• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.9-15
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• 2023

The cement is a typical CO₂ emission industry. Manufacturing process improvements and increased use of alternative materials are needed to reduce energy consumption and CO₂ emissions. This study confirmed the basic characteristics of cement hydration by sintering CAF at low temperature as a CO₂ adsorbent material. For the hydration product of the synthetic CAF, crystal phase analysis, porosity, and structural images were confirmed, and the compressive strength was measured. The replacement rate of SCAF was 10, 20, and 100 %, and the compressive strength tended to decrease as the replacement rate increased. In addition, when the SCAF substitution rate is 100 %, the hydration products of the early age are calcium aluminum oxide hydrate (Ca₃Al₂O₆ x H₂O) and calcium iron hydroxide (Ca₃Fe(OH)₁₂), and at substitution rates of 10 and 20 %, CAF compounds other than general cement hydrates brownmillerite was observed. As for the porosity, the pore size increased and the porosity increased with the increase of the replacement ratio. As a result of this study, CAF manufactured by low-temperature sintering seems to be difficult to use alone and general curing for utilization as a CO₂ adsorbing material.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.16-24
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• 2023

Coal ash generated from thermal power plants using briquettes contains Si, Al, and Fe components. These components are the main components required for the manufacture of cement clinker. In particular, Al and Fe components form the interstitial phase of cement clinker and have an important effect on the sintering of cement clinker. In this study, a large amount of coal ash was applied as a raw material for cement clinker by content, and the mineral formation process of cement clinker to which coal ash was applied was confirmed by sintering temperature. It was confirmed that the intermediate phase was generated in the sintering temperature range of 1050 ~ 1150 ℃ in the cement clinker to which a large amount of coal ash was applied. As the content of coal ash increased, the production amount of the intermediate phase increased. The phase produced by the addition of coal ash is expected to be converted to calcium silicate phase and interstitial phase and disappear above 1350 ℃. The cement clinker applied with a large amount of coal ash at 1450 ℃ formed well-developed minerals equivalent to the standard cement clinker.

• Resources Recycling
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• v.32 no.1
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• pp.21-32
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• 2023

Because the application of lithium has gradually increased for the production of lithium ion batteries (LIBs), more research studies about recycling using solvent extraction (SX) should focus on Li⁺ recovery from the waste solution obtained after the removal of the valuable metals nickel, cobalt and manganese (NCM). The raffinate obtained after the removal of NCM metal contains lithium ions and other impurities such as Na ions. In this study, we optimized a selective SX system using di-(2-ethylhexyl) phosphoric acid (D2EHPA) as the extractant and tri-n-butyl phosphate (TBP) as a modifier in kerosene for the recovery of lithium from a waste solution containing lithium and a high concentration of sodium (Li⁺ = 0.5 ~ 1 wt%, Na⁺ = 3 ~6.5 wt%). The extraction of lithium was tested in different solvent compositions and the most effective extraction occurred in the solution composed of 20% D2EHPA + 20% TBP + and 60% kerosene. In this SX system with added NaOH for saponification, more than 95% lithium was selectively extracted in four extraction steps using an organic to aqueous ratio of 5:1 and an equilibrium pH of 4 ~ 4.5. Additionally, most of the Na⁺ (92% by weight) remained in the raffinate. The extracted lithium is stripped using 8 wt% HCl to yield pure lithium chloride with negligible Na content. The lithium chloride is subsequently treated with high purity ammonium bicarbonate to afford lithium carbonate powder. Finally the lithium carbonate is washed with an adequate amount of water to remove trace amounts of sodium resulting in highly pure lithium carbonate powder (purity > 99.2%).

• Journal of Korea Water Resources Association
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• v.56 no.7
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• pp.461-470
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• 2023

The purpose of this research is to derive the optimal temperature, location, and heating control system for a tipping bucket rain gauge heating system used for observing snowfall during winter. We conducted indoor and outdoor experiments by manufacturing a tipping bucket rain gauge that can be variably controlled for heating at the funnel, exterior, and interior, and indoor and outdoor. The indoor experiments involved using a temperature and humidity chamber to compare the performance and derive the appropriate temperature of the precipitation gauge heating system. Subsequently, the outdoor experiments were carried out at the Cloud Physics Observation Center located in Daeguallyeong, heavy snowfall region, to validate the findings. The analysis result was derived that the heating temperature of the funnel should be set at the 10 to 30℃, while the internal heating temperature should be 70℃. Furthermore, the optimal locations for the heating devices, which aim to minimize measurement delay, were identified as the exterior of the rain gauge, the rim of the funnel, and the vertical surface of the funnel. Our result shows that used as the basis for the operating conditions of precipitation gauge heating systems for solid precipitation measurement in winter.

• Resources Recycling
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• v.33 no.1
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• pp.69-76
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• 2024

In an effort to achieve the goal of carbon neutrality, countries around the world are aiming to phase out coal-fired power plants. Due to various reasons, electricity production through coal-fired power generation and sulfur oxide (SOx) emissions are expected to continue in the future. In the South Korea, sodium bicarbonate (NaHCO₃) and lime materials are used to treat SOx, and most of the sodium bicarbonate is imported. Therefore, this research was conducted to replace sodium bicarbonate by improving the physical properties of lime materials using domestic limestone. Limestone was heat-treated through a box-type electric furnace and a vertical electric furnace. Due to the structural characteristics of the vertical electric furnace, a lime material(quicklime) was possible to improve the physical properties like a specific surface area and a pore volume. Then, they were reached to 22.33 m²/g specific area and 0.14 cc/g pore volume.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2004.11a
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• pp.15-19
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• 2004

Domestic use, or embody program that transmit NMEA protocol using multi port as software and is using because there is no fee and product that develop NMEA protocol Multiplexer, import mounting for foreign climax present. These method is paid or there is problem that must make out special processing part in each application program. Also, each mountings that display NMEA protocol can cause double resources waste and damage etc. because manufacturing firm and platform are different. Can act separatively as single hardware module of reliable processing method and high efficiency to supplement this in this treatise, and because using design of optimized cue, heighten memory efficiency of module, and proposed NMEA protocol Multiplexer that can keep high trustability of Come on, deviation compass, echo sound, mountings of GPS and so on and real time communication that is main input sensor equipment about embodiment.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.05a
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• pp.326-330
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• 2004

Thermosetting matrix composites have disadvantages in terms of moulding time, repairability and manufacturing cost. Thus the high-performance thermoplastic composites to eliminate such disadvantages have been developed so far. As a result of environmental and economical concerns, there is a growing interest in the use of thermoplastic composites. However, since their mechanical properties are very sensitive to the environment such as moisture, temperature etc., those behaviors need to be studied. Particularly the temperature is a very important factor influencing the mechanical behavior of thermoplastic composites. The effect of temperature have not yet been fully quantified. Since engineering applications of reinforced composites necessitate their fracture mechanics characterization, work is in progress to investigate the fracture and related failure behavior. An approach which predicts the tensile strength was perpormed in the tensile test. The main goal of this work is to study the effect of temperature on the result of tensile test with respect to GF/PE composite. The tensile strength and failure mechanisms of GF/PE composites were investigated in the temperature range $60^{\circ}C\;to\;-50^{\circ}C$. The tensile strength increased as the fiber volume fraction ratio increased. The tensile strength showed the maximum at $-50^{\circ}C$, and it tended to decrease as the temperature increased from $-50^{\circ}C$. The major failure mechanisms was classified into the fiber matrix debonding, the fiber pull-out, the delamination and the matrix deformation.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.45 no.3
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• pp.9-19
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• 2013

This research was performed to make functional papers by using the waste of herbal medicine such as Astragalus membranaceus, Angelica acutiloba, and Artemisia capillaris as additives, and to evaluate their physical and optical properties of the manufactured paper. The physical and optical properties were decreased with the increase of the amount of herbal medicine. Of those manufactured papers, the functional paper with Artemisia capillaris showed the dramatic decrease in its physical properties. Adding the herbal medicine waste as additives developed the aesthetic pattern on the surface of the manufactured paper. The paper showing the black pattern on white surface was most favored. Different patterns could be made by changing the size of fibers and the amount of wastes. There was odor emitted from the paper due to the herbal medicine waste, which make the paper to have a potential for the diverse purpose. The herbal medicine waste can be applied to replace weighting agents in the manufacturing process of paper or used for the fuctional additives, resulting in the reduce of the quantity of a pulp consumed. The paper with 10-20% Angelica acutiloba waste were thought to have the most excellent quality on the process point of view.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.39 no.4
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• pp.26-39
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• 2016

Korea's main manufacturing industries, which have led its economy for the past three decades, are faced with a serious downturn and loss of competitive advantages due to the current economic depression, China's rise, and the drop of oil prices. Korean business firms must adopt the paradigm shift in their value strategies, along with a government-led industrial restructuring in order to gain sustainable competitive advantages. Business firms allocate their limited resources between value creation and value appropriation, however, what effect does strategic emphasis on value creation versus value appropriation have on a business firm's financial performance? This paper empirically addresses this issue by examining the effect of shifts in strategic emphasis on stock return. Furthermore, this study examines appropriate choices of strategic emphasis to gain differential financial performance. The data set used in this regression analysis comes from the KISLINE database of NICE Information Service. The variables that form the basis of this analysis are stock return, ROA, and Strategic Emphasis [(advertising expenditures-R&D expenditures)/assets]. The interactive effect with situational factors regarding the firm and the type of technological environment in which the firm is operating was also analyzed. Our results show that investors acknowledge a shift of strategic emphasis as a sign of stock valuation. In comparison to US, Korean business firms have weak value creation capabilities in high-technology industries, and weak value appropriation capabilities in low-technology industries. This proves Korean firms are fast followers in the global market. Our findings suggest that Korean firms have to adopt a balanced value strategy, nurturing value creation and developing value appropriation for overcoming the current economic downturn and becoming a first mover in the dawn of "Industry 4.0."

• Journal of the Korea Convergence Society
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• v.8 no.12
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• pp.329-341
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• 2017

In order to analyze how the entrepreneurship affects the commercialization performance in relation to R&D input factors, technological innovation and technology in the course of technology commercialization process. Korean manufacturing venture companies has been surveyed. The structural equation model showed technology commercialization mechanism driven by entrepreneurship. Innovativeness is one of the most important factors in the success of venture firms. Technology commercialization was dependent on innovation rather than the input of research and development resources. Technological innovation shows mediating effects in the influence of entrepreneurship on commercialization performance, but technology capability has relatively small effect. Commercialization process of new product development and product improvement was different. The government needs to actively support R&D strategies and commercialization infrastructure in order to promote innovation, assist R&D workforce and enhance product commercialization in venture companies.