Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Electroactive Conjugated Polymer / Magnetic Functional Reduced Graphene Oxide for Highly Capacitive Pseudocapacitors: Electrosynthesis, Physioelectrochemical and DFT Investigation

  • Ehsani, A. (Department of Chemistry, Faculty of science, University of Qom) ;
  • Safari, R. (Department of Chemistry, Faculty of science, University of Qom) ;
  • Yazdanpanah, H. (Department of Chemistry, Payame Noor University) ;
  • Kowsari, E. (Department of chemistry, Amirkabir University of Technology) ;
  • Shiri, H. Mohammad (Department of Chemistry, Payame Noor University)
  • Received : 2017.07.07
  • Accepted : 2018.07.31
  • Published : 2018.12.31
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Abstract

The current study fabricated magnetic functional reduced graphene oxide (MFRGO) by relying on ${FeCl_4}^-$ magnetic anion confined to cationic 1-methyl imidazolium. Furthermore, for improving the electrochemical performance of conductive polymer, hybrid poly ortho aminophenol (POAP)/ MFRGO films have then been fabricated by POAP electropolymerization in the presence of MFRGO nanorods as active electrodes for electrochemical supercapacitors. Surface and electrochemical analyses have been used for characterization of MFRGO and POAP/ MFRGO composite films. Different electrochemical methods including galvanostatic charge discharge experiments, cyclic voltammetry and electrochemical impedance spectroscopy have been applied to study the system performance. Prepared composite film exhibited a significantly high specific capacity, high rate capability and excellent cycling stability (capacitance retention of ~91% even after 1000 cycles). These results suggest that electrosynthesized composite films are a promising electrode material for energy storage applications in high-performance pseudocapacitors.

Keywords

References

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