• 제목/요약/키워드: Mass Efficiency

검색결과 1,889건 처리시간 0.034초

Superconducting Strip Ion Detectors for Time-of-flight Mass Spectrometer

  • Zen, N.;Suzuki, K.;Shiki, S.;Ukibe, M.;Koike, M.;Casaburi, A.;Ejrnaes, M.;Cristiano, R.;Ohkubo, M.
    • Progress in Superconductivity
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    • 제14권2호
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    • pp.92-95
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    • 2012
  • Superconducting detectors are promising as ion detectors for time-of-flight mass spectrometers (TOF MS). They can achieve mass-independent detection efficiency even for macromolecular bombardments, because output signals are produced through the deposited kinetic energy at ion impact instead of secondary electron emission that is the ion detection mechanism of conventional microchannel plate (MCP) detectors or secondary electron multipliers (SEM). Among the superconducting detectors, the superconducting strip ion detectors (SSIDs), which consist of several hundreds of superconducting lines with a width of a few hundreds nm and a thickness of a few tens of nm, have a fast response time of less than 1 ns. Inherently, the response time of SSIDs is determined by kinetic inductance, so that it was difficult to realize a fast SSID with a large detection area. However, we succeeded in realizing the detector size up to $5{\times}5mm^2$ without response time degradation by using a parallel configuration.

MALDI Mass Spectrometric Analysis of Nonderivatized Steroids Using Cyclodextrin-supported 2,5-Dihydroxybenzoic Acid as Matrix

  • Son, Jeongjin;Cha, Sangwon
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1409-1412
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    • 2014
  • Sex hormones are important metabolites in vertebrates' development and reproduction. For rapid screening sex hormones, matrix-assisted laser desorption/ionization (MALDI) mass spectrometry (MS) is one of the promising analytical platforms, but MALDI MS faces many challenges in detecting steroids such as low ionization efficiency and matrix background interference. One potential strategy to overcome matrix interference in the low m/z region is using a cyclodextrin (CD)-supported matrix for steroid analysis since CD-supported matrixes are known to effectively suppress matrix-related ion signals. In this study, we aimed to find the optimal CD-supported matrix for the analysis of the nonderivatized sex steroids. Our results showed that the ${\alpha}CD$-supported 2,5-dihydroxybenzoic acid (DHB) matrix efficiently ionized all three major classes of sex hormones, estrogens, androgens, and progestagens, with low or no matrix background and also with high sensitivity. In addition, the ${\alpha}CD$-supported DHB matrix mainly generated molecular ions or protonated ions of sex hormones, and this enabled us to obtain information-rich tandem mass spectra which potentially lead to unambiguous identification of steroid species from complex metabolite mixtures.

Performance of TMDs on nonlinear structures subjected to near-fault earthquakes

  • Domizio, Martin;Ambrosini, Daniel;Curadelli, Oscar
    • Smart Structures and Systems
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    • 제16권4호
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    • pp.725-742
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    • 2015
  • Tuned mass dampers (TMD) are devices employed in vibration control since the beginning of the twentieth century. However, their implementation for controlling the seismic response in civil structures is more recent. While the efficiency of TMD on structures under far-field earthquakes has been demonstrated, the convenience of its employment against near-fault earthquakes is still under discussion. In this context, the study of this type of device is raised, not as an alternative to the seismic isolation, which is clearly a better choice for new buildings, but rather as an improvement in the structural safety of existing buildings. Seismic records with an impulsive character have been registered in the vicinity of faults that cause seismic events. In this paper, the ability of TMD to control the response of structures that experience inelastic deformations and eventually reach collapse subject to the action of such earthquakes is studied. The results of a series of nonlinear dynamic analyses are presented. These analyses are performed on a numerical model of a structure under the action of near-fault earthquakes. The structure analyzed in this study is a steel frame which behaves as a single degree of freedom (SDOF) system. TMD with different mass values are added on the numerical model of the structure, and the TMD performance is evaluated by comparing the response of the structure with and without the control device.

적분형 초음파 유량계를 이용한 MPI 엔진의 비정상상태 공연비 제어 (A/F Control of an MPI Engine on Transient Conditions with an Intergration type Ultrasonic Flow Meter)

  • 김중일;장준석;고상근
    • 한국자동차공학회논문집
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    • 제7권9호
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    • pp.36-47
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    • 1999
  • Three-way catalyst converter, cleaning up the exhaust gas contamination of SI engine, has the best efficiency when A/F ratio is near the stoichiometry . The feedback control using oxygen sensors in the exhaust manifold has limits caused by the system delays. So the accurate measurement of air flow rate to an engine is essential to control the fuel injection rate especially on transient condition like the rapid throttle opening and closing. To measure the rapid change of flow rates. the air flow meter for the engine requires quick response, flow reversal detection, and linearity . Tjhe proposed integration type air flow meter (IFM), composed of an ultrasonic flow meter with an integration circuit, has significantly improved the measurement accuracy of air mass inducted through the throttle body. The proposed control method estimated the air mass at the cylinder port using the measured air mass at the throttle . For the fuel dynamic model, the two constant fuel model is introduced . The control parameters from air and fuel dynamics are tuned to minimize the excursion of the air fuel ratio. As a result A/F ratio excursion can be reduced within 5% when throttle rapidly opens and closes at the various engine conditions.

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Enhancement of Analyte Ionization in Desoprtion/Ionization on Porous Silicon (DIOS)-Mass Spectrometry(MS)

  • Lee Chang-Soo;Kim Eun-Mi;Lee Sang-Ho;KIm Min-Soo;Kim Yong-Kweon;Kim Byug-Gee
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제10권3호
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    • pp.212-217
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    • 2005
  • Desorption/ionization on silicon mass spectrometry (DIOS-MS) is a relatively new laser desorption/ionization technique for mass spectrometry without employing an organic matrix. This present study was carried to survey the experimental factors to improve the efficiency of DIOS-MS through electrochemical etching condition in structure and morphological properties of the porous silicon. The porous structure of silicon structure and its properties are crucial for the better performance of DIOS-MS and they can be controlled by the suitable selection of electrochemical conditions. The fabrication of porous silicon and ion signals on DIOS-MS were examined as a function of silicon orientation, etching time, etchant, current flux, irradiation, pore size, and pore depth. We have also examined the effect of pre- and post-etching conditions for their effect on DIOS-MS. Finally, we could optimize the electrochemical conditions for the efficient performance of DIOS-MS in the analysis of small molecule such as amino acid, drug and peptides without any unknown noise or fragmentation.

불연속 암반내 터널굴착의 안정성 평가 및 암반분류를 위한 인공 신경회로망 개발 (Development of Artificial Neural Networks for Stability Assessment of Tunnel Excavation in Discontinuous Rock Masses and Rock Mass Classification)

  • 문현구;이철욱
    • 터널과지하공간
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    • 제3권1호
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    • pp.63-79
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    • 1993
  • The design of tunnels in rock masses often demands more informations on geologic features and rock mass properties than acquired by usual field survey and laboratory testings. In practice, the situation that a perfect set of geological and mechanical input data is given to geomechanics design engineer is rare, while the engineers are asked to achieve a high level of reliability in their design products. This study presents an artificial neural network which is developed to resolve the difficulties encountered in conventional design techniques, particulary the problem of deteriorating the confidence of existing numerical techniques such as the finite element, boundary element and distinct element methods due to the incomplete adn vague input data. The neural network has inferring capabilities to identify the possible failure modes, support requirements and its timing for underground openings, from previous case histories. Use of the neural network has resulted in a better estimate of the correlation between systems of rock mass classifications such as the RMR and Q systems. A back propagation learning algorithm together with a multi-layer network structure is adopted to enhance the inferential accuracy and efficiency of the neural network. A series of experiments comparing the results of the neural network with the actual field observations are performed to demonstrate the abilities of the artificial neural network as a new tunnel design assistance system.

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고온호기성 소화공정 배가스 처리를 위한 바이오필터 성능평가 (Performance Evaluation of Biofilter Treating Autothermal Thermophilic Aerobic Digestion Offgas)

  • 배병욱;최기승
    • 한국물환경학회지
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    • 제26권5호
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    • pp.732-739
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    • 2010
  • Two combined autothermal thermophilic aerobic digestion (ATAD) and biofilter (BF) systems were operated to treat the piggery wastewater and the ammonia offgas. Experimental results indicated that the organic removal efficiency of ATAD-2, operated with oxygen, was higher than that of ATAD-1, operated with air. The concentration of ammonia in ATAD-2 offgas was higher compared to ATAD-1 offgas, but the total amount of ammonia produced from ATAD-2 was less than that from ATAD-1 due to the lower oxygen flowrate. The ammonia gas produced from both ATAD reactors was successfully removed by the BF. The BF-1, connected with ATAD-1, removed 93% of ammonia at the loading rate of $9.4g\;NH_3-N/m^3/hr$. The BF-2, connected with ATAD-2, removed 95% of ammonia gas at the loading rate of $8.1g\;NH_3-N/m^3/hr$. As the nitrification process continued, pH value of recirculating solution continuously decreased due to the accumulation of nitrate. When the ammonia loading rate was less than $22.7g\;NH_3-N/m^3/h$, the proper replacing cycle of recirculating solution was in the range of 10 to 11 days. Almost 90% of total mass of nitrogen fed into the each BF was confirmed from the mass balance on nitrogen.

간척지 자연순환형 친환경축산단지 도입 타당성 연구 (Feasibility Study on the Development of Environmental Friendly Livestock Complex in the Reclaimed Tideland)

  • 허남효;이승헌;김병기
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.430-433
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    • 2009
  • The development of large-scale environmental friendly livestock complex in the reclaimed tideland is one of different alternatives to increase the competitiveness of internal livestock industry against an international opening markets as DDA and FTA in agricultural field. Recently, it is possible to introduce an environmental friendly livestock complex in the reclaimed tideland by an amendment of the acts for agricultural land. However more studies that are on the basis of nitrogen and phosphorus mass balance need to preserve the agricultural environments as the quality of agricultural water and soil in rural area. In this study, the reference for feasibility study is Whaong reclaimed tideland which located at Whaseong city, Gyeonggi Province, and a basic concept of environmental friendly livestock complex is the production of forage crops with the supply of liquid fertilizer and the production of bioenergy such as biogas by the recycling of pig slurry as a resource. The mass balance of nitrogen based on between forage crops such as maize, barley and liquid fertilizer supplied at the reclaimed tideland, and also it was estimated an economical efficiency as anaerobic digestion plant for treating pig slurry of $100m^3/day$ introduce in an environmental friendly livestock complex.

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Seismic effectiveness of tuned mass dampers in a life-cycle cost perspective

  • Matta, Emiliano
    • Earthquakes and Structures
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    • 제9권1호
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    • pp.73-91
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    • 2015
  • The effectiveness of tuned mass dampers (TMDs) in reducing the seismic response of civil structures is still a debated issue. The few studies regarding TMDs on inelastic structures indicate that they would perform well under moderate earthquake loading, when the structure remains linear or weakly nonlinear, while tending to fail under severe ground shaking, when the structure experiences strong nonlinearities. TMD seismic efficiency should be therefore rationally assessed by considering to which extent moderate and severe earthquakes respectively contribute to the expected cost of damages and losses over the lifespan of the structure. In this paper, a method for evaluating, in a life-cycle cost (LCC) perspective, the seismic effectiveness of TMDs on inelastic building structures is presented and exemplified on the SAC LA 9-storey steel moment-resisting frame benchmark building. Results show that the LCC concept may provide an appropriate alternative to traditional performance criteria for the evaluation of the effectiveness of TMDs and that TMD installation on typical existing middle-rise buildings in high seismic hazard regions may significantly reduce building lifetime cost despite the poor control performance observed under the most severe seismic events.

Testing Gravitational Weak-lensing Maps with Galaxy Redshift Surveys: preliminary results

  • Ko, Jongwan;Utsumi, Yousuke;Hwang, Ho Seong;Dell'Antonio, Ian P.;Geller, Margaret J.;Yang, Soung-Chul;Kyeong, Jaemann
    • 천문학회보
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    • 제39권2호
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    • pp.45.2-45.2
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    • 2014
  • To measure the mass distribution of galaxy systems weak-lensing analysis has been widely used because it directly measures the total mass of a system regardless of its baryon content and dynamical state. However, the weak-lensing only provides a map of projected surface mass density. On the other hand, galaxy redshift surveys provide a map of the three-dimensional galaxy distribution. It thus can resolve the structures along the line of sight projected in the weak-lensing map. Therefore, the comparison of structures identified in the weak-lensing maps and in the redshift surveys is an important test of the issues limiting applications of weak-lensing to the identification of galaxy clusters. Geller et al. (2010) and Kurtz et al. (2012) compared massive clusters identified in a dense redshift survey with significant weak-lensing map convergence peaks. Both assessments of the efficiency of weak-lensing map for cluster identification did not draw a general conclusion, because the sample is so small. Thus, we additionally perform deep imaging observations of fields in a dense galaxy redshift survey that contain galaxy clusters at z~0.2-0.5, using CFHT Megacam.

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