• Title/Summary/Keyword: Main compounds

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Characteristics of Carbonaceous and Organic Components in PM2.5 over the Yellow Sea (서해상 PM2.5 내 탄소성분 및 유기성분의 화학적 특성)

  • Yoo, Ha Young;Kim, Ki Ae;An, Hyunjin;Lee, Yeonjung;Zihui, Teng;Yoo, Hee-Jung;Kim, Jeong Eun;Ko, Hee-Jung;Sung, Min-Young;Choi, Jin-Soo;Park, Jin-Soo;Lee, Ji Yi
    • Atmosphere
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    • v.31 no.3
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    • pp.267-282
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    • 2021
  • Characteristics of carbonaceous components and organic compounds in PM2.5 over the atmosphere of the Yellow Sea were investigated. PM2.5 samples were collected onboard the meteorological research vessel, GISANG 1, over the Yellow Sea during the YES-AQ campaign in 2018 and 2019, respectively. The average concentrations of carbonaceous components in this region were 2.59 ± 1.59 ㎍ m-3 for the OC, 0.24 ± 0.10 ㎍ m-3 for the EC, 2.14 ± 1.30 ㎍ m-3 for the WSOC and 1.17 ± 0.94 ㎍ m-3 for the HULIS-C, respectively. The total concentration of 56 organic compounds (ΣOCs) accounts for 10% of OC. The main group among organic compounds were dicarboxylic acids which account for 57% of ΣOCs, followed by n-alkanoic acids accounting for 34% of ΣOCs. In n-alkanoic acid distribution, hexanoic (C6:0) and octanoic (C8:0) acids which are low molecular weight n-alkanoic acids and known as emitted from marine biogenic activities were dominant in this region. Furthermore, non-HULIS-C fraction increased when the air mass originated from the marine region rather than the continental region. When the Asian dust episode was observed, the WISOC concentrations along with the levoglucosan were increased, while the haze episodes caused the increase of WSOC, HULIC-S and DCAs. In this study, we found that the components of carbonaceous and organic aerosols in PM2.5 over the Yellow Sea were changed with the specific air pollution episodes. It indicates that the physicochemical properties of PM2.5 can be changed by the air pollution episodes in this region.

Changes of Nitrogen Compounds and Nutritional Evaluation of Soybean Sprout -Part VI. Changes in electrophoretic pattern of protein- (콩나물 제조중(製造中) 질소화합물(窒素化合物)의 변화(變化)와 그 영양학적(營養學的) 연구(硏究) -제육보(第六報). 단백질(蛋白質)의 전기영동양상변화(電氣泳動樣相變化)-)

  • Yang, Cha-Bum;Park, Sang-Ki;Yoon, Suk-Kwon;Park, Hoon
    • Applied Biological Chemistry
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    • v.27 no.2
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    • pp.129-134
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    • 1984
  • Change of protein component in soybean sprout grown at four temperatures was investigated by polyacrylamide gel electrophoresis. Main bands were identified using purified seed globulins. Electrophoretogram showed 5 main bands (a. b, c, d, and p) and 10 minor bands in seed and maximum number (19) of bands (8 main band including 0 and 11 minor) at 4th day after germination in cotyledon. All bands appeared in axis protein but resolution was poor. In cotyledon, a component (most rapidly) and b+c+d component decreased while o+p component and other minor components were increased at 6th day and decreased thereafter. In axis all components increased rapidly, especially in minor components and b+c+d component. High growing temperature accelerated decrease in cotyledon and increase in axis of protein, especially for 11S. The a component was identified as 7S, b+c+d as 11S and o+p as 2S globulin.

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Mixed Design of Grouting Materials for Settlement Restoration Using Micro Cement (마이크로시멘트를 이용한 침하복원용 그라우팅재료의 배합 설계)

  • Lee, Il-Wha;Lee, Sung-Jin;Yun, Won-Min;Park, Sung-Ki
    • Proceedings of the KSR Conference
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    • 2011.05a
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    • pp.1786-1792
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    • 2011
  • If the concrete track is settled excessively, it must be restored or reinforced immediately. Especially, reinforcement/restoration method should be applied without affecting on train operation. To deal with this problem, special equipment, process and material should be prepared. This paper suggest a special mixing ratio to restore the settled concrete track. Materials are classified the quick hardening mortar and the middle hardening mortar. The quick hardening mortar is used to restore the settled track and the middle hardening mortar is used to fill the void. These materials must have the appropriate gel time(1-40sec) and compressive strength($5kg/cm^2$). Various compounds is used and the micro cement is used as a main base.

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A Strong Dependence of the P-P Bond Length on the Transition Metal Component in ThCr2Si2-Type Phosphides CaM2P2 (M = Fe, Ni): The Influence of d Band Position and σp* Mixing

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1215-1218
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    • 2003
  • An analysis of the bonding situation in CaM₂P₂ (M=Fe, Ni) with ThCr₂Si₂ structure is made in terms of DOS and COOP plots. The main contributions to covalent bonding are due to M-P and P-P interactions in both compounds. Particularly, the interlayer P-P bonding by variation in the transition metal is examined in more detail. It turns out that the shorter P-P bonds in CaNi₂P₂ form as a result of the decreasing electron delocalization into ${{\sigma}_p}^*$ of P₂ due to the weaker bonding interaction between the metal d and ${{\sigma}_p}^*$ as the metal d band is falling from Fe to Ni.

The Phonetic Realization of High Tone in North Kyungsang Korean

  • Chang, Woo-Hyeok
    • Speech Sciences
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    • v.11 no.3
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    • pp.37-54
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    • 2004
  • The main goal of this study is to examine the current issue of the deletion of high tone vs. the downstep or upstep of high tone in North Kyungsang Korean (NKK). In this phonetic experiment, five native speakers of North Kyungsang Korean participated and two categories, such as compounds and two-word phrases were included as a test material. This experiment shows that when the first word belongs to the nonfinal class, the high tone of the second word is overwhelmingly deleted. When the first word belongs to the final class, the high tone of it is also overwhelmingly deleted. It is thus concluded that when two words are combined into a phrase, the peak of one word retains, whereas the peak of the other is deleted. It is confirmed that a single high tone prominence in a phonological phrase in NKK is not due to the processes of down step or upstep but the deletion process.

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The protective effects of trace elements against side effects induced by ionizing radiation

  • Hosseinimehr, Seyed Jalal
    • Radiation Oncology Journal
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    • v.33 no.2
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    • pp.66-74
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    • 2015
  • Trace elements play crucial role in the maintenance of genome stability in the cells. Many endogenous defense enzymes are containing trace elements such as superoxide dismutase and metalloproteins. These enzymes are contributing in the detoxification of reactive oxidative species (ROS) induced by ionizing radiation in the cells. Zinc, copper, manganese, and selenium are main trace elements that have protective roles against radiation-induced DNA damages. Trace elements in the free salt forms have protective effect against cell toxicity induced by oxidative stress, metal-complex are more active in the attenuation of ROS particularly through superoxide dismutase mimetic activity. Manganese-complexes in protection of normal cell against radiation without any protective effect on cancer cells are more interesting compounds in this topic. The aim of this paper to review the role of trace elements in protection cells against genotoxicity and side effects induced by ionizing radiation.

Recycling Process of WC Fine Powder Contained by Cemented Carbides Parts in JAPAN

  • Mitsuru Nakamura;Kim, Ha-Young;Hwang, Sun-Hyo
    • Proceedings of the KWS Conference
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    • 1999.10a
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    • pp.297-298
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    • 1999
  • Cemented carbides material (WC-Co hard alloy) were recognized very important and expensive tool or die assembly parts because of compose for the main elements of rare metal (W and Co etc). This research was developed to separate and recover of WC fine powder contained by WC-Co materials. Recycling process was a new method named by the Tin impregnation for decobaltification on cemented carbides. This reaction occurred to product a brittle Co-Sn intermetallic compounds, thereafter it carried out by acid cleaning solution and physical milling or powdering. New process was able to recover about 60% WC fine powder from 1 to 5 ${\mu}{\textrm}{m}$.

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Antioxidative Activity of Low Molecular Weight Biocompounds Purified from Anchovy (Engraulis japonicus) Sauce (멸치액젓 유래 저분자 물질의 항산화활성)

  • CHOI Geun-Pyo;SEO Jung-Gil;KIM Sang-Moo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.4
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    • pp.321-326
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    • 2003
  • Antioxidative activities of low molecular weight biocompounds purified from anchovy (Engraulis japonicus) sauce fermented at $15\pm3^{\circ}C$ for 5 years were investigated. The fermented anchovy sauce showed 5 peaks on gel chromatography pattern. Antioxidant activity of peak 2 was $82.7\%$ followed by $42.6\%$ of peak 1. Main antioxidant compounds of peak 1 were glutamic acid and lysine, but those of peak 2 were not confirmed by amino acid sequence analysis.

Systematic Analysis of Ginseng-focused Research Worldwide (국내외 인삼연구동향에 대한 분석 및 고찰연구)

  • Park, Hye-Jung;Son, Chang-Gue
    • The Journal of Korean Medicine
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    • v.29 no.1
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    • pp.60-66
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    • 2008
  • Objective : To construct a comprehensive understanding of thepharmaceutical efficacies of ginseng, then build a basis for a research strategy for development of Korean ginseng as a globally-competitive medical product. Methods : Surveying literature, we found 1690 ginseng-focused papers in Pub-Med. Analysis of was done of number of reports according to date, nation, components of Panax ginseng, research methods, and effects of ginseng. Results : The main countries contributing toginseng research are China, Korea, Japan and America. Recently, ginseng-related studies have been increasing, and individual compounds from ginseng or its products rather than ginseng itself are subjects for study. Anti-cancer associated or neuroprotective effects showed priority in therapeutic efficacy. Panax ginseng was the focus of around 60% of all ginseng-related studies, but only 22% of them were done in Korea. Conclusion :This review will help Korean doctors or scientists to systematically understand ginseng as a powerfulherbal medicine, and to develop Korean ginseng as a globally competitive drug in world markets.

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Deuterium-labeling Toward Robust Function of Organic Molecules: Enhanced Photo-stability of Partially Deuterated 1', 3', 3'-Trimethyl-6-nitrospiro[2H-1- benzopyran-2, 2'-indoline]

  • Kawanishi, Yuji;Inoue, Kyoko;Ohta, Shin-Ichi;Miyazawa, Akira
    • Rapid Communication in Photoscience
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    • v.3 no.4
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    • pp.64-66
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    • 2014
  • Synthesis of a deuterium-labeled derivative of nitrospirobenzopyran (NSP), one of representative photochromic compounds, has been described. Four deuteriums were successfully introduced on 1-methyl and ${\alpha}$-methyne relative to spiro-carbon in the title compound with more than 95atom%D purity. Main photodegraded products of NSP were two oxindoles in acetonitrile, and additional products were formed in poly(isobutyl-methacrylate) films possibly due to restricted molecular motion in polymer matrix. Quantitative HPLC analysis revealed that partial introduction of deuterium to NSP brought a noticeable isotope effect, recognizable enhancement in photo-resistivity of NSP, i.e.,8.3% in solutions and 29% in polymeric films.