• Journal of Electrochemical Science and Technology
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• v.2 no.3
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• pp.174-179
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• 2011

The mesoscopic $Sb_2S_3$-sensitized photoelectrochemical solar cells using cobalt redox electrolyte exhibit nonlinear behavior of power conversion efficiency with illuminated sun intensity. From the measurement of bulk diffusion and electrochemical impedance spectroscopy studies, we suggest that the nonlinearity of device performance with illuminated sun intensity is attributed not to the slow bulk diffusion problem of cobalt electrolyte but to the limited mass transport in narrowed pore volume in mesoscopic $TiO_2$ electrode.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.682-688
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• 2016

In $TiO_2$-CuO systems, low-temperature sinterability was investigated by a conventional sintering method. Sintering temperatures were set at under $950^{\circ}C$, at which the volume diffusion is inactive. The temperatures are less than the melting point of Ag ($961^{\circ}C$), which is often used as an internal conductor in low-temperature co-fired ceramic technology. To optimize the amount of CuO dopant, various dopant contents were added. The optimum level for enhanced densification was 2 wt% CuO. Excess dopants were segregated to the grain boundaries. The segregated dopants supplied a high diffusion path, by which grain boundary diffusion improved. At lower temperatures in the solid state region, grain boundary diffusion was the principal mass transport mechanism for densification. The enhanced grain boundary diffusion, therefore, improved densification. In this regard, the results of this study prove that the sintering mechanism was the same as that of activated sintering.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.52 no.1
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• pp.74-80
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• 2019

Nonylphenol is an endocrine-disrupting chemical that is the degradation product of the nonionic surfactants nonylphenol ethoxylates. To understand the contamination and behavioral characteristics of nonylphenol, we measured the nonylphenol concentrations in surface water in the lower reaches of the Suyeong River, Korea. The results were used to estimate the material balance. The target area was divided into three regions to estimate the material balance of nonylphenol. In region 1, in flux of the dissolved nonylphenol was 282.3 g/day and the nonylphenol influx in particulate suspended solids was 1,582.8 g/day. The dissolved nonylphenol outflow discharged toward region 2 was 192.5 g/day, while the adsorption to particulate suspended solids was 89.8 g/day. Within the particulate suspended solids, the outflow to region 2 was 1,250.0 g/day, while the estimated amount settling in the sediments was 422.7 g/day. The adsorption of dissolved nonylphenol to the particulate suspended solids in regions 1 and 2 was 31.8% and 54.9%, respectively. In region 3, the desorption rate was 8.8%.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.109-114
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• 2008

A dynamic model has been developed to simulate dynamic operation of a real double-effect absorption chiller. Dynamic behavior of working fluids in main components was modeled in first-order nonlinear differential equations based on heat and mass balances. Mass transport mechanisms among the main components were modeled by valve throttling, 'U' tube overflow and solution sub-cooling. The nonlinear dynamic equations coupled with the subroutines to calculate thermodynamic properties of working fluids were solved by a numerical method. The dynamic performance of the model was compared with the test data of a commercial medium chiller. The model showed a good agreement with the test data except for the first 5,000 seconds during which different flow rates of the weak solution caused some discrepancy. It was found that the chiller dynamics is governed by the inlet temperatures of the cooling water and the chilled water when the heat input to the chiller is relatively constant.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.12
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• pp.781-788
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• 2008

A dynamic model has been developed to simulate dynamic operation of a real double-effect absorption chiller. Dynamic behavior of working fluids in main components was modeled in first-order nonlinear differential equations based on heat and mass balances. Mass transport mechanisms among the main components were modeled by valve throttling, 'U' tube overflow and solution sub-cooling. The nonlinear dynamic equations coupled with the subroutines to calculate thermodynamic properties of working fluids were solved by a numerical method. The dynamic performance of the model was compared with the test data of a commercial medium chiller. The model showed a good agreement with the test data except for the first 5,000 seconds during which different flow rates of the weak solution caused some discrepancy. It was found that the chiller dynamics is governed by the inlet temperatures of the cooling water and the chilled water when the heat input to the chiller is relatively constant.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.268-277
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• 2004

process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.91-101
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• 1996

In recent years, phytoremediation, the use of plants to detoxify hydrocarbons, has been a promising new area of research, particularly in situ cleanup of large volumes of slightly contaminated soils. There is increasing need for a mathematical model that can be used as a predictive tool prior to actual field implementation of such a relatively new technique. Although a number of models exist for solute-plant interaction in the vegetated zone of soil, most of them have focused on ionic nutrients and some metals. In this study, we developed a mathematical model for simulation of bioremediation of hydrocarbons in soil, associated with plant root systems. The proposed model includes root interactions with soil-water and hydrocarbons in time and space, as well as advective and dispersive transport in unsaturated soil. The developed model considers gas phase diffusion and liquid-gas mass exchanges. For simulation of temporal and spatial changes in root behavior on soil-water and with hydrocarbons, time-specific distribution of root quantity through soil was incorporated into the simulation model. Hydrocarbon absorption and subsequent uptake into roots with water were simulated with empirical equations. In addition, microbial activity in the rhizosphere, a zone of unique interaction between roots and soil microorganisms, was modeled using a biofilm theory. This mathematical model for understanding and predicting fate and transport of compound in plant-aided remediation will assist effective application of plant-aided remediation to field contamination.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.10
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• pp.649-657
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• 2017

A rupture in a high-pressure pipe causes the fluid in the pipe to be discharged in the atmosphere at a high speed resulting in a supersonic jet that generates the compressible flow. This supersonic jet may display complicated and unsteady behavior in general. In this study, Computational Fluid Dynamics (CFD) analysis was performed to investigate the compressible flow generated by a supersonic jet ejected from a high-pressure pipe. A Shear Stress Transport (SST) turbulence model was selected to analyze the unsteady nature of the flow, which depends upon the various gases as well as the diameter of the pipe. In the CFD analysis, the basic boundary conditions were assumed to be as follows: pipe of diameter 10 cm, jet pressure ratio of 5, and an inlet gas temperature of 300 K. During the analysis, the behavior of the shockwave generated by a supersonic jet was observed and it was found that the blast wave was generated indirectly. The pressure wave characteristics of hydrogen gas, which possesses the smallest molecular mass, showed the shortest distance to the safety zone. There were no significant difference observed for nitrogen gas, air, and oxygen gas, which have similar molecular mass. In addition, an increase in the diameter of the pipe resulted in the ejected impact caused by the increased flow rate to become larger and the zone of jet influence to extend further.

• Nuclear Engineering and Technology
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• v.55 no.12
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• pp.4357-4366
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• 2023

MARS-KS, a domestic regulatory confirmatory code of Republic of Korea, had been developed by integrating RELAP5/MOD2 and COBRA-TF. The integration of COBRA-TF allowed to extend the capability of MARS-KS, limited to one-dimensional analysis, to multi-dimensional analysis. The use of COBRA-TF was mainly focused on subchannel analyses for simulating multi-dimensional behavior within the reactor core. However, this feature has been remained as a legacy without ongoing maintenance. Meanwhile, MARS-KS also includes its own multidimensional component, namely MULTID, which is also feasible to simulate three-dimensional convection and diffusion. The MULTID is capable of modeling the turbulent diffusion using simple mixing length model. The implementation of the turbulent mixing is of importance for analyzing the reactor core where a disturbing cross-sectional structure of rod bundle makes the flow perturbation and corresponding mixing stronger. In addition, the presence of this turbulent behavior allows the secondary transports with net mass exchange between subchannels. However, a series of assessments performed in previous studies revealed that the turbulence model of the MULTID could not simulate the aforementioned effective mixing occurred in the subchannel-scale problems. This is obvious consequence since the physical models of the MULTID neglect the effect of mass transport and thereby, it cannot model the void drift effect and resulting phasic distribution within a bundle. Thus, in this study, the turbulence mixing model of the MULTID has been improved by means of the inter-channel mixing model, widely utilized in subchannel analysis, in order to extend the application of the MULTID to small-scale problems. A series of assessments has been performed against rod bundle experiments, namely GE 3X3 and PSBT, to evaluate the performance of the introduced mixing model. The assessment results revealed that the application of the inter-channel mixing model allowed to enhance the prediction of the MULTID in subchannel scale problems. In addition, it was indicated that the code could not predict appropriate phasic distribution in the rod bundle without the model. Considering that the proper prediction of the phasic distribution is important when considering pin-based and/or assembly-based expressions of the reactor core, the results of this study clearly indicate that the inter-channel mixing model is required for analyzing the rod bundle, appropriately.

• 제어로봇시스템학회:학술대회논문집
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• 1991.10b
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• pp.1639-1645
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• 1991

Because of the important role LD converters play in the production of high quality steel, various dynamic models have been attempted in the past by many researchers not only to understand the complex chemical reactions that take place in the converter process but also to assist the converter operation itself using computers. And yet no single dynamic model was found to be completely satisfactory because of the complexity involved with the process. The process indeed involves dynamic energy and mass balances at high temperatures accompanied by complex chemical reactions and transport phenomena in the molten state. In the present study, a mathematical model describing the dynamic behavior of LD converter process has been developed. The dynamic model describes the time behavior of the temperature and the concentrations of chemical species in the hot metal bath and slag. The analysis was greatly facilitated by dividing the entire process into three zones according to the physical boundaries and reaction mechanisms. These three zones were hot metal (zone 1), slag (zone 2) and emulsion (zone 3) zones. The removal rate of Si, C, Mn and P and the rate of Fe oxidation in the hot metal bath, and the change of composition in the slag were obtained as functions of time, operating conditions and kinetic parameters. The temperature behavior in the metal bath and the slag was also obtained by considering the heat transfer between the mixing and the slag zones and the heat generated from chemical reactions involving oxygen blowing. To identify the unknown parameters in the equations and simulate the dynamic model, Hooke and Jeeves parttern search and Runge-Kutta integration algorithm were used. By testing and fitting the model with the data obtained from the operation of POSCO #2 steelmaking plant, the dynamic model was able to predict the characteristics of the main components in the LD converter. It was possible to predict the optimum CO gas recovery by computer simulation