• 제목/요약/키워드: Mass transfer limitation

검색결과 28건 처리시간 0.029초

삼각단면 극소히트파이프의 작동특성에 관한 기초 연구 (Fundamental study on performance characteristics of a micro heat pipe with triangular cross section)

  • 문석환;김종오;김철주
    • 설비공학논문집
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    • 제11권2호
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    • pp.176-184
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    • 1999
  • Numerical and experimental studies were performed to examine the characteristics of heat and mass transfer processes for a Micro Heat Pipe(MHP) with a triangular cross-section. Solutions on mass flow rate, pressure variation, and radius of meniscus were obtained using the mathematical model developed by Faghri and Khrustalev. To obtain an increase in capillary limitation, a triangular tube with curved walls was designed and fabricated. The measurement by microscope showed that the radius at corners of the tube was ranging between 0.03-0.05mm. Performance test for MHPs using the triangular tube with curved walls proved a substantial increasement in heat transport limitation, with 4.5W and 2.0W in case of using water and ethanol as a working fluid, respectively. In the previous study by Faghri a limitation of 0.5W was reported for a water MHP with a regular triangular tube.

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Estimation of the Chestnut Mass Transfer Coefficient through its Microscopic Structure - Chestnut Mass Transfer Coefficient through its Microscopic Structure -

  • Xu, Hui Lan;Chung, Woo-Yang
    • Journal of the Korean Wood Science and Technology
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    • 제40권5호
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    • pp.352-362
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    • 2012
  • Mass transfer behavior in wood was estimated through its microscopic structure. The diffusion coefficients which were decided by theoretical equations are influenced by different anatomical properties of wood. From the experiment, the moisture flux was linear to the square root of time. The diffusion coefficients had a regular tendency during the time elapse. During the modeling, it is necessary to understand the limitation of parameters and consider the particular situation to be simulated. In hardwood, because the apertures were not considered, tangential mass transfer simulation was totally different from experiment. As a result, a hardwood model design should consider the apertures which are even on the fiber walls.

냉각 평판에서 서리 성장 모델링 (Modeling for Frost Growth on a Cold Plate)

  • 양동근;이관수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1546-1551
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    • 2004
  • This paper presents a mathematical model to predict the frost properties and heal and mass transfer within the frost layer formed on a cold plate. The laminar flow equations for the air-side are analyzed. and the empirical correlations of local frost properties are employed in order to predict the frost layer growth. The correlations of local frost density and effective thermal conductivity of frost layer, obtained from various experimental conditions, are derived as functions of various frosting parameters (Reynolds number, frost surface temperature, absolute humidity and temperature of moist air, cooling plate temperature, and frost density). The numerical results are compared with experimental data and the results of various models to validate the present model, and agree well with experimental data within a maximum error of 10%. The heat and mass transfer coefficients obtained from the numerical analyses are presented, as the results, it is found that the model for frost growth using the correlation of heat transfer coefficient without solving air flow have a limitation in its application.

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Gas sparged gel layer controlled cross flow ultrafiltration: A model for stratified flow regime and its validity

  • Khetan, Vivek;Srivastava, Ashish;De, Sirshendu
    • Membrane and Water Treatment
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    • 제3권3호
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    • pp.151-168
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    • 2012
  • Gas sparging is one of the techniques used to control the concentration polarization during ultrafiltration. In this work, the effects of gas sparging in stratified flow regime were investigated during gel layer controlling cross flow ultrafiltration in a rectangular channel. Synthetic solution of pectin was used as the gel forming solute. The liquid and gas flow rates were selected such that a stratified flow regime was prevalent in the channel. A mass transfer model was developed for this system to quantify the effects of gas flow rates on mass transfer coefficient (Sherwood number). The results were compared with the case of no gas sparging. Gas sparging led to an increase of mass transfer coefficient by about 23% in this case. The limitation of the developed model was also evaluated and it was observed that beyond a gas flow rate of 20 l/h, the model was unable to explain the experimental observation, i.e., the decrease in permeate flux with flow rate.

생촉매의 수분함유량이 기상의 연속반응에 미치는 영향 (Effect of Moisture Content of Biocatalyst on the Gas Phase Continuous Bioreaction)

  • 황순옥
    • KSBB Journal
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    • 제8권5호
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    • pp.417-423
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    • 1993
  • 생촉매의 수분함량이 기상에서의 연속반응기의 성능에 미치는 영향을 물질전달제한에 대한 연구와 함께 조사하였다. 각각 46.2%와 37.2%의 수분을 함유한 생촉매가 알코올 옥시데이즈 효소의 엠버라이트 IRA-400에로의 고정화 및 저속의 탈수화에 따라 준비되어져, 컬럼에 채워졌다. 연속식 기상반응에서의 상대생산속도(RPR)와 아세트알데하이드 조성($X_p$) 및 전환율(X)이 비교되었고 37.2%의 경우가 46.2%의 경우보다 우수하였는데 이는 기상에서의 물질전달 향상에 따른 것으로 판단되었다.

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AC Impedance Study of Hydrogen Oxidation and Reduction at Pd/Nafion Interface

  • Song, Seong-Min;Koo, Il-Gyo;Lee, Woong-Moo
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.231-238
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    • 2001
  • Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

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코발트 금속 폼 촉매와 열교환형 반응기를 이용한 Fischer-Tropsch 합성 반응 (Fischer-Tropsch synthesis in the novel system: cobalt metallic foam catalyst and heat-exchanger typed reactor)

  • 양정일;양정훈;고창현;김학주;천동현;이호태;정헌
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.133.2-133.2
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    • 2010
  • Fischer-Tropsch synthesis (FTS) was carried out in heat-exchanger typed reactor with cobalt metallic foam catalyst. Considering the heat and mass transfer limitations in the cobalt catalyst, a Co-foam catalyst with an inner metallic foam frame and an outer cobalt catalyst was developed. The Co-foam catalyst was highly selective toward liquid hydrocarbon production and the liquid hydrocarbon productivity at $203^{\circ}C$ reached to $52.5ml/(kg_{cat}{\cdot}h)$, which was higher than that obtained by the Co-pellet. Furthermore, the heat-exchanger typed reactor was developed to efficiently control the highly exothermic reaction heat. The reaction heat generated in the FTS reaction on the cobalt active site was easily transferred to reactor wall by the metallic foam in the catalyst and the transferred reaction heat was directly removed by the hot oil which circulated the wall side of the heat-exchanger typed reactor.

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Oxygen Transfer Rate Coefficient of Membrane Aeration Bioreactor for Vero Cell Culture

  • 전주미;정연호;김익환;이상종;장용근;전계택
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2002년도 생물공학의 동향 (X)
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    • pp.269-270
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    • 2002
  • Oxygen is a key substrate in animal cell metabolism and its consumption is thus a parameter of great interest for monitoring and control in animal cell culture bioreactor. The use of a gas-permeable membrane offered the possibility to provide the required quantity of oxygen into the culture. while avoiding problems of foaming or shear damage generally linked to sparging. For determining the optimum DO control strategy of this gas-permeable membrane aeration bioreactor, the oxygen transfer rate coefficient was measured with varying $N_2$ ratio in inlet air. The results showed that an increasing mass flow rate of nitrogen reduced the $K_La$ value. and 5% nitrogen in air did not result in any oxygen limitation.

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Modelling and numerical simulation of concrete structures subject to high temperatures

  • Ostermann, Lars;Dinkler, Dieter
    • Coupled systems mechanics
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    • 제3권1호
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    • pp.73-88
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    • 2014
  • The paper deals with a model founded on the physical processes in concrete subject to high temperatures. The model is developed in the framework of continuum damage mechanics and the theory of porous media and is demonstrated on selected structures. The model comprises balance equations for heat transfer, mass transfer of water and vapour, for linear momentum and for reaction. The balance equations are completed by constitutive equations considering the special behaviour of concrete at high temperatures. Furthermore, the limitation and decline of admissible stresses is achieved by using a composed, temperature depending crack surface with a formulation for the damage evolution. Finally, the complete coupled model is applied to several structures and to different concrete in order to determine their influence on the high-temperature-behaviour.

전기장에 의해 생성된 미세기포를 이용한 페놀의 오존산화 (Oxidation of Phenol Using Ozone-containing Microbubbles Formed by Electrostatic Spray)

  • 신원태;정유진;성낙창
    • 대한환경공학회지
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    • 제27권12호
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    • pp.1292-1297
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    • 2005
  • 상수나 하수처리장에서 쓰이는 오존처리는 물질전달에 제약을 받는 공정임은 알려져왔다. 이런 물질전달의 한계를 극복하는 방법으로 매우 효과적인 것은 오존가스를 함유한 기포의 크기를 줄임으로써 물질전달에 필요한 접촉면적을 넓히는 것이다. 오존의 전달을 크게 하기 위한 방법으로서 본 연구에서는 전기장분사(Electrostatic spraying: ES)를 사용하였다. 실험에서는 ES와 기포발생판을 비교하였는데 ES실험에서는 전압을 0 kV에서 4 kV 범위까지 높여주어 물질전달효과를 살펴보았고 기공크기가 다른 두 가지 기포발생판(미세기공: 기공크기 $10{\sim}15{\mu}m$, 중간기공: 기공크기 $40{\sim}60{\mu}m$)을 사용하여 물질전달효율을 비교 분석 하였다. 물질전달효율은 시간의 경과에 따른 용존오존농도의 측정과 페놀의 산화시간으로 간접 계산하였다. 실험 결과 ES의 경우 전압을 0 kV에서 4 kV까지 올렸을 때 기포의 크기가 작아짐으로 인해 오존전달율을 약 40% 정도 향상시킬 수 있었다. 또한 ES와 기포발생판의 물질전달 비교실험에서 미세기공 기포발생판보다 4 kV의 ES가 더 효과적임을 알 수 있었다.