• Korean Journal of Metals and Materials
• /
• v.50 no.3
• /
• pp.201-205
• /
• 2012

The effects of various manganese precursors for the low-temperature selective catalytic reduction (SCR) of $NO_x$ were investigated in terms of structural, morphological, and physico-chemical analyses. $MnO_x/TiO_2$ catalysts were prepared from three different precursors, manganese nitrate, manganese acetate(II), and manganese acetate(III), by the sol-gel method. The manganese acetate(III)-$MnO_x/TiO_2$ catalyst tended to suppress the phase transition from the anatase structure to the rutile or the brookite after calcination at $500^{\circ}C$ for 2 h. It also had a high specific surface area, which was caused by a smaller particle size and more uniform distribution than the others. The change of catalytic acid sites was confirmed by Raman and FT-IR spectroscopy and the manganese acetate(III)-$MnO_x/TiO_2$ had the strongest Lewis acid sites among them. The highest de-NOx efficiency and structural stability were achieved by using the manganese cetate(III) as a precursor, because of its high specific surface area, a large amount of anatase $TiO_2$, and the strong catalytic acidity.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.8
• /
• pp.2446-2450
• /
• 2013

Oxindole dimers have been used as intermediates in the synthesis of various cyclotryptamine alkaloids. An efficient direct synthesis of oxindole dimers has been carried out from 3-substituted oxindoles via an oxidative dimerization using manganese(III) acetate or copper acetate/silver acetate system.

• Applied Chemistry for Engineering
• /
• v.17 no.6
• /
• pp.648-652
• /
• 2006

Demand for $MnO_{2}$ has been increased with interest for its various applications in the fields of battery, catalyst, and capacitor. In this study, $MnO_{2}$ hollow microspheres were synthesized by sacrificial core method. $MnO_{2}$ nano particles were produced by the hydrolysis and condensation of manganese acetate. The stable $MnO_{2}$ hollow microspheres can very well be synthesized with mixing 0.2% of water, 0.65 mM of manganese acetate, and 0.02 mM catalyst at a room temperature.

• Journal of the Korean Professional Engineers Association
• /
• v.9 no.1
• /
• pp.35-39
• /
• 1976

Possible methods of protection of non cellulosic fibers, particularly nylon filament yarn, from the damaging effects of light are discussed. Manganese acetate, cupricacetate, G1-06-196 and sodium phosphate are used as a light stabilizer for nylon filament yarn. The light stability of filament containing different weight of TiO$_2$ is increased as the following order: Bright>Semi-Dull>Full-Dull The protection effect against light according to the present of the light stabilizer in filament increased in the following order: Manganese acetate> Cupric acid> G1-06-196> Sodium phosphate Manganese acetate is shown to be the most effecting salt for protecting nylon against light. 15 ppm of the salt is shown to be effective enough for protecting nylon filament yarn against light.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.10a
• /
• pp.29.1-29.1
• /
• 2011

The selective catalytic reduction (SCR) of $MnO_x$ with $NH_3$ is an effective method for the removal of $MnO_x$ from stationary system. The typical catalyst for this method is $V_2O_5-WO_3(MoO_3)/TiO_2$, caused by the high activity and stability. However, This catalyst is active within $300{\sim}400^{\circ}C$ and occurs the pore plugging from the deposition of ammonium sulfate salts on the catalysts surface. It needs to locate the SCR unit after the desulfurizer and electrostatic precipitator without reheating of the flue gas as well as deposition of dust on the catalyst. The manganese oxides supported on titania catalysts have attracted interest because of its high SCR activity at low temperature. The catalytic activity of $MnO_x/TiO_2$ SCR catalyst with different manganese precursors have investigated for low-temperature SCR in terms of structural, morphological, and physico-chemical analyses. The $MnO_x/TiO_2$ were prepared from three different precursors such as manganese nitrate, manganese acetate (II), and manganese acetate (III) by the sol-gel method and then it calcinated at $500^{\circ}C$ for 2 hr. The structural analysis was carried out to identify the phase transition and the change intensity of catalytic activity by various manganese precursors was analyzed by FT-IR and Raman spectroscopy. These different precursors also led to various surface Mn concentrations indicated by SEM. The Mn acetate (III) tends to be more suppressive the crystalline phase (rutile), and it has not only smaller particle size, but also better distributed than the others. It was confirmed that the catalytic activity of MA (III)-$MnO_x/TiO_2$ was the highest among them.

• Applied Chemistry for Engineering
• /
• v.23 no.1
• /
• pp.105-111
• /
• 2012

Manganese (Mn) catalysts were generated using $CeO_2$ and $ZrO_2$supports synthesized by the supercritical hydrothermal method and two different Mn precursors, aimed at an application for a low-temperature selective catalytic reduction process. Manganese acetate (MA) and manganese nitrate (MA) were used as Mn precursors. Effects of the kind and the concentration of the Mn precursor used for catalyst generation on the NOx removal efficiency were investigated. The characteristics of the generated catalysts were analyzed using $N_2$ adsorption-desorption, thermo-gravimetric analysis, X-ray diffraction, and X-ray photoelectron spectroscopy. De-NOx experiments were carried out to measure NOx removal efficiencies of the catalysts. NOx removal efficiencies of the catalysts generated using MA were superior to those of the catalysts generated using MN at every temperature tested. Analyses of the catalyst characteristics indicated that the higher NOx removal efficiencies of the MA-derived catalysts stemmed from the higher oxygen mobility and the stronger interaction with support material of $Mn_2O_3$ produced from MA than those of $MnO_2$ produced from MN.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.10
• /
• pp.1455-1456
• /
• 2004

• Korean Journal of Crystallography
• /
• v.12 no.4
• /
• pp.212-215
• /
• 2001

The hydrothermal reaction between manganese nitrate (Mn(NO₃)₂·H₂O ) and midzole-4,5-dicarboxylic acid(IDCH₂) in the presence of sodium acetate (NaOAC·3H₂O) gave a two-dimensional manganese-imidazoledicarboxylate coordination polymer with an empirical formula of [Mn(IDC)(H₂O)](1) Compound 1 was characterized by spectroscopy (IR) and X-ray diffraction. Crystal-lographic date for 1: orthorhombic space group, Pbca, a=7.257(5) Å b=13.687(5)Å, c=14.332(6)Å Z=8, R(wR₂)=0.0498(0.0999).

• Bulletin of the Korean Chemical Society
• /
• v.23 no.11
• /
• pp.1635-1639
• /
• 2002

A new solvent polymeric membrane sensor based on tetra(p-chlorophenyl)porphyrinato manganese (III) acetate is described which demonstrates excellent selectivity toward the triiodide ion. The electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-2}$ M and 7.0 ${\times}$$10^{-6}$M with a Nernstian slope of $-59.6{\pm}1$ mV per decade and a detection limit of 5.0 ${\times}$$10^{-6}$M. The proposed sensor revealed good selectivities for triiodide over a wide variety of other anions and could be used in a pH range 2-9. The electrode can be used for at least two months without any considerable divergence in potential. It was applied as indicator electrode in potentiometric titration of the triiodide and As(III) ions.

• Bulletin of the Korean Chemical Society
• /
• v.19 no.11
• /
• pp.1175-1179
• /
• 1998

The aerobic reaction of 2-(acetylpyridine)-S-methyldithiocarbazate (acpy-mdtcH) and 2-(acetylpyridine)-N-phenylthiosemicarbazate(acpy-phTscH) with manganese(Ⅱ) acetate affords Mn(acpy-mdtc)2 and Mn(acpyphTsc)2, respectively. The spectroscopic data and X-ray structure of Mn(acpy-mdtc)2 are reported. Crystal data for Mn(acpy-mdtc)2; C18H20N6S4Mn, mol wt 503.58, monoclinic crystal system(P21/c) a=12.240(5) Å, b= 10.918(l) Å, c=17.651(3) Å, β=105.93(2), and V=2268(l) Å3, Z=4, 5071 data collected with 0°< 2θ < 52.64°, 2995 data with I > 3σ(I), R= 0.046, Rw= 0.065. The ligands act as tridentate NNS donors. The two Mn-S distances are not equal, and respectively 2.512(2) Å and 2.541(2) Å. The average Mn-N (azomethine) length, 2.242(5) Å, is slightly shorter than the average Mn-N (pyridyl) length, 2.262(5) Å. The coordination environment about MN(Ⅱ) center deviates considerably from octahedral geometry. The manganese(Ⅱ)-manganese(Ⅰ) and manganese(Ⅰ)-manganese(0) reduction potentials of Mn(acpy-mdtc)2 are ∼-l.71 and ∼-l.98 V while those of Mn(acpy-phTsc)2 are ∼-l.87 and ∼-2.11 V vs. Ag/Ag+ in dimethyl sulfoxide, respectively.