• 제목/요약/키워드: Material Derivative

검색결과 213건 처리시간 0.022초

온도와 물성의 불확실성을 고려한 고무 마운트의 동특성 해석 (Analysis on the Dynamic Characteristics of a Rubber Mount Considering Temperature and Material Uncertainties)

  • 이두호;황인성
    • 한국전산구조공학회논문집
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    • 제24권4호
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    • pp.383-389
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    • 2011
  • 본 논문에서는 통계적인 방법을 이용하여 점탄성 제진재인 합성고무의 물성에 대한 변동성을 평가하는 방법을 제안하고 측정데이터를 이용하여 합성고무에 대한 평가를 수행하고 합성고무로 이루어진 고무 마운트에 대한 동특성 해석을 수행하였다. 고무 물성의 불확실성 인자로는 외기 온도의 변화와 실험 데이터의 오차 및 점탄성 물질모델의 오차를 고려하였다. 고무는 분수차 미분모델로 표현되었고, 온도의 영향은 비선형 이동계수모델을 도입하여 복소계수로 나타내어 동강성과 감쇠를 표현하였다. 이러한 물성모델을 바탕으로 고무에 대한 물성 실험데이터와 물성계수의 확률밀도함수 사이에 정의된 우도함수를 최대화하는 통계적 보정방법을 이용하여 물성모델의 물질계수들에 대한 변동성을 추정하였다. 합성고무로 이루어진 제진용 고무 마운트에 대하여 유한요소모델을 이용하여 동특성을 계산하였다. 동특성의 계산시 추정된 물성의 통계값을 적용하고 몬테카를로 해석을 통하여 동강성의 변동성을 살펴서 그 변동성이 매우 큼을 확인하였다.

$\tau$-H$_2$PC/oxadiazole 유기이층막의 감광특성 연구 (I) (Electrophotographic properties of $\tau$-H$_2$Pc/oxadiazole photoreceptor (I))

  • 이덕출;박구범;조기선;오승현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 추계학술대회 논문집
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    • pp.141-143
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    • 1993
  • A nontoxic organic photoreceptor for near infrared light has been developed. A double layered photoreceptor using $\tau$-H$_2$Pc as the CGL was made. The CTL was formed by oxadiazole derivative dispersed in two other host polymers. This photoreceptor has a charge acceptance of -900 V when a corona charge is used, and has residual potentials of -20 V for PC, and -10 V for PVB by light irradiation.

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Synthesis and Characterization of Crosslinkable Hole-Injection Transport Material for Polymer Light Emitting Diodes

  • Thi, Mai Nguyen;Kim, Jin-Woo;Vu, Quang Hung;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.810-813
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    • 2009
  • Fluorene derivatives are well-known in the polymer OLEDs due to their good charge carrying property. In this work, we synthesized a series of conjugated copolymers based fluorene derivative and phenylamine units by using Buchwald-Hartwig reaction in order to investigate their photoreactivities and use as the HIL/HTL layers of OLEDs using solution processes.

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TCNQ를 사용한 유기 발광 소자의 특성 변화 (Property change of organic light-emitting diodes using a TCNQ)

  • 나수환;이원재;홍진웅;정동회;한원근;김태완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.275-276
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    • 2009
  • We have studied physical properties of organic light-emitting diodes (OLEDs) in a device with 7,7,8,8-tetracyanoquinodimethane (TCNQ). Since the TCNQ has a high electron affinity, it is widely used for a charge-transport and injection layer. And the TCNQ-derivatives have also been used to control the conductivity of the materials. It is known that a charge injection and transport in OLEDs with a TCNQ-derivative enhances a performance of the devices such as operating voltage and efficiency. To see how the TCNQ affects on the device performance, we have made a reference device in a structure of ITO(170nm)/TPD(40nm)/$Alq_3$(60nm)/LiF(0.5nm)/Al(100nm). And several type of devices were manufactured by doping TCNQ either in TPD or $Alq_3$ layer. The TCNQ layer was also formed in between the organic layers. N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD), tri(8-hydroxy quinoline) aluminium ($Alq_3$), and TCNQ layers were formed by thermal evaporation at a pressure of $10^{-6}$ torr. The deposition rate was $1.0{\sim}1.5\;{\AA}/s$ for TPD, and $1.0{\sim}1.5\;{\AA}$ for $Alq_3$. The LiF was thermally evaporated at a deposition rate of $0.2\;{\AA}/s$ successively. The device with TCNQ-derivative improved the turn-on voltage compared to the one without TCNQ-derivative.

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A Study of the Development of CVD Precursors III-Synthesis and Properties of New Lead $\beta$-diketonate Derivatives

  • 임종태;이중철;이완인;이익모
    • Bulletin of the Korean Chemical Society
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    • 제20권3호
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    • pp.355-361
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    • 1999
  • To improve the volatility and stability of lead complexes, the principle of stabilization by saturating the metal coordination sphere by intramolecular coordination through a β-diketonates with an ethereal group has was tested. Several new lead complexes with alkoxyalkyl-substituted β-diketonates, Pb(R1C(O)CHC(O)(CH2)3OR2)2(Rl=t-Bu, Me, OMe, i-Pr, R2=Me, Et), or carboxylate, Pb(OC(O)(CH2)3OEt)2, were prepared by the reaction between Pb(OAc)2 and corresponding alkoxyalkyl-substituted β-diketonates, and they were found to have a viscous liquid phase. The nature of the head (β-diketonate or carboxylate) or tails and substituents of β-diketonates appeared not to be important for the formation of the liquid phase. It is worth mentioning that Pb(OAc)2, which has limited use due to its low solubility, was successfully adopted as a starting material for the preparation of new lead complexes. Easy hydrolysis, reaction with HCl, and 13C NMR spectra indicated that tail portions were not coordinated to the metal as a copper derivative, Cu(t-BuC(O)CHC(O)(CH2)3OMe)2. All these complexes were not volatile enough for the MOCVD experiments, but a methyl derivative, Pb(MeC(O)CHC(O)(CH2)3OEt)2, showed some sublimation. The methoxy derivative, Pb(MeOC(O)CHC(O)(CH2)3OEt)2, was thermally unstable due to possible equilibrium between species coordinating with a keto oxygen atom and an ethereal atom of a methoxy group, which was confirmed by IR and 13C NMR spectra.

하중경계조건의 변화에 대한 선형탄성문제의 민감도 해석 (Sensitivity Analysis of Linear Elastic Problem due to Variations of the Traction Boundary Conditions)

  • 이태원
    • 대한기계학회논문집
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    • 제15권6호
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    • pp.1852-1860
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    • 1991
  • 본 연구에서는 연구대상을 주어진 구조물 형상에서 경계조건의 변화에 따른 현상 설계민감도, 특히 하중경계조건의 변화에 따른 구조물의 변형에 주안점을 두었다. 이 연구결과는 가공물의 지지위치에 따른 가공면의 변형정도 향상 및 접촉문제 해석등 에 응용이 가능하다. 유도된 민감도가 정확함을 입증하기 위하여 예제로서 하중경계 조건의 변화에 따른 범함수로 정의된 변형의 변화량을 예측하는 문제를 선정하였다.

수정진동자를 이용한 자기조립된 Viologen 유도체의 계면전하이동 특성 (Surface Charge Transfer of Self-Assembled Viologen Derivative Using Quartz Crystal Microbalance)

  • 박상현;류길용;이동윤;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.256-257
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    • 2005
  • We fabricated self-assembled monolayers(SAMs) onto quartz crystal microbalance(QCM) using viologen, which has been widely used as electron acceptor and electron transfer mediator. The viologen derivative exist in three redox states, namely. These redox reactions are highly reversible and can be cycled many times without significant side reactions, respectively. We studied the characteristics of charge transfer using different electrolyte solutions by electrochemical quartz crystal microbalance (EQCM). From the data, the redox peak currents were nearly equal charges during redox reaction and existed to an excellent linear interrelation between the scan rates and first redox peak currents. The redox reactions of viologen were highly reversible and the EQCM has been employed to monitor the electrochemically induced adsorption of SAMs during the redox reactions.

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영구자석 동기전동기의 센서리스 속도제어 시스템 (A Novel Position Sensorless Speed Control Scheme for Permanent Magnet Synchronous Motor Drives)

  • 원태현;박한웅;송달섭;김문수;이만형
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계합동학술대회 논문집
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    • pp.112-116
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    • 2002
  • A sensorless control strategy for permanent magnet synchronous motors is presented in this paper. A speed control scheme based on the measurement and observation of stator current, voltage. and flux vector is proposed. Two phase voltages and two stator currents are measured and processed in discrete form in DSP. The rotor position and speed are estimated through the stator flux and its derivative estimation. Flux and its derivative are calculated in the stationary reference frame and used to estimate the speed and position. The rotor position angle is then used in a microcontroller to produce the appropriate stator current command signals for the hysteresis current controller of the inverter. The closed-loop speed control has been shown to be effective from standstill to rated speed. Moreover, a flux drift problem caused by the integration can be eliminated so that a stable sensorless starting and running operation can be achieved. Computer simulation and experimental results are presented to demonstrate the effectiveness of the proposed scheme.

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Optical study of environmental and light induced effects on 8-hydroxyquinoline derivative metal complex small molecules thin films

  • Shukla, Vivek Kumar;Datta, Debjit;Kumar, Satyendra
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.629-631
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    • 2004
  • We report on the synthesis and film formation on a variety of small molecules such as $Alq_3$, $Znq_2$, and $Inq_3$, used as light emitting material in organic light emitting diodes (OLEDs) . The organic materials are usually susceptible to environmental aging and photo-oxidation, which influences their viability for commercial utility. Here, we examine the effects of oxygen and light on these organic materials to enhance the efficiency and lifetime of OLEDs. Optical techniques - ellipsometry, photoluminescence and infrared spectroscopies- have been used to study of environmental and light induced effects on 8-hydroxyquinoline derivative metal complex small molecules thin films

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일반 경계 조건을 가진 얇은 물체에 대한 직접 경계 요소법의 개발 (Development of the Direct Boundary Element Method for Thin Bodies with General bBundary Conditions)

  • 이강덕;이덕주
    • 소음진동
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    • 제7권6호
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    • pp.975-984
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    • 1997
  • A direct boundary element method (DBEM) is developed for thin bodies whose surfaces are rigid or compliant. The Helmholtz integral equation and its normal derivative integral equation are adoped simultaneously to calculate the pressure on both sides of the thin body, instead of the jump values across it, to account for the different surface conditions of each side. Unlike the usual assumption, the normal velocity is assumed to be discontinuous across the thin body. In this approach, only the neutral surface of the thin body has to be discretized. The method is validated by comparison with analytic and/or numerical results for acoustic scattering and radiation from several surface conditions of the thin body; the surfaces are rigid when stationary or vibrating, and part of the interior surface is lined with a sound-absoring material.

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