• Title/Summary/Keyword: Material dispersion

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Electrical Characteristics for Epoxy-Organoclay Nanocomposites of Several Types using Centrifugal Dispersion Technique (Centrifugal 분산기법을 이용한 여러종류 Epoxy-Organoclay 나노콤포지트의 전기적 특성)

  • Park, Jae-Jun;Kim, Ju-Ho;Park, Young-Bum;Lee, Dong-Yoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.281-282
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    • 2008
  • 고압절연용 에폭시-나노콤포지트의 전기적, 기계적, 열적특성이 동반적 물성의 상승을 가져오기 때문에 활발한 연구가 진행 중에 있다. 에폭시 메트릭스 내에서 유기화된 층상구조를 갖는 나노입자의 분산정도에 따라 여러 가지 물성에 영향을 나타내고 있다. Centrifugal 분산기법으로 나노콤포지트제조시 에폭시분자의 층간내로 충분한 삽입으로 박리가 발생하였다. 전기적 특성로서 기본적 구조적 특성인 X-RD특성과 TEM의 관찰로 분산을 확인할 수있었고, DSC의 측정으로 가교도를 알 수 있는 Tg값이 원형수지에 비하여 $11^{\circ}C$향상된 여러종류의 나노콤포지트를 개발하였다. 유전특성 및 절연파괴 특성으로도 원형수지에 비하여 나노콤포지트의 향상된 특성을 얻을 수 있었다.

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Structural, Thermal, Electrical Characteristics for Epoxy/Organoclay Nanocomposites according to Physical Dispersion Method of Several Types (여러종류의 물리적 분산기법에따른 Epoxy/Organoclay Nanocomposites의 구조적, 열적, 전기적특성 연구)

  • Park, Jae-Jun;Cho, Hee-Su;Cho, Min-Sung;Hwang, Byung-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.39-40
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    • 2008
  • 유기용매를 사용한 나노분산체의 경우, 유기용매를 완전하게 제거 것은 극히 어렵다. 이는 유기용매와 유기고분자와의 일부 반응되는 경우가 발생되어 전기적 물성에 영향을 줄 수 있다. 본 연구는 친환경적인 분산기법으로 물리적 분산기법을 제안하는 바이다. 양호한 분산체를 얻기위해 균질한 상태인 마이크로적 분산기법과 층상실리케이트인 층간사이에 고분자인 에폭시분자가 삽입되어 박리가 양호하게 일어나게 하는 나노적인 분산기법을 통시에 적용하여 분산이 훌륭하게 일어나는 경우를 개발하였다. 마이크로적인 분산을 위해 사용된 Homogenizer의 적용속도와 적용시간에서 원형인 Organoclay_10A Powder의 d-spacing이 262%, 263%로 증가되는 결과를 얻었다. 또한 DSC의 유리천이온도 분석에서도 적용시간의 증가에 따라 유리천이온도가 되어 원형에폭시수지에 비하여 $9^{\circ}C$상승된 결과를 얻을 수 있었다.

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Dielectric Properties of Complex Cconcentration in IMI-0 Thin Films (IMI-O 초박막의 착체농도에 대한 유전 특성)

  • 정상범;유승엽;박재철;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.345-348
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    • 1999
  • The monolayer behaviors at the air-water interface and the dielectric properties of MI-0 LB films for complex concentration were investigated by the surface pressure-area ($\pi$-A) isotherms and dielectric constant. The molecular area was expanded with increase of metal ions concentration. It is considered that the expansion of molecular area is due to electrostatic repulsion between the polymer chains andhydrophobic increase of ionic strength. In the frequency-dependent complex dielectric constant at room temperature, the real part of dielectric constant($\varepsilon'$) is about 6.0~10.0 in the low-frequency range and is decreasing slowly upto $1O^4$Hz. It decreased abruptly near $1O^5Hz$. It seems to be dielectric dispersion in this frequency range. Also, the imaginary part of dielectric constant ($\varepsilon"$) shows a peak in $1O^5$~$1O^6Hz$. It seems to be dielectric absorption in this frequency range.ange.

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Electro-Optic Characteristics of the Fringe-Field driven Reflective Hybrid Aligned Nematic Liquid Crystal Display (Fringe-Field 구동형 반사형 Hybrid Aligned Nematic 액정 디스플레이의 전기-광학 특성)

  • 정태봉;박지혁;손정석;송제훈;이승희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.2
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    • pp.201-206
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    • 2004
  • We have performed computer simulation and experiment to obtain electro-optic characteristics of reflective hybrid aligned nematic (R-HAN) cell driven by fringe field, in which the cell consists of polarizer, optical compensation film, LC layer and reflector. Conventional R-HAN cell driven by fringe field using only the LC layer shows high wavelength dispersion at dark-state and thus viewing angle characteristic is strongly wavelength-dependent. In order to improve this demerit, we added one optical compensation film to conventional R-HAN cell. The display with optimized cell parameters shows low wavelength dispersion at dark-state and exhibits a wide viewing angle without the occurrence of grey scale inversion over a wide range of viewing angles and the contrast ratio greater than 5 over exists about 120$^{\circ}$ in vortical direction and 160$^{\circ}$in horizontal direction. Experimental results show good agreements with theoretical results and fast response time.

A size-dependent quasi-3D model for wave dispersion analysis of FG nanoplates

  • Karami, Behrouz;Janghorban, Maziar;Shahsavari, Davood;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.28 no.1
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    • pp.99-110
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    • 2018
  • In this paper, a new size-dependent quasi-3D plate theory is presented for wave dispersion analysis of functionally graded nanoplates while resting on an elastic foundation and under the hygrothermaal environment. This quasi-3D plate theory considers both thickness stretching influences and shear deformation with the variations of displacements in the thickness direction as a parabolic function. Moreover, the stress-free boundary conditions on both sides of the plate are satisfied without using a shear correction factor. This theory includes five independent unknowns with results in only five governing equations. Size effects are obtained via a higher-order nonlocal strain gradient theory of elasticity. A variational approach is adopted to owning the governing equations employing Hamilton's principle. Solving analytically via Fourier series, these equations gives wave frequencies and phase velocities as a function of wave numbers. The validity of the present results is examined by comparing them with those of the known data in the literature. Parametric studies are conducted for material composition, size dependency, two parametric elastic foundation, temperature and moisture differences, and wave number. Some conclusions are drawn from the parametric studies with respect to the wave characteristics.

The evaluation of Mechanical properties of Strain Hardening Cement-based composites manufactured at batcher plant (배처플랜트에 의해 제조된 SHCC의 역학적 성능 평가에 관한 연구)

  • Lim, Chang-Hyuck;Kim, Young-Sun;Kim, Young-Duck;Jeong, Jae-Hong;Lee, Seung-Hoon;Kim, Gyu-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.05b
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    • pp.93-96
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    • 2009
  • This study is to examine a change of quality and a material performance of fiber reinforced cement composite for mass production. It is necessary to make Strain-hardening cementitious composite(SHCC) by batcher plant for ready-mixed concrete and use the performance of SHCC which made based on laboratory level. This study makes a comparative performance of press and mechanics that is the property of Strain-hardening by direct tension. In case of making by batcher plant. This experiment has demonstrated that even if it takes long after being mixed small and compared with the one which made based on laboratory, it has a tendency to be dissatisfied with fiver's dispersion and lower its performance of Strain-hardening. The reason why the material performance of SHCC for mass production went down is through SHCC that mixed sometimes matrix's viscosity and fiber's dispersion.

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Opto-electrical properties of solution based carbon nanotube electrode (용액코팅된 탄소나노튜브 전극의 광전기적 성질)

  • Woo, Jong-Seok;Kim, Sun-Young;Han, Joong-Tark;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.394-394
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    • 2007
  • Transparent conductive films can serve as a critical component in displays, solar cells, lasers, optical communication devices, and solid state lighting. Carbon nanotube (CNT) based transparent conductive films are fabricated on glass and polymer substrates. CNTs typically exist in form of quasi-crystalline bundles or highly entangled bundles containing tens of individual nanotubes. To achieve full potential, CNTs must be dispersed in a solvent or other organic media. CNTs are acid treated with nitric acid then the stable dispersion of CNTs in polar solvent such as alcohols, DMF, etc. is achieved by sonication. The solubility of CNTs correlates well with the area ratio of the D and G bands from Raman spectrum. Thin films are formed from well dispersed CNT solutions using spray coating method. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders.

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Evaluation of Thermal Behavior of Oil-based Nanofluids using Ceramic Nanoparticles (세라믹 분말을 이용한 오일 기지 나노유체의 열적거동 평가)

  • Choi, Cheol;Yoo, Hyun-Sung;Oh, Je-Myung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.587-593
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    • 2007
  • Oil-based nanofluids were prepared by dispersing spherical and fiber shaped $Al_2O_3$ and AlN nanoparticles in transformer oil. Two hydrophobic surface modification processes using oleic acid (OA) and polyoxyethylene alkyl acid ester (PAAE) were compared in this study. The dispersion stability, viscosity and breakdown voltage of the nanofluids were also characterized. $(Al_2O_3+AlN)$ mixed nanofluid was prepared to take an advantage of the excellent thermal conductivity of AlN and a good convective heat transfer property of fiber shaped $Al_2O_3$. For $(Al_2O_3+AlN)$ particles with 1 % volume fraction in oil, the enhancement of thermal conductivity and convective heat transfer coefficient was nearly 11 % and 30 %, respectively, compared to pure transformer oil. The nanofluid, containing $Al_2O_3+AlN$, successfully lowered the temperature of the heating element and oil itself during a natural convection test using a prototype transformer.

Performance characteristics of AGM lead acid battery with the content of positive plate incorporating nano-size additive material (나노 사이즈 입자가 포함된 양극 활물질 함량에 따른 차량용 AGM 연축전지 성능 특성)

  • Lim, Tae Seop;Kim, Sung Jun;Kim, Sang Dong;Yang, Seung Cheol;Jung, Yeon Gil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.123-130
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    • 2020
  • Nano seed incorporated in micro-sized 4BS (Tetrabasic lead Sulfate) seed was applied to the positive electrode active material and compared with Nano 4BS seed (NS). The dispersion of NS decreased due to the aggregation phenomenon, while the nano seed incorporated in micro-sized 4BS seed (INS) could confirm excellent dispersion. As the content of INS increased, the particle size of the active material became small and constant, which was confirmed through SEM and particle size analysis. The specific surface area for the reaction was increased and the high-rate discharge and lifetime characteristics were improved. In order to confirm the variation in particle size distribution in the plate manufacturing process, internal resistance and voltage were measured for 200 AGM lead-acid batteries, and it was confirmed that batteries quality variation decreased.

On wave dispersion properties of functionally graded plates resting on elastic foundations using quasi-3D and 2D HSDT

  • Bennai, Riadh;Mellal, Fatma;Nebab, Mokhtar;Fourn, Hocine;Benadouda, Mourad;Atmane, Hassen Ait;Tounsi, Abdelouahed;Hussain, Muzamal
    • Earthquakes and Structures
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    • v.22 no.5
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    • pp.447-460
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    • 2022
  • In this article, wave propagation in functional gradation plates (FG) resting on an elastic foundation with two parameters is studied using a new quasi-three-dimensional (3D) higher shear deformation theory (HSDT). The new qausi-3D HSOT has only five variables in fields displacement, which means has few numbers of unknowns compared with others quasi-3D. This higher shear deformation theory (HSDT) includes shear deformation and effect stretching with satisfying the boundary conditions of zero traction on the surfaces of the FG plate without the need for shear correction factors. The FG plates are considered to rest on the Winkler layer, which is interconnected with a Pasternak shear layer. The properties of the material graded for the plates are supposed to vary smoothly, with the power and the exponential law, in the z-direction. By based on Hamilton's principle, we derive the governing equations of FG plates resting on an elastic foundation, which are then solved analytically to obtain the dispersion relations. Numerical results are presented in the form of graphs and tables to demonstrate the effectiveness of the current quasi-3D theory and to analyze the effect of the elastic foundation on wave propagation in FG plates.