• 한국산업보건학회지
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• 제32권1호
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• pp.41-52
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• 2022

Objectives: This study intends to review the impact on cleaning workers and suggest directions for improvement by reviewing the legal and institutional ways in which Article 86 Nos. 7 and 16 of the Enforcement Decree of the Occupational Safety and Health Act work on the maintenance and promotion of cleaning workers' health. Methods: The following laws and systems were reviewed and considered: First, the occupational safety and health legislation obligated or required to be applied to protect the health of cleaning workers; Second, the status of control of chemicals or mixtures used at cleaning sites through the Consumer Chemicals Product and Biocide Safety Control Act; Third, Control of consumer products according to foreign material safety data sheet related laws. Results: Legal and institutional measures necessary to protect the health of cleaning workers include the legal control of harmful substances to be controlled, work environment monitoring, and special health examinations. The application of the Consumer Chemicals Product and Biocide Safety Control Act does not satisfy the legal and practical level of health maintenance and promotion required by the Occupational Safety and Health Act, and the communication of chemical information is insufficient. Overseas, there are restrictions on the use of consumer products in the workplace without material safety data sheets. Conclusions: It is necessary to improve the system to ensure the health of workers handling consumer chemical products. The remaining laws and regulations exempted from the obligation to prepare material safety data sheets should be additionally reviewed.

• 한국환경보건학회지
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• 제27권4호
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• pp.85-91
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• 2001

The regulation of Material safety data sheets(MSDS) was required for the chemicals in use in the workplace from July 1976. Under the provisions of the workplace hazardous materials information system, employers in Korea must be provided with accurate and comprehensive MSDS. To examine the reliability of MSDS for organic solvents, 63 organic solvents and MSDS were collected from the workplace of 39 companies located in Kyonggi province. Manufacture\`s MSDS were compared with the actual composition of the collected samples, and further examined the reliability by checking whether the chemicals analyzed were included in the MSDS correctly. 38 solvents were able to analyze their composition by gas chromatography-mass selective detector(GC-MSD). Among them, 28 solvents were incorrect in their composition and contents. In some case, health hazardous or carcinogenic chemicals which were not included in the MSDS were detected from samples. As a result of evaluating whether the MSDS correspond to the regulation required by Industrial Safety and Health Act (ISHA), the information in the MSDS including hazard classification, occupational exposure level, toxicity, regulatory information were incorrectly provided, and some MSDS did not disclose carcinogenic in their MSDS, and some MSDS were not written in the standard format. From this survey, continuous monitoring and promoting correct MSDS, and analyzing the components of the solvents were required to endure the reliability of MSDS for organic solvents.

• 한국산업보건학회지
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• 제22권4호
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• pp.276-283
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• 2012

Objectives: This study was conducted to survey the viewpoints on the material safety data sheets(MSDS) training for safety and health managers(SHMs) and workers. Subjects and Methods: A surveillance was made using a self-reported questionnaire for 78 SHMs and 122 workers to survey their viewpoints on the MSDS training. Survey results were analyzed using the SPSS program(Version 12.0 SPSS Inc., USA). Results: The result of the study shows that there are contrasts with the cognition of SHMs' and workers' on the education of MSDS and the program preference for education efficiency of MSDS. Workers were significantly more interested in the MSDS education than the SHMs did. Workers preferred the education program which is easily to be understood, to voluntarily participate on MSDS education, but SHMs did the quiz program. Also we found that the SHMs wanted to learn the education program via the expert(37.3%) rather than education resources(33.3%) which were served by government or relevant agency. In contrast, workers wanted the audio-visual education program, which is mainly consisted of accident cases (33.3%), rather than periodical education program(22.1%). Conclusions: This study showed that effectiveness of MSDS education was associated with the program served by company, and the education program for the voluntary participation of the workers should be made practical and attractive.

• 한국산업보건학회지
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• 제15권1호
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• pp.52-60
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• 2005

This study was carried to assess the accuracy of material safety data sheets (MSDS) for some water-soluble metalworking fluid (MWF) with respect to mono- ethanolamine(MEA), di-ethanolamine(DEA) and tri-ethanolamine (TEA). 39 fresh and 52 used MWFs for this study were taken from the workplace. The quantification and qualification of MEA, DEA and TEA were done using ion-chromatography. Three main findings of this study were 1) EA that was not addressed in material safety & data sheets (MSDS) was found to be enough higher than 1%, 2) 33.3% of 39 fresh MWF showed ingredient and concentration of MEA, DEA and TEA in MSDS and 3) the concentrations of MEA(20.5%), DEA(41.3%) and TEA(15.4%) were much higher than those indicated in MSDS. Consequently, we concluded that the accuracy on ingredients and concentrations of MEA, DEA and TEA provided in MWF was very low. Our study recommends that the limit concentration of chemical except for carcinogen that employer has to indicate in MSDS should be lowered from 1% to 0.1% .

• 한국위험물학회지
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• 제6권2호
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• pp.23-29
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• 2018

The fire and explosion properties necessary for waste, safe storage, transport, process design and operation of handling flammable substances are lower explosion limits(LEL), upper explosion limits(UEL), flash point, AIT( minimum autoignition temperature or spontaneous ignition temperature), fire point etc., An accurate knowledge of the combustion properties is important in developing appropriate prevention and control measures fire and explosion protection in chemical plants. In order to know the accuracy of data in MSDSs(material safety data sheets), the flash point of phenol was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of phenol was measured by ASTM 659E apparatus. The explosion limits of phenol was investigated in the reference data. The flash point of phenol by using Setaflash and Pensky-Martens closed-cup testers were experimented at $75^{\circ}C$ and $81^{\circ}C$, respectively. The flash points of phenol by Tag and Cleveland open cup testers were experimented at $82^{\circ}C$ and $89^{\circ}C$, respectively. The AIT of phenol was experimented at $589^{\circ}C$. The LEL and UEL calculated by using Setaflash lower and upper flash point value were calculated as 1.36vol% and 8.67vol%, respectively. By using the relationship between the spontaneous ignition temperature and the ignition delay time proposed, it is possible to predict the ignition delay time at different temperatures in the handling process of phenol.

• 디지털융복합연구
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• 제15권2호
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• pp.215-223
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• 2017

본 연구의 목적은 물질안전보건자료(MSDSs)의 인식정도와 영향을 미치는 근무환경특성이 무엇인지 분석함으로서 향후 치과재료에 대한 위험 유해성에 대한 인식을 개선하고자 대구 경북지역에 근무하는 치과위생사 238명을 조사하였다. 물질안전보건자료(MSDSs)의 항목별 중요도의 평균점수가 $3.98{\pm}0.59$점, 가장 높은 항목은 '유해 위험성'으로 나타났고 개선에 대한 필요도 평균점수는 $4.34{\pm}0.57$점으로 조사되었다. 개선필요도는 경력이 길어질수록 평균점수가 높아지고 항목별 중요도 차이는 치과 병원에 근무하는 대상자가 높은 점수를 보였다(p<0.01). 치과위생사들의 치과재료의 화학물질에 대한 안전을 확보하고 근로환경 질의 향상을 위하여 치과재료의 화학물질을 설명하고 있는 물질안전보건자료(MSDSs)에 대한 좀 더 적극적인 홍보 및 교육이 필요하며, 치과 병의원 근로자의 근로 안전을 위한 구체적인 정책 및 제도가 마련되어야 할 것이라 사료되어 진다.

• 한국산업보건학회지
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• 제18권1호
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• pp.62-71
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• 2008

The use of chemical products to enhance and improve life is a widespread practice worldwide. But alongside the benefits of these products, there is also the potential for adverse effects to people or the environment. As a result, a number of countries or organizations have developed laws or regulations over the years that require information to be prepared and transmitted to those using chemicals, through labels or Material Safety Data Sheets (MSDS). While these existing laws or regulations are similar in many respects, their differences are significant enough to result in different labels or MSDS for the same product in different countries. Given the reality of the extensive global trade in chemicals, and the need to develop national programs to ensure their safe use, transport, and disposal, it was recognized that a Globally harmonization system of classification and labeling of chemicals(GHS) would provide the foundation for such programs. This study offered complementary details of GHS classification criteria adopted in Korea by analyzing the differences in chemical classification system between UN and Korea Ministry of Labor. Also it is proposed that mutual agreement of information DB used is required by comparing classification results of chemicals in Korea, Japan, and EU. We offered the lists of information sources useful for chemical classification.

• 한국산업보건학회지
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• 제17권1호
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• pp.63-70
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• 2007

This study investigated the current management staus of chemical substance information on Material Safety Data Sheets(MSDS) and Chemical Information Cards(CIC) provided by Korea Occupational Safety & Health Agency(KOSHA) and also researched the kind and the characteristics of chemical substance information provided in other organizations. MSDS DB in Korean provided on KOSHANET(which is Kosha website) is 50,802 in total, among whom are single chemical substances with 31,870 kinds(18,932%) and are mixed chemical substances with 31,870 kinds(62.7%). The number of visiting MSDS DB on KOSHANET for the search of chemicals was 2,049,806. The number has increased each year. The CIC provided for workplaces is all 542 kinds : 14 harmful substances subject to permission, 168 harmful substances subject to management, 360 KOEL(Korean Occupational Exposure Limits) establishment substances. MSDS internationally provided by organizations producing MSDS DB was written with 16 sections, which is suitable for the writing basis of American Standards Institute(ANSI) and International Organization for Standardization(ISO) and provided chemical substance information on more than 100,000 kinds in most organizations.

• 한국콘텐츠학회논문지
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• 제18권11호
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• pp.540-549
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• 2018

본 연구는 대구 경북지역에서 근무하는 치과위생사 238명을 대상으로 자기기입식 설문을 통하여 근무유형별 치과재료에 대한 유해전달 실태를 파악하기위해 병원 유형별 유해인자 노출시간 및 근무환경특성 차이를 비교하고 물질안전보건자료(MSDS) 인지정도의 차이를 조사하였다. 연구 결과 병원 유형별 유해인자 노출시간을 비교한 결과 병원의 경우 화학물질에서 발생하는 분진유발에 노출되는 시간이 가장 길었고, 레진충전, 소독제 접촉 순으로 나타났다. 치과재료에 대한 물질안전보건자료(MSDS)를 인지하고 있는지에 대한 문항에 대하여 '인지한다'고 답한 대상자는 병원근로자는 37명(29.4%), 14명(12.5%)로 나타났으며(p<0.001), 치과재료를 사용하기 전 MSDS를 읽어본 경험이 있는 근로자는 병원근로자는 18명(14.3%), 의원근로자는 6명(5.4%)으로 조사되었다. 사용하는 치과재료의 물질안전보건자료(MSDS)를 비치한다고 응답한 대상자는 병원근로자의 경우 의원근로자에 비해 2.39배 물질안전보건자료(MSDS)를 비치하는 경우가 많았다. 이에 병원 유형별 특성에 맞게 화학물질의 건강상의 유해성에 대해 인지하고 안전보건교육을 지속적으로 실시함으로써 MSDS 정보에 대한 올바른 인식확립으로 근무환경이 개선되어져야 할 것이며, 치과재료의 제품에 사용설명서 및 MSDS 화학물질 정보제공 관리가 강화하여 전략적 접근 및 근로자의 알 권리를 보장할 수 있는 제도의 필요성을 제안한다.

• 한국산업보건학회지
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• 제28권1호
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• pp.91-99
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• 2018

Objectives: From a policy perspective, the introduction of confidential information reviews is a vital task for expanding workers' right to know and improving hazardous materials information communication. In this study, rational methods for introducing and administering confidential information reviews were examined as a part of advancing chemical information communication. Methods: The domestic status, social demands, and control cases from other countries about confidential information in material safety data sheets(MSDSs) were all examined. Additionally, principles for introducing MSDS confidential information review, what needs to be revised prior to its introduction, and procedures and manners of reviewing confidential information were suggested. Results and Conclusions: When composition information on MSDS needs to be protected in the EU and Canada, confidential information should be claimed and then approved by competent authorities with a principle of reviewing confidential information prior to rescinding information from MSDS. Applying the same principle, certain information on an MSDS that needs to be protected should be reviewed and approved in Korea. As a result, the MSDS is communicated with approval numbers replacing composition information. MSDS confidential information review has five steps, including deciding whether chemicals claimed to be confidential are excluded from applying for a confidentiality exemption, the names and concentration ranges of ingredients are adequate, and the claimed information is valid in terms of confidentiality.