• KEPCO Journal on Electric Power and Energy
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• 제5권3호
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• pp.181-188
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• 2019

본 연구에서는 발전시스템의 설계 입출력변수들을 Heat & Mass balance 계산 solver 및 최적화 알고리즘과 연계하고 반복계산 과정을 자동화함으로써 기술 및 경제적 측면을 고려한 최적의 발전시스템 Heat & Mass balance 설계를 도출하는 최적설계 자동화 기법을 개발하였다. 그리고 이에 대한 효과를 분석하기 위하여 발전소 형식별 10종에 대하여 최적설계 기법을 적용한 결과, NPV 및 IRR에 대한 개선 효과를 기대할 수 있었다.

• 한국토양비료학회지
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• 제24권2호
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• pp.124-129
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• 1991

Batch 측정법(測定法)은 농약(農藥)의 토양중(土壤中) 흡착량(吸着量) 측정(測定)에 사용되는 가장 일반적인 방법(方法)이다. 이 Batch 측정법(測定法)은 토양용액중(土壤溶液中)의 농약농도변화(農藥濃度變化)로부터 간접적으로 흡착량(吸着量)을 측정(測定)하기 때문에 흡착력(吸着力)이 낮은 토양(土壤)에서는 용액중(溶液中)의 농도변화(濃度變化)가 작아 흡착측정(吸着測定)이 어렵거나 불가능(不可能)하다. 본(本) 시험(試驗)에서는 용액중(溶液中)의 농약(農藥)의 농도(濃度)를 측정(測定)함과 동시(同時)에 토양(土壤)에 흡착(吸着)된 농약(農藥)을 직접 추출하여 흡착량(吸着量)을 측정(測定)하는 방법(方法)을 설정(設定)하고 Mass balance 방법(方法)이라고 이름하였다. 용액중(溶液中) 농도(濃度) 및 토양에 흡착(吸着)된 농약(農藥)을 직접 추출하여 흡착량(吸着量)을 측정(測定)하는데 일정한 임의의 측정오차(測定誤差)를 설정(設定)하고 Batch 방법(方法)과 Mass balance 방법(方法)을 비교(比較)한 가설시험결과(假設試驗結果) Mass balance 방법(方法)이 측정오차(測定誤差)를 크게 줄일수 있을 것으로 판단(判斷)되었다. 이 가설시험(假設試驗)을 Wahiawa 토양(土壤) 0-20cm, 40-60cm, 100-120cm와 Salinas 토양(土壤) 0-15cm, 115-130cm 깊이에서 얻는 5개(個) 토양시료(土壤試料)에서 실증(實證)한 결과(結果) Mass balance방법(方法)은 모든 토양(土壤)에서 측정요차(測定誤差)를 경감(輕減) 시킬수 있었으며, 특(特)히 흡착력(吸着力)이 낮은 Wahiawa 토양(土壤) 100-120cm의 토양(土壤)에서 측정오차(測定誤差)를 크게 줄일 수 있었다.

• 한국환경과학회지
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• 제17권4호
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• pp.359-364
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• 2008

PM10 samples were collected from July 2007 to Oct. 2007 at Gwaebopdong(inland area) and Dongsamdong(coastal area), in Busan. This paper investigates the contribution of emission sources to PM10 mass in Busan. Source apportionment results derived from the chemical mass balance(CMB) method. A source profiles applied in this study is organized to minimize the collinearity among sources type via statistical method. Source profiles applied in this study utilized a measured value of fine particle directly sampled from metropolitan area such as Seoul and Incheon, After a CMB modeling, sulfate and nitrate related sources among those contributing to PM10 in Busan showed high contribution by 36.53% in Gwaebopdong and 42.02% in Dongsamdong.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2006년도 춘계학술대회논문집
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• pp.314-319
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• 2006

Main focus on balance shaft module is to reduce the vibration triggered from engine block and compensate it from unbalance mass in balance shaft. Since the performance of balance shaft module is controlled by rotor shape including unbalance mass, a design strategy on rotor is key issue on determine the quality of balance shaft system. Even the design result on balance shaft mostly affect the lay-out of housing and other related components, its issue on balance shaft should be considered in advance throughout the total design procedure. In this paper, optimal design strategy focused on balance shaft is presented to make a design process efficiently with ensuring its high performance. And its method is verified with field design process of balance shaft in commonly adapted vehicle with 3-cylinder and 4-cylinder engine.

• 상하수도학회지
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• 제37권6호
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• pp.347-361
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• 2023

Water utilities are making various efforts to reduce water losses from water networks, and an essential part of them is to recognize the moment when a pipe burst occurs during operation quickly. Several physics-based methods and data-driven analysis are applied using real-time flow and pressure data measured through a SCADA system or smart meters, and methodologies based on machining learning are currently widely studied. Water utilities should apply various approaches together to increase pipe burst detection. The most intuitive and explainable water balance method and its procedure were presented in this study, and the applicability and detection performance were evaluated by applying this approach to water supply pipelines. Based on these results, water utilities can establish a mass balance-based pipe burst detection system, give a guideline for installing new flow meters, and set the detection parameters with expected performance. The performance of the water balance analysis method is affected by the water network operation conditions, the characteristics of the installed flow meter, and event data, so there is a limit to the general use of the results in all sites. Therefore, water utilities should accumulate experience by applying the water balance method in more fields.

• 분석과학
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• 제30권5호
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• pp.226-233
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• 2017

In general, quantitative chemical analysis in various areas including food, the environment, in vitro diagnostics, etc., requires traceability in order to increase the reliability of the measurements. Measurement traceability is a property of an unbroken chain of comparisons relating an instrument's measurements to SI units. Purity analysis is the first process for establishing traceability to SI units in chemical measurements. The purpose of this study is to develop and validate a method of purity assignment for establishing the traceability of $17{\beta}$-estradiol measurements in an in vitro diagnostics field. The establishment of this method is very important as it can be applied to the development of CRM and to the analysis of the purity of other hormones. The method of assignment of the purity of $17{\beta}$-estradiol was developed using the mass balance method and was validated through participation in an International comparison. In the mass balance method, impurities are categorized into four classes as follows: total related structure impurities, water, residual organic solvents, and nonvolatiles/inorganics. In this study, total related structure impurities were characterized by a gas chromatography-flame ionization detector (GC-FID) and a high-performance liquid chromatography-ultraviolet (HPLC-UV) detector, water content was determined by a Karl-Fisher coulometer, and total residual solvents and nonvolatiles/inorganics were checked simultaneously by thermogravimetric analysis (TGA). The purity of the $17{\beta}$-estradiol was 985.6 mg/g and the expanded uncertainty was 2.1 mg/g at 95% confidence. The developed method can be applied to the development of certified reference materials, which play a critical role in traceability.

• Environmental Engineering Research
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• 제20권2호
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• pp.191-197
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• 2015

The first objective of this study was to discuss the applicability of the $CO_2/CH_4$ ratio method in order to assess $CH_4$ oxidation efficiency. To achieve this objective, a comparison between $CO_2/CH_4$ ratios and the mass balance method was conducted. The second objective of this study was to estimate the $CH_4$ oxidation efficiency in an interim landfill soil cover and assess how a $CH_4$ influx influences the $CH_4$ oxidation efficiency. The results showed that despite the $CO_2$ problems brought by respiration, the $CH_4$ oxidation efficiencies obtained by the $CO_2/CH_4$ ratio method led to similar results compared to the mass balance method. In this respect, the $CO_2/CH_4$ ratio method can be an indicator of the $CH_4$ oxidation efficiencies for landfill cover soils. The $CH_4$ oxidation efficiencies derived in this study through the $CO_2/CH_4$ ratio method ranged between 46% and 64%, and between 41% and 62% through the mass balance method. The results imply that the Intergovernmental Panel on Climate Change's (IPCC) default value of 10% for the $CH_4$ oxidation efficiency is an underestimation for landfill cover soils. $CH_4$ oxidation efficiency tends to be negatively correlated with $CH_4$ influx. Therefore, $CH_4$ influx reaching a landfill cover should be limited in order to increase the $CH_4$ oxidation efficiency.

• Natural Product Sciences
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• 제25권3호
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• pp.222-227
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• 2019

Quantitative nuclear magnetic resonance (qNMR) is a well-established method adopted by international pharmacopoeia for quantitative and purity analyses. Emodin is a type of anthraquinone, well known as the main active component of Fabaceae, Polygonaceae and Rhamnaceae. Purity analysis of emodin is usually performed by using the high-performance liquid chromatography (HPLC)-UV method. However, it cannot detect impurities such as salts, volatile matter, and trace elements. Using the qNMR method, it is possible to determine the compound content as well as the nature of the impurities. Several experimental parameters were optimized for the quantification, such as relaxation delay, spectral width, number of scans, temperature, pulse width, and acquisition time. The method was validated, and the results of the qNMR method were compared with those obtained by the HPLC and mass balance analysis methods. The qNMR method is specific, rapid, simple, and therefore, a valuable and reliable method for the purity analysis of emodin.

• 대한토목학회논문집
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• 제28권5B호
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• pp.475-483
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• 2008

사고 등으로 인해 하천에 순간적으로 주입되는 오염물질의 2차원 이송-확산을 모의하기 위하여 SUPG법에 의한 2차원 유한요소 모형을 개발하고 주입된 질량과 모의 질량간의 오차를 산정하였다. 지배방정식으로부터 질량 오차 산정식을 유도하고 이를 간단한 예제에 적용하였다. 적용 예제로는 단순 직선수로에서 선원을 통한 질량주입과 일방향의 등질 유속장을 가지는 2차원 공간에서 점원을 통한 질량주입 문제를 가정하였으며, 기존의 Galerkin법과의 비교를 위하여 두가지 수치기법에 대한 모의 검증을 실시하였다. 검증결과 기존의 Galerkin법에 의한 모의 결과에 비하여 SUPG법을 통한 수치모형의 구성이 모의의 정확성뿐만 아니라 주입 질량의 보존에 있어서도 보다 정확한 방법임을 확인하였다.

• 분석과학
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• 제32권6호
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• pp.225-232
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• 2019

Traceability establishment in chemical measurements is a like a linkage established through an unbroken chain from the measured results to the international system (SI) of units. The primary process for traceability establishment is the purity assignment of a target material to be measured. In this study, we studied the purity assignment of 17α-hydroxyprogesterone (17-OHP). The presence of 17-OHP is indicative of congenital adrenal hyperplasia (CAH) and it builds up due to the deficiency of 21-hydroxylase and 11β-hydroxylase enzyme in the human blood. The purity assignment of 17-OHP was performed by the mass balance method, in which the impurities are categorized into four classes: total related structural impurities, water, residual organic solvents, and nonvolatiles/inorganics. The total related structural impurities were characterized by HPLC-UV; water content was determined by Karl-Fisher coulometer; and the total residual solvents and nonvolatiles/inorganics were determined by TGA. The purity of 17-OHP from a commercial manufacturer was calculated as 993.30 mg/g, and the expanded uncertainty was 0.58 mg/g. The proposed method was validated by uncertainty evaluation and comparing with the actual value of purity.