• Proceedings of the Korea Water Resources Association Conference
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• 2002.05b
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• pp.1027-1033
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• 2002

The solute transport in a two-dimensional heterogeneous porous medium is numerically studied by using a random walk particle tracking (RWPT) method. Lognormally isotropic hydraulic conductivity fields are generated by using the turning band methods with mean zero and four different values of standard deviation. The numerical transport experiments are carried out to investigate the large time and spatial effects of the variable pore velocity field on solute plumes. The behavior of the solute plume through numerical simulations is presented in terms of longitudinal and transverse spatial moments: displacement of center-of-mass, plume spread variance and skewness coefficient. It was observed that the dispersive behavior of the solute plume is strongly affected by the degree of heterogeneity in the flow domain.

• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1742-1756
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• 2023

The hydrogen behavior in a nuclear containment vessel is a significant issue when discussing the potential of hydrogen combustion during a severe accident. After the Fukushima-Daiichi accident in Japan, we have investigated in-depth the hydrogen transport mechanisms by utilizing experimental and numerical approaches. Computational fluid dynamics is a powerful tool for better understanding the transport behavior of gas mixtures, including hydrogen. This paper describes a Large-eddy simulation of gas mixing driven by a high-buoyancy flow. We focused on the interaction behavior of heat and mass transfers driven by the horizontal high-buoyant flow during density stratification. For validation, the experimental data of the Containment InteGral effects Measurement Apparatus (CIGMA) facility were used. With a high-power heater for the gas-injection line in the CIGMA facility, a high-temperature flow of approximately 390 ℃ was injected into the test vessel. By using the CIGMA facility, we can extend the experimental data to the high-temperature region. The phenomenological discussion in this paper helps understand the heat and mass transfer induced by the high-buoyancy flow in the containment vessel during a severe accident.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2822-2827
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• 2008

Among the main components of PEM fuel cell, the functions of GDL are to transport reactants from the channel to the catalyst and remove reaction products from the catalyst and transport heat from the catalyst to the channels in the flow filed plate. Permeability of GDL is known to make it possible to enhance the gas transport through GDL, devoting to get better performance. In this paper, three dimensional numerical simulation of the fuel cell by the permeability of GDL is presented by using a FLUENT modified to include the electrochemical behavior. Results show that as permeability is higher than $10^{-12}m^2$, gradients of temperature distribution, oxygen molar concentration and current density distribution in MEA were decreased. Although heat generation was increased as high permeability, MEA's temperature was lower than the low permeability of GDL. This seems because that convection was higher affects in mass and heat transfer process than diffusion as permeability of GDL is increases.

• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.648-654
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• 2005

The performance prediction of a planar-type solid oxide fuel ceil is conducted by a computational analysis. The transport processes are formulated with the help of a simplified treatment of heat generation by the electrochemical reaction. From the result of the computational analysis, it is shown that the electrochemical reaction is closely related to the transport phenomena inside a solid oxide fuel cell. Transport phenomena including heat and mass transfer have influence on the distribution of local current density and as a result, on the performance characteristics of the fuel cell. Computational analysis is also extended to the parametric study to investigate the performance behavior of the fuel cell with different amount of supplied fuel flow rates. It is also demonstrated that the mathematical formulation and computational procedures proposed in this study can be applied to prove the importance of the specific TPB(Three-Phase-Boundary) area in the manufacturing process of electrodes in a solid oxide fuel cell.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.291-294
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• 2006

Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

• Journal of Electrochemical Science and Technology
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• v.2 no.1
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• pp.20-25
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• 2011

This work focuses on the behavior of the overpotential increase due to a utilization rise in a molten carbonate fuel cell. The behavior is generally explained by Nernst loss, which is a kind of voltage loss due to the thermodynamic potential gradients in a polarization state due to the concentration distribution of reactant species through the gas flow direction. The evaluation of Nernst loss is carried out with a traditional experimental method of constant gas utilization (CU). On the other hand, overpotential due to the gas-phase mass-transport resistance at the anode and cathode shows dependence on the utilization, which can be measured using the inert gas step addition (ISA) method. Since the Nernst loss is assumed to be due to the thermodynamic reasons, the voltage loss can be calculated by the Nernst equation, referred to as a simple calculation (SC) in this work. The three values of voltage loss due to CU, ISA, and SC are compared, showing that these values rise with increases in the utilization within acceptable deviations. When we consider that the anode and cathode reactions are significantly affected by the gas-phase mass transfer, the behavior strongly implies that the voltage loss is attributable not to thermodynamic reasons, namely Nernst loss, but to the kinetic reason of mass-transfer resistance in the gas phase.

• Bulletin of the Korean Chemical Society
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• v.17 no.9
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• pp.781-786
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• 1996

Mass transport behavior of C60 films on electrodes with different thicknesses has been studied by an Electrochemical Quartz Crystal Microbalance (EQCM) during electrochemical reduction-oxidation processes in the presence of water. C60 films were found to be reduced in the presence of water and they remains quite stable. In thin films, the mass on electrode decreased after a complete cycle while X-ray Photoelectron Spectroscopy (XPS) study does not support the existence or formation of C60-epoxides during electrochemical reduction processes in the presence of water or oxygen.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.8
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• pp.116-122
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• 1999

According to the stringent exhaust emission regulation, precise control of air fuel ratio is one of the most important issues on gasoline engine. Although many researches have been carried out to identify the fuel transport phenomena in a port fueled gasoline engine, complexity of fuel film behavior in the intake port makes it difficult. The fuel film behavior was investigated recently by using visualization method and these gave us qualitative understanding. The purpose of this study is to estimate of wall wetting fuel in the intake port and the inducted fuel mass was predicted by using wall wetting fuel model . The model coefficient($\alpha$,$\beta$) and fuel film mass on the port wall were determined from measured in-cylinder HC concentration using FRFID after injection off. The fuel film mass was increased, but $\alpha$(ratio of directly inducted fuel mass into cylinder from injected fuel mass) was decreased with increasing load at the same engine speed. $\beta$is nearly constant value(0.8~0.9). when injected fuel mass is varied at 1500rpm , the calculated air fuel ratio using well wetting fuel model was nearly the same as measured by UEGO.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.15-22
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• 2002

As the emission regulations on the automobiles have been increasingly stringent, precise control of air/fuel ration is one of the most important issues on the gasoline engines. Although many researches have been carried out to identify the fuel transport phenomena in the port fuel injection gasolines, mixture preparation in the cylinder has not been fully understood due to the complexity of fuel film behavior, In this paper, the mixture preparation during cold engine start is studied by using a Fast Response Flame ionization Detector.(FRFID) In order to estimate the transportation of injected fuel from the intake port into cylinder, the wall wetting fuel model was used. The two coefficient($\alpha$,$\beta$) of the wall-wetting fuel model was determined from the measured fuel mass that was inducted into the cylinder at the first cycle after injection cut-in. $\alpha$( ratio of directly inducted fuel mass into cylinder from injected fuel mass) and $\beta$ (ratio of indirectly inducted fuel mass into cylinder from wall wetted fuel film on the wall) was increased with increasing cooling water temperature. To reduce a air/fuel ratio fluctuation during cold engine start, the appropriate fuel injection rate was obtained from the wall wetting fuel model. Result of air/fuel ratio control, air/fuel excursion was reduced.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.745-748
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• 2001

We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.