over-duplication, compared to the wild type protein. In contrast to the Cdc6-mediated inhibition of PCM protein recruitment to the centrosome, the independence of Cdc6 on its ATPase activity for suppressing centrosome over-duplication, along with the difference between the Cdc6 protein regions participating in the two functions, suggested that Cdc6 controls centrosome duplication in a manner independent of its recruitment of PCM proteins to the centrosome.

An Experimental Study of the Recycled Cement Manufacturing Method for Improving the Material Quality (재생시멘트의 품질향상을 위한 제조방법에 관한 연구)

  • Oh, Sang-Gyun
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.2
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    • pp.143-149
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    • 2004
  • The recycle of domestic waste concrete is, however, still in an early stage, and it has been only partially being used for the road fillers. As a counter-plan of activating recycled concrete, we have confirmed the hydration possibility of the waste concrete powder from the experiment on recycling the aggregate powder since 2000. Though that study, we have known that the strength is increasing when the baking time is longer, and baking temperature maintain in $700^{\circ}C$. Also, the quality is lowered because of the fine aggregate powder which has a bad influence on flowability & compression strength by adhesion of mortar on the aggregate face. Therefore, mortar and interfacial separation of aggregate are large in proper quality for concrete recycling is expected that affect. The purpose of this study is to investigate effective aggregate separation and to determine the most suitable production method controlling the duration of baking time for recycled cement from the compressive strength, X-ray diffraction and ingredient analysis test.