• 제목/요약/키워드: Material Composition

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사암계 석탄폐석을 활용한 E-glass fiber 조성의 유리 제조 및 특성 (Fabrication and characterization of glass with E-glass fiber composition by using silica-alumina refused coal ore)

  • 이지선;임태영;이미재;황종희;김진호;현승균
    • 한국결정성장학회지
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    • 제23권4호
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    • pp.180-188
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    • 2013
  • 삼척도계지역의 탄광에서 석탄채굴시에 부산물로 발생되는 사암계 석탄폐석을 원료로 사용하여 E-glass fiber 조성의 유리를 제조하였다. 본 연구에서는 카본함량이 비교적 적은 실리카-알루미나질의 사암계 석탄폐석을 사용하였으며, 폐석의 투입량을 0~35 %까지 변화시켰다. 서로 다른 석탄폐석 투입량을 갖는 배치원료를 $1550^{\circ}C$에서 2시간 용융하여 E-glass조성을 갖는 투명하고 맑은 유리가 얻어졌고, 81~84 %의 높은 가시광투과율, $5.39{\sim}5.61{\times}10^{-6}/^{\circ}C$의 열팽창계수, 851~$860^{\circ}C$의 연화점을 나타내었다. 유리섬유 시편은 $1150^{\circ}C$에서 섬유인상장치를 통해 얻어졌고, 복합재료의 보강용 유리섬유로서 내화학성 시험과 기계적 특성평가를 위한 인장강도를 측정하였다. 그 결과 석탄폐석을 사용한 E-glass fiber의 특성이 석탄폐석을 사용하지 않은 보통 E-glass 섬유에 비해 충분히 양호한 특성을 나타내어 E-glass 섬유용 원료로서 석탄폐석의 활용가능성을 확인할 수 있었다.

LiNi1/3Mn1/3Co1/3O2계 정극활물질을 적용한 전극 제조조건 최적화 연구 (A Study on Optimization of Manufacturing Condition for LiNi1/3Mn1/3Co1/3O2-based Cathode Electrode)

  • 김현수;김성일;이창우;문성인;김우성
    • 한국전기전자재료학회논문지
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    • 제19권2호
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    • pp.139-144
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    • 2006
  • A fabrication condition of the cathode electrode was optimized in a lithium secondary battery. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ powders were used as a cathode material. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$/Li cells were prepared with a certain formulation and their cycleability and rate-capability were evaluated. Optimum electrode composition simulated from the evaluated value was 86.3: 5.6: 8.1 in mass $\%$ of active material: binder: conducting material. Discharge capacity decreased markedly as the press ratio exceeded $30\%$ during preparation of the electrode. Discharge performance at a high current rate deteriorated abruptly as the electrode thickness was over $120{\mu}m$.

고정밀급 박막저항을 위한 NiCr/NiCrSi박막의 제조 및 전기적 특성 (Electrical Characteristics and Fabrication of NiCr/NiCrSi Alloy Film for High Precision Thin Film Resistors)

  • 이붕주
    • 한국전기전자재료학회논문지
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    • 제20권6호
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    • pp.520-526
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    • 2007
  • In order to acquire fundamental informations to fabricate high precision thin film resistors, NiCr/NiCrSi alloy films were prepared using Ni and Cr targets. Effect of composition on the electrical properties of the NiCr/NiCrSi alloy film were then investigated. Considering the effect of Si doping on the electrical and material characteristics, the lower TCR (temperature coefficient of resistance) values could be achieved for samples with Ni/Cr ratio of $0.8{\sim}1.5$ (in a range of relative higher specific resistivity and Cr composition of $40\;wt%{\sim}55\;wt%$) and with Si doping. Consequently, the sample prepared using a DC power showed a good TCR of $-25\;ppm/^{\circ}C$, which implies that increase of specific resistivity and decrease of TCR would be achieved more efficiently not for Ni-Cr binary material but for Si doped Ni-Cr ternary material, and not using RF power but using DC power in the sputtering process.

화염분무열분해법을 이용한 구형의 고결정성 리튬 과잉 양극재 제조 (Synthesis of Li-rich Cathode Material with Spherical Shape and High Crystallinity by Using Flame Spray Pyrolysis)

  • 임성남
    • 신재생에너지
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    • 제20권3호
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    • pp.20-27
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    • 2024
  • A Li-rich cathode material, Li1.167Mn0.548Ni0.18Co0.105O2, with a spherical shape and high crystallinity, is prepared using flame spray pyrolysis. The post-heat treatment condition influences the properties of the prepared material, such as its structure, morphology, and chemical composition, and optimum performance is achieved at 900℃. Various excess Li contents (0-12 wt.%) are introduced in the precursor solution to compensate for volatilized Li during synthesis, bringing it close to the target composition. Compensation for volatilized Li enhances the electrochemical performance, i.e., the Li-compensated sample shows a good discharge capacity of 247 mAh g-1 at a current density of 20 mA g-1 in a potential window of 4.6-2.5 V. In addition, the prepared Li-rich cathode material supplemented with 9 wt.% of the Li source shows increased discharge capacity of 175 and 148 mAh g-1 at 200 and 400 mA g-1, respectively, compared with those of a bare sample (164 and 127 mAh g-1, respectively).

구성형태(構成形態)와 구성비율별(構成比率別)로 제조(製造)한 슬러지-파티클보드의 물리적(物理的) 및 기계적(機械的) 성질(性質) (Physical and Mechanical Properties of Sludge-Particle Board Manufactured by Composition Types and Composition Ratios from Mixed or Layered Paper Sludge and Wood Particle)

  • 이필우;윤형운
    • Journal of the Korean Wood Science and Technology
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    • 제24권1호
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    • pp.17-26
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    • 1996
  • This research was accomplished to evaluate possibility of using paper sludge for the raw materials of wood based panel products. The experimental panels were manufactured by four mixed ratios, the proportion of paper sludge to wood particle: 20:80, 30:70, 40:60, 50:50% (oven dry weight basis) and by three composition types, sludge-particle mixed board, three layered sludge-particle board and three layered particle board. They were tested mechanical (bending strength and internal bond) and physical properties (water absorption, thickness swelling and linear expansion). From the results they were shown that bending strength of mixed and three layered sludge-particle board were decreased with increasing of composition ratios of sludge. And the mechanical and physical properties of the boards of three layered composition types have superior to those of mixed composition type. Although composition ratios of sludge increased, the internal bond strength and dimensional stability of sludge-particle board not decreased quantitatively. We concluded that the mechanical and physical properties of three layered sludge-particle board were similar w those of three layered particle-board (control) made by our laboratory design. Therefore, it was recognized that paper sludge can be used as potential raw material in particle-board manufacturing industry.

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Study of MgSrO and MgCaO thin films as protective layers for PDPs

  • Matulevich, Y.T;Moon, Sung-Hwan;Choi, Jong-Seo;Zang, Dong-Sik
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.181-183
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    • 2009
  • Comparative study of the dependence of the firing voltage of MgSrO and MgCaO protective layers on chemical composition was carried out. It was observed that the firing voltage increases when CaO/MgO or SrO/MgO ratio increases.

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전자빔 증착으로 제조한 $CuInS_2$ 박막의 구조적 및 광학적 특성 (Structural and optical properties of $CuInS_2$ thin films fabricated by electron-beam evaporation)

  • 박계춘;정운조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.193-196
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    • 2001
  • Single phase $CuInS_2$ thin film with the highest diffraction peak (112) at diffraction angle $(2\theta)$ of $27.7^{\circ}$ and the second highest diffraction peak (220) at diffraction angle $(2\theta)$ of $46.25^{\circ}$ was well made with chalcopyrite structure at substrate temperature of $70^{\circ}C$, annealing temperature of $250^{\circ}C$, annealing time of 60 min. The $CuInS_2$ thin film had the greatest grain size of $1.2{\mu}m$ and Cu/In composition ratio of 1.03. Lattice constant of a and c of that $CuInS_2$ thin film was 5.60 A and 11.12 A respectively. Single phase $CuInS_2$ thin films were accepted from Cu/In composition ratio of 0.84 to 1.3. P-type $CuInS_2$ thin films were appeared at over Cu/In composition ratio of 0.99. Under Cu/In composition ratio of 0.96, conduction types of $CuInS_2$ thin films were n-type. Also, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of p-type $CuInS_2$ thin film with Cu/In composition ratio of 1.3 was 837 nm, $3.0{\times}104cm^{-1}$ and 1.48 eV respectively. When Cu/In composition ratio was 0.84, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of n-type $CuInS_2$ thin film was 821 nm, $6.0{\times}10^4cm^{-1}$ and 1.51 eV respectively.

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전자빔 층착으로 제조한 $CuInS_2$ 박막의 구조적 및 광학적 특성 (Structural and optical properties of $CuInS_2$ thin films fabricated by electron-beam evaporation)

  • 박계춘;정운조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.193-196
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    • 2001
  • Single phase CuInS$_2$ thin film with the highest diffraction peak (112) at diffraction angle (2$\theta$) of 27.7$^{\circ}$ and the second highest diffraction peak (220) at diffraction angle (2$\theta$) of 46.25$^{\circ}$ was well made with chalcopyrite structure at substrate temperature of 70 $^{\circ}C$, annealing temperature of 25$0^{\circ}C$, annealing time of 60 min. The CuInS$_2$ thin film had the greatest grain size of 1.2 ${\mu}{\textrm}{m}$ and Cu/In composition ratio of 1.03. Lattice constant of a and c of that CuInS$_2$ thin film was 5.60 $\AA$ and 11.12 $\AA$ respectively. Single phase CuInS$_2$ thin films were accepted from Cu/In composition ratio of 0.84 to 1.3. P-type CuInS$_2$ thin films were appeared at over Cu/In composition ratio of 0.99. Under Cu/In composition ratio of 0.96, conduction types of CuInS$_2$ thin films were n-type. Also, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of p-type CuInS$_2$ thin film with Cu/In composition ratio of 1.3 was 837 nm, 3.0x10 $^4$ $cm^{-1}$ / and 1.48 eV respectively. When CuAn composition ratio was 0.84, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of n-type CuInS$_2$ thin film was 821 nm, 6.0x10$^4$ $cm^{-1}$ / and 1.51 eV respectively.

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레시틴이 함유된 경피 약물전달용 용해성 마이크로니들의 제작과 특성 (Fabrication and Characterization of Dissolving Microneedles Containing Lecithin for Transdermal Drug Delivery)

  • 최원호;김범상
    • Korean Chemical Engineering Research
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    • 제59권3호
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    • pp.429-434
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    • 2021
  • 약물의 피부 투과성을 향상시키기 위해 고안된 방법 중 하나인 용해성 마이크로니들의 재료로서 레시틴의 적용 가능성을 평가하고, 레시틴의 조성이 마이크로니들의 기계적 강도와 용해성, 그리고 최종적으로 rhodamine B (RhB)의 피부 투과성에 미치는 영향을 조사하였다. 마이크로니들용 몰드를 제작하는 기존의 포토리소그래피 방법에 비해서 간단하고 효율적인 laser-writing 기법을 이용하여 제작한 몰드로 균일한 모양과 크기의 바늘을 가진 용해성 마이크로니들을 제작하였다. 마이크로니들 내 레시틴의 조성은 바늘의 기계적 강도와 용해성에 영향을 미쳤으며, 그 결과 바늘 내 레시틴의 조성이 증가함에 따라서 바늘의 기계적 강도가 증가하고 최종적으로 마이크로니들에 탑재된 RhB의 피부 투과성이 향상되었다. 레시틴 대신 동일한 조성의 amylopectin (AP)가 함유된 마이크로니들과 비교하여 보면, 레시틴이 포함된 마이크로니들의 RhB 피부 투과성이 더 높은 것을 볼 수 있었다. 이러한 결과들은 레시틴이 용해성 마이크로니들의 재료로 사용될 수 있으며, 그 조성을 변화함에 따라서 마이크로니들의 피부에 대한 약물의 투과성을 제어할 수 있는 가능성이 있음을 보여준다.

Optimization of Lithium in Li1+x[Mn0.720Ni0.175Co0.105]O2 as a Cathode Material for Lithium Ion Battery

  • Kim, Jeong-Min;Jeong, Ji-Hwa;Jin, Bong-Soo;Kim, Hyun-Soo
    • Journal of Electrochemical Science and Technology
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    • 제2권2호
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    • pp.97-102
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    • 2011
  • Different amounts of excess lithium in the range of x = 0~0.3 were added to $Li_{1+x}[Mn_{0.720}Ni_{0.175}Co_{0.105}]O_2$ cathode materials synthesized using the co-precipitation method to investigate its microstructure and electrochemical properties. Pure layered structure without impurities was confirmed in the XRD pattern analysis and increasing peak intensity of $Li_2MnO_3$ was observed along with the addition of over 0.2 mol Li. The initial discharge capacity of the stoichiometric composition was determined to be 246 mAh/g, while the discharge capacity of the addition of 0.1 mol Li was obtained to be 241 mAh/g, which was not significantly different from that of the stoichiometric composition. However, the discharge capacities decreased dramatically after the addition of 0.2 and 0.3 mol Li to 162 mAh/g and 146 mAh/g, respectively. In the rate capability test, the active $Li_{1+x}[Mn_{0.720}Ni_{0.175}Co_{0.105}]O_2$ cathode material of the stoichiometric composition showed a dramatic decrease in its discharge capacity with increasing C-rate, as evidenced by the result that the discharge capacity at 5C was 13% compared with 0.1C. On the other hand, the discharge capacity of compositions containing excess lithium was improved at higher current rates. The cycling test showed that the composition containing an excess of 0.1 mol Li had the most outstanding capacity retention.