• Journal of Electrochemical Science and Technology
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• v.9 no.4
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• pp.301-307
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• 2018

The current study fabricated magnetic functional reduced graphene oxide (MFRGO) by relying on ${FeCl_4}^-$ magnetic anion confined to cationic 1-methyl imidazolium. Furthermore, for improving the electrochemical performance of conductive polymer, hybrid poly ortho aminophenol (POAP)/ MFRGO films have then been fabricated by POAP electropolymerization in the presence of MFRGO nanorods as active electrodes for electrochemical supercapacitors. Surface and electrochemical analyses have been used for characterization of MFRGO and POAP/ MFRGO composite films. Different electrochemical methods including galvanostatic charge discharge experiments, cyclic voltammetry and electrochemical impedance spectroscopy have been applied to study the system performance. Prepared composite film exhibited a significantly high specific capacity, high rate capability and excellent cycling stability (capacitance retention of ~91% even after 1000 cycles). These results suggest that electrosynthesized composite films are a promising electrode material for energy storage applications in high-performance pseudocapacitors.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.180.2-180.2
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• 2014

Opening a bandgap by forming graphene nanoribbons (GNRs) and tailoring their properties via doping is a promising direction to achieve graphene-based advanced electronic devices. Applying a first-principles computational approach combining density functional theory (DFT) and DFT-based non-equilibrium Green's function (NEGF) calculation, we herein study the structural, electronic, and charge transport properties of boron-nitrogen binary edge doped GNRs and show that it can achieve novel doping effects that are absent for the single B or N doping. For the armchair GNRs, we find that the B-N edge co-doping almost perfectly recovers the conductance of pristine GNRs. For the zigzag GNRs, it is found to support spatially and energetically spin-polarized currents in the absence of magnetic electrodes or external gate fields: The spin-up (spin-down) currents along the B-N undoped edge and in the valence (conduction) band edge region. This may lead to a novel scheme of graphene band engineering and benefit the design of graphene-based spintronic devices.

• Proceedings of the Korean Magnestics Society Conference
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• 2013.05a
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• pp.17-17
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• 2013

• Proceeding of EDISON Challenge
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• 2017.03a
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• pp.376-382
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• 2017

Graphene nanoribbons with zigzag-shaped edge (zGNRs) are predicted to be magnetic insulator at the ground state, attracting significant interest in view of spintronic applications [1]. On the other hand, although they are energetically and thermodynamically more favored than zGNRs [2], graphene nanoribbons with armchair-shaped edge (aGNRs) have been less spotlighted than zGNRs due to the absence of magnetism. Herein, based on the combined density functional theory (DFT) and matrix Green's function (MGF) approach, we consider aGNRs functionalized with various molecular groups, and show that the spin polarizations develop for some of the considered aGNR edge functionalization cases. The origin of the induced magnetism will be discussed within the Lieb's theorem [3]. This work will provide a novel guidance for the development of graphene-based spintronic devices.

• Steel and Composite Structures
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• v.33 no.6
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• pp.891-906
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• 2019

This study considers the instability behavior of sandwich plates considering magnetorheological (MR) fluid core and piezoelectric reinforced facesheets. As facesheets at the top and bottom of structure have piezoelectric properties they are subjected to 3D electric field therefore they can be used as actuator and sensor, respectively and in order to control the vibration responses and loss factor of the structure a proportional-derivative (PD) controller is applied. Furthermore, Halpin-Tsai model is used to determine the material properties of facesheets which are reinforced by graphene platelets (GPLs). Moreover, because the core has magnetic property, it is exposed to magnetic field. In addition, Kelvin-Voigt theory is applied to calculate the structural damping of the piezoelectric layers. In order to consider environmental forces applied to structure, the visco-Pasternak model is assumed. In order to consider the mechanical behavior of structure, sinusoidal shear deformation theory (SSDT) is assumed and Hamilton's principle according to piezoelasticity theory is employed to calculate motion equations and these equations are solved based on differential cubature method (DCM) to obtain the vibration and modal loss factor of the structure subsequently. The effect of different factors such as GPLs distribution, dimensions of structure, electro-magnetic field, damping of structure, viscoelastic environment and boundary conditions of the structure on the vibration and loss factor of the system are considered. In order to indicate the accuracy of the obtained results, the results are validated with other published work. It is concluded from results that exposing magnetic field to the MR fluid core has positive effect on the behavior of the system.

• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2795-2799
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• 2013

Irradiation of gold nanorods (GNRs) with laser light corresponding to the longitudinal surface plasmon oscillation results in rapid conversion of electromagnetic energy into heat, a phenomenon commonly known as the photothermal effect of GNRs. Herein, we propose a facile strategy for increasing the photothermal conversion efficiency of GNRs by integration to form graphene oxide (GO) nanocomposites. Moreover, conjugation of iron oxide (IO) with the GO-GNR nanohybrid allowed magnetic enrichment at a specific target site and the separated GO-IO-GNR assembly was rapidly heated by laser irradiation. The present GO-IO-GNR nanocomposites hold great promise for application in various biomedical fields, including surface enhanced Raman spectroscopy imaging, photoacoustic tomography imaging, magnetic resonance imaging, and photothermal cancer therapy.

• Structural Engineering and Mechanics
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• v.74 no.6
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• pp.809-819
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• 2020

For the first time, the influence of in-plane magnetic field on wave propagation of Graphene Nano-Platelets (GNPs) polymer composite nanoplates is investigated here. The impact of three- parameter Kerr foundation is also considered. There are two different reinforcement distribution patterns (i.e. uniformly and non-uniformly) while the material properties of the nanoplate are estimated through the Halpin-Tsai model and a rule of mixture. To consider the size-dependent behavior of the structure, Eringen Nonlocal Differential Model (ENDM) is utilized. The equations of wave motion derived based on a higher-order shear deformation refined theory through Hamilton's principle and an analytical technique depending on Taylor series utilized to find the wave frequency as well as phase velocity of the GNPs reinforced nanoplates. A parametric investigation is performed to determine the influence of essential phenomena, such as the nonlocality, GNPs conditions, Kerr foundation parameters, and wave number on the both longitudinal and flexural wave characteristics of GNPs reinforced nanoplates.

• Bulletin of the Korean Chemical Society
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• v.22 no.4
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• pp.367-371
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• 2001

Lithium inserted into artificial carbon has been synthesized as a function of the Li concentration. The characteristics of these prepared compounds were determined from the studies using X-ray diffraction(XRD), solid nuclear magnetic resonance (NM R) spectrophotometric and differential scanning calorimeter(DSC) analysis. X-ray diffraction showed that lower stage intercalation compounds were formed with increasing Li concentration. In the case of the AG3, most compounds formed were of the stage 1 structure. Pure stage 1 structural defects of artificial graphite were not observed. 7Li-NMR data showed that bands are shifted toward higher frequencies with increasing lithium concentration; this is because non-occupied electron shells of Li increased in charge carrier density. Line widths of the Li inserted carbon compounds decreased slowly because of nonhomogeneous local magnetic order and the random electron spin direction for located Li between graphene layers. The enthalpy and entropy changes of the compounds can be obtained from the differential scanning calorimetric analysis results. From these results, it was found that exothermic and endothermic reactions of lithium inserted into artificial carbon are related to the thermal stability of lithium between artificial carbon graphene layers.

• Journal of Magnetics
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• v.18 no.3
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• pp.225-229
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• 2013

We report a measurement for the anomalous Nernst effects induced by a temperature gradient in [CoSiB/Pt] multilayer films with perpendicular magnetic anisotropy. The Nernst voltage shows a characteristic hysteresis which reflects the magnetization of the film as in the case of the anomalous Hall effects. With a local heating geometry, we also measure the dependence of the anomalous Nernst voltage on the distance d from the heating element. It is roughly proportional to $1/d^{1.3}$, which can be conjectured from the expected temperature gradient along the sample from the heat equation.

• Proceedings of the Korean Magnestics Society Conference
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• 2007.05a
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• pp.213.2-213.2
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• 2007