• Title/Summary/Keyword: Mass Transfer Resistance

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Effect of Mo and Mn Addition on the Oxidation Behavior of Binary Ti-Al Alloys

  • Han, Chang-Suk;Jin, Sung-Yooun;Bang, Hyo-In
    • Korean Journal of Materials Research
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    • v.28 no.6
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    • pp.361-364
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    • 2018
  • Binary Ti-Al alloys below 51.0 mass%Al content exhibit a breakaway, transferring from parabolic to linear rate law. The second $Al_2O_3$ layer might have some protectiveness before breakaway. Ti-63.1 mass%Al oxidized at 1173 K under parabolic law. Breakaway oxidation is observed in every alloy, except for Ti-63.1 mass%Al. After breakaway, oxidation rates of the binary TiAl alloys below 34.5 mass%Al obey almost linear kinetics. The corrosion rate of Ti-63.1 mass%Al appears to be almost parabolic. As content greater than 63.0 mass% is found to be necessary to form a protective alumina film. Addition of Mo improves the oxidation resistance dramatically. No breakaway is observed at 1123 K, and breakaway is delayed by Mo addition at 1173 K. At 1123 K, no breakaway, but a parabolic increase in mass gain, are observed in the Mo-added TiAl alloys. The binary Ti-34.5 mass%Al exhibits a transfer from parabolic to linear kinetics. At 1173 K, the binary alloys show vary fast linear oxidation and even the Mo-added alloys exhibit breakaway oxidation. The 2.0 mass%Mo-added TiAl exhibits a slope between linear and parabolic. At values of 4.0 and 6.0 mass% added TiAl alloys, slightly larger rates are observed than those for the parabolic rate law, even after breakaway. On those alloys, the second $Al_2O_3$ layer appears to be persistently continuous. Oxidation resistance is considerably degraded by the addition of Mn. Mn appears to have the effect of breaking the continuity of the second $Al_2O_3$ layer.

A Dynamic Characteristic of the Multi-Inverter Heat Pump with Frosting (착상을 수반한 멀티 가변속 열펌프의 동특성)

  • ;;Shigeru Koyama
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.5
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    • pp.337-345
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    • 2003
  • In the case of heat exchangers operating under frosting condition, the growth of frost layer causes the heat exchanger to increase the thermal resistance and pressure loss of the air flow. In this paper, a transient characteristic prediction model of the heat transfer for multi inverter heat pump with frosting on its surface was presented taking into account the change of the fin efficiency due to the growth of the frost layer. In this dynamic simulation program, which was peformed for a basic air conditioning system model, such as evaporator, condenser, compressor, linear electronic expansion valve (LEV) and bypass circuit. The theoretical model was driven from the obtained heat transfer coefficient and mass transfer coefficient, independently. And we consider heat transfer performance was only affected by a decrease of the wind flow area. The calculated results were compared with some cases of experiments for frosting conditions.

Development of the Dynamic Simulation Program of a Multi-Inverter Heat Pump under Frosting Conditions

  • Park Byung-Duck;Lee Joo-Dong;Chung Baik-Young
    • International Journal of Air-Conditioning and Refrigeration
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    • v.12 no.3
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    • pp.113-122
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    • 2004
  • In case of heat exchangers operating under frosting condition, the thermal resistance and the air-side pressure loss increase with a growth of frost layer. In this paper, a transient characteristic prediction model of the heat transfer for a multi-inverter heat pump with frosting on its surface was presented by taking into account the change of the fin efficiency due to the growth of the frost layer. This dynamic simulation program was developed for a basic air conditioning system composed of an evaporator, a condenser, a compressor, a linear electronic expansion valve, and a bypass circuit. The theoretical model was derived from measured heat transfer and mass transfer coefficients. We also considered that the heat transfer performance was only affected by the decrease of wind flow area. The calculated results were compared with the experimental results for frosting conditions.

End Bearing Load Transfer Behavior of Rock Socketed Drilled Shafts (암반에 근입된 현장타설말뚝의 선단하중전이거동 분석)

  • Cho, Hoo-Yeon;Jung, Sang-Sum;Seol, Hoon-Il
    • Journal of the Korean Geotechnical Society
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    • v.25 no.8
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    • pp.77-93
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    • 2009
  • The load distribution and deformation of rock socketed drilled shafts subjected to axial loads were evaluated by a load transfer approach. The emphasis was laid on quantifying the end bearing load transfer characteristics of rock socketed drilled shafts based on 3D Finite Difference (FD) analysis performed under varying rock strength and rock mass conditions. From the results of FD analysis, it was found that the ultimate unit toe resistance ($q_{max}$) was influenced by both rock strength and rock mass conditions, while the initial tangent of end bearing load transfer curve ($G_{ini}$) was only dependent on rock strength. End bearing load transfer function of drilled shafts socketed in rock was proposed based on the FD analysis and the field loading tests which were performed on weathered rock in South Korea. Through the comparison with the results of the field loading tests, it is found that the load transfer curve by the present study is in good agreement with the general trend observed by field loading tests, and thus represents a significant improvement in the prediction of load transfer behavior of drilled shaft.

A Numerical Study on the Design of Exchanger for Desiccant Dehumidifier (데시칸트 제습기용 열교환기 설계에 관한 수치해석적 연구)

  • Kim, Chi-Wan;Ahn, Young-Chull;Kim, Gil-Tae
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.54-62
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    • 2013
  • A numerical analysis is performed to evaluate mass flow balance in the heat exchanger for the dehumidifier. To improve the mass flow balance for maximum heat transfer performance, inlet, outlet and baffle are changed. Mass flow balance is evaluated by non-uniformity of flow which is the same concept with the standard deviation. Usually, there will occur many paths between the inlet and the outlet, however, it will follow shortest and low resistance ways. The uniform distribution of flow is numerically analyzed for several types of heat exchangers. Making the shortest way between the inlet and the outlet is most important factor. Two types of heat exchangers are installed in the dehumidifier and 4 cases of Type A heat exchangers and 3 cases of Type B heat exchangers are evaluated and optimized. The result of this research is applied to design heat exchanger for commercial dehumidifiers.

Study Characteristics in Packed Tower of Liquid Desiccant Solar Cooling System Using Counter Flow Configuration

  • Rahmanto, R. Hengki;Choi, K.H.;Agung, B.;Sukmaji, I.C.
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.168-174
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    • 2009
  • High water vapour content in air can cause a number of problems as for human or surrounding materials. For human a high water vapour can create physiological stress, discomfort, and also can encourage ill health. While, the cause for the environment is can accelerate the corrosion of metals, accelerate the growth of spores and mould, can reduce the electrical resistance of insulators and etc. Desiccant systems have been proposed as energy saving alternatives to vapor compression air conditioning for handling especially the latent load and also sensible load. Use of liquid desiccants offers several design and performance advantages over solid desiccants, especially when solar energy is used for regeneration. The liquid desiccants contact the gas inside the packed tower of liquid desiccant solar cooling system and the heat transfer and mass transfer will occur. This thesis is trying to study the characteristics inside the packed tower of dehumidifier systems. This characteristics consist of mass transfer rate, heat transfers rate, human comfort and energy that consume by the system. Those characteristics were affected by air flow rates, air temperature and humidity, and desiccant temperature and all that variation will influence the performance of the systems. The results of this thesis later on can be used to determine the best performance of the systems.

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Reversed Micellar Protein Extraction in a Hollow Fiber Membrane Extractor (단백질 추출용 역미셀 실관막장치에 관한 연구)

  • 윤현희;박상준유인상
    • KSBB Journal
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    • v.9 no.3
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    • pp.332-338
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    • 1994
  • Solubilization phenomena of a protein in a reversed micellar solution were investigated and a hollow fiber membrane extractor was tested for reversed micellar protein extraction equipment. Alkaline protease was used as a model protein compound and the reversed micellar solution was consisted of AOT and isooctane. It was found that protein solubilization was strongly influenced by ionic strength and pH. The distribution coefficient of the protease between the aqueous solution and the AOT/isooctane solution was also observed to be as high as 4.0 within the scope of this experiment. A hollow fiber membrane extractor was constructed and tested for the protein extraction. The overall mass transfer coefficient at a typical experimental condition of this study was observed to be $6.7{\times}10^{-5}cm/s$. It was also found that the mass transfer resistance on reversed micellar solution was the dominant resistance for the protein transfer.

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Self-pressurization Effect and PEMFC Performance Improvement Using Metal Foam Compression (금속 폼 압축에 의한 자가 가압 효과 및 PEMFC 성능 개선)

  • Kim, Hyeonwoo;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.618-623
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    • 2022
  • The bipolar plate is a key component of the polymer electrolyte membrane fuel cell (PEMFC) that transfers reactants and electrons, discharges water and heat as by-products, and serves as a mechanical support for the membrane electrode assembly (MEA). Therefore, the flow field structure of the bipolar plate plays an important role in improving fuel cell performance. In this study, PEMFC performance was investigated with copper foams with different compressibility ratios applied to cathode bipolar plates using a 25 cm2 unit cell. The total resistance decreased as the compressibility ratio of the metal foams increased, and, in particular, the charge transfer and mass transfer resistance were significantly improved compared to the serpentine flow field, lowering voltage loss in medium and high current density region. In the case of pressurized air reactant flow with serpentine structure, fuel cell performance was similar to that of a compressed metal foam flow field (S3) up to the medium current density region, but low performance appeared in the high current density region due to flow field structure limitations.

Ice Formation on the Outer Surface of a Vertical Tube with Inside Refrigerant Boiling (관 내부 냉매비등이 있는 수직관 외부 얼음 형성 연구)

  • Nguyen, Minh Phu;Lee, Geun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.2
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    • pp.129-135
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    • 2011
  • An ice-making model has been developed and analyzed in this study. The effects of the following on the ice formation on the outer surface of a tube in which a refrigerant flows and boils are numerically investigated: thermal resistance of the refrigerant and thermal resistance of the ice formed on the outer surface of the tube. The ice thickness and related variables are analyzed in the case of the refrigerants R22 and R134a by using the expressions for phase-change heat transfer and boiling heat transfer coefficient. Vapor qualities of the refrigerants range from 0 to 0.8. As a result, up to the first 30 min, the internal convection resistance is higher than the thermal resistance of the ice on the external surface of the tube. However, after about 30 min, the thermal resistance of the ice increases remarkably due to the increase in the ice thickness. Thus, the heat flux to the refrigerant decreases, and further, the refrigerant quality and the boiling heat transfer coefficient also decrease. As the heat transfer coefficient of R22 is higher than that of R134a, the mass of the ice formed when R22 is used is higher than that formed when R134a is used.

A Nuclide Transfer Model for Barriers of the Seabed Repository Using Response Function (응답함수를 이용한 해저처분장의 방벽에 대한 핵종전달 모델)

  • Lee, Youn-Myoung;Kang, Chul-Hyung;Hahn, Pil-Soo
    • Nuclear Engineering and Technology
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    • v.28 no.2
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    • pp.175-184
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    • 1996
  • A nuclide transfer by utilizing mass transfer coefficient and barrier response function defined for each barrier is proposed, by which the final nuclide transfer rate into the sea water can be evaluated. When simple and immediate quantification of the nuclide release is necessary in the conservative aspect, using this kind of approach may be advantageous since each layered barrier can be treated separately from other media in series in the repository system, making it possible to apply separate solutions in succession to other various media. Although one disadvantage is that while flux continuity can be maintained at the interface by using the exit nuclide flux from the first medium as the source flux for the next one, there may be no guarantee for concentration continuity, this problem could be eliminated assuming that there is no boundary resistance to mass transfer across the interface. Mass transfer coefficient can be determined by the assumption that the nuclide concentration gradient at the interface between adjacent barriers remains constant and barrier response function is obtained from an analytical expression for nuclide flow rate out of each barrier in response to a unit impulse into the barrier multiplied by mass transfer coefficient. Total time-dependent nuclide transfer rate from the barrier can then be obtained by convoluting the response function for the barrier with a previously calculated set of time-varying input of nuclide flow rate for the previous barrier.

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