• Title/Summary/Keyword: Magnetic orbital

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Spin-glass behavior in (A,B)-site deficient manganese perovskites

  • Lee, Kyu-Won;Phan, Manh-Huong;Yu, Seong-Cho;Nguyen Chau;Tho, Nguyen-Duc
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.150-151
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    • 2003
  • In the past years, a giant magnetoresistance (GMR) effect found in perovskite-like structured materials has attracted considerable attention among scientists and manufacturers, since, a practical point of view, the capacity of producing magnetic and sensing sensors. In a stream of this interest, further efforts to understand the underlying mechanism that leads to the GMR effect relative to the correlation between transport and magnetic properties, have been extensively devoted. In these cases, spin-glass-like behaviors are ascribed to the frustration of random competing exchange interactions, namely the ferromagnetic double-exchange interaction between Co$\^$3+/ (or Mn$\^$3+/) and Co$\^$4+/(or Mn$\^$4+/) and the antiferromagnetic one like spins. Noticeably, the distinction of spin-glass region from cluster-glass one, involved in the remarkable changes in transport and magnetic properties at a critical value of doping concentration, was observed. Magnetic anomalies in zero-field-cooled (ZFC) magnetization as well as ac magnetic susceptibility below Curie temperature T$\sub$c/ and the charge/orbital fluctuation were also realized. In this work, we present a study of magnetic properties of a deficient manganese perovskites system of La$\sub$0.6/Sr$\sub$x/MnTi$\sub$y/O$_3$, and particularly provide its new magnetic phase diagram.

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Electronic and Magnetic Propwrties of a Novel Rare-earth Permanent Magnet : $Sm_{2}Fe_{17}N_{3}$ (신소재 희토류 영구자석, $Sm_{2}Fe_{17}N_{3}$ 화합물의 전자구조 연구)

  • 민병일;양충진
    • Journal of the Korean Magnetics Society
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    • v.3 no.2
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    • pp.94-100
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    • 1993
  • Electronic and magnetic properties of the novel rare-earth permanent magnet, $Sm_{2}Fe_{17}N_{3}$, are investigated by performing self-consistent local density functional electronic structure calculations. Employing the LMTO(Linearized Muffin-Tin Orbital) band method, we have obtained the electronic band structures for both paramag-netic and ferromagnetic phases of $Sm_{2}Fe_{17}N_{3}$. Based on the energy band structures, we have studied bonding ef-fects among Sm, Fe, and N atom as well as electronic and magnetic structures. It is found that the N atom sub-stantially reduces the magnetic moment of neighboring Fe atoms through the hybridization interaction and also plays a role in stabilizing the structure. the average magnetic moment of Fe atoms in the ferromagnetic phase of $Sm_{2}Fe_{17}N_{3}$ is estimated to be $2.33{\mu}_B$, which is ~8% larger than the magnetic moment of $Sm_{2}Fe_{17}$, $2.16{\mu}_B$. The Fe I (c) atom, which is located farthest from the N atom and surrounded by 12 Fe nearest neighbors, has the largest magnetic moment ($2.65{\mu}_B$), while the Fe III (f), whose hybridization interaction with N atom is very strong, has the smallest magnetic moment($1.96{\mu}_B$).

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MASS TRANSFER AND LIGHT TIME EFFECT STUDIES FOR AU SERPENTIS

  • Amin, S.M.
    • Journal of The Korean Astronomical Society
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    • v.48 no.1
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    • pp.1-7
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    • 2015
  • The orbital period changes of the W UMa eclipsing binary AU Ser are studied using the (O-C) method. We conclude that the period variation is due to mass transfer from the primary star to the secondary one at a very low and decreasing rate $dP/dt=-8.872{\times}10^{-8}$, superimposed on the sinusoidal variation due to a third body orbiting the binary with period $42.87{\pm}3.16$ years, orbital eccentricity $e=0.52{\pm}0.12$ and a longitude of periastron passage ${\omega}=133^{\circ}.7{\pm}15$. On studying the magnetic activity, we have concluded that the Applegate mechanism failed to describe the cycling variation of the (O-C) diagram of AU Ser.

Effects of solar variations on standing Alfven waves in the dayside magnetosphere: Polar observations

  • Kim, Khan-Hyuk;Takahashi, Kazue
    • Bulletin of the Korean Space Science Society
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    • 2008.10a
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    • pp.23.4-23.4
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    • 2008
  • In March and April 2001, the apogee (~9 Re) of the Polar spacecraft was located near the subsolar magnetopause with its orbital plane nearly parallel to a magnetic meridian plane. Polar electric and magnetic field data acquired during the two-month interval of solar maximum have been used to study fundamental standing Alfven waves near the subsolar meridian plane (magnetic local time = 1000-1400 hours) at magnetic latitudes from the equator to $\pm45$ degrees and at L values between 7 and 12. In the frequency band from 1.5 to 10 mHz, fundamental mode oscillations were identified based on high coherence (more than 0.7) and an approximately 90-degree phase shift between the azimuthal magnetic and radial electric field components. The L dependence of the fundamental frequencies is studied, and the frequencies are compared with those observed near the solar minimum interval (Takahashi et al. 2001). We found that the average frequencies in solar maximum are lower than those in solar minimum by a factor of ~2. This implies that the mass density in solar maximum is higher than that in solar minimum by a factor of ~4. Since there is a positive correlation between solar irradiance and solar activity, we suggest that the ionosphere in solar maximum produces more ions and load magnetic flux tubes with more ions.

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Magnetic circular dichroism measurement of Co films on Pd(111) substrate

  • Kwanghyun Cho;C. C. Whang;Kim, Wookje;Kim, Wondong;Kim, H.-J.;Kim, Jae-Young;Hoon Koh;S.-J Oh;Park, J.-H.
    • Journal of Korean Vacuum Science & Technology
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    • v.5 no.2
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    • pp.33-37
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    • 2001
  • We measured x-ray magnetic circular dichroism of Co films on Pd(111) surface with and without Pd capping layer at the Co L$_2$,$_3$ edges. Perpendicular magnetization and orbital-moment enhancement are induced by the capping layer. The increase of perpendicular magnetic anisotropy induced by capping layer is considered to result from the increase of surface anisotropy due to the hybridization at the surface.

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FIRST PRINCIPLE CALCULATIONS OF MCD SPECTRA FOR SANDWICHED Co(110) SYSTEMS

  • Hong, Soon-C.;Lee, Jae-Il;Wu, R.;Freeman, A.J.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.575-578
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    • 1995
  • X-ray magnetic-circular-dichroism (MCD) spectra, orbital ($$) and spin magnetic moments ($$) for Co(110) monolayers a free standing mode or sandwiched between Pd(Pd/1Co/Pd)and Cu layers (Cu/1Co/Cu) are calculated using the thin film full potential linearized augmented plane wave energy band method. In contrast to the double peak structure predicted for the Co(0001) surface, only a minor side peak is found in the MCD spectra for Cu/Co/Cu, while MCD spectra for the other systems show a single peak structure. The MCD sum rules originally derived from a single ion model are found in the band approach to be valid for the systems investigated. However, for the spin sum rule, the magnetic dipole term ($$) is not negligible and needs to be included.

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Magnetism in α-RuCl3 : Dependence on Coulomb Interaction and Hund's Coupling

  • Gong, Hoshin;Kim, Kyoo;Ji, Sungdae;Kim, Bongjae;Min, B.I.
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1691-1697
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    • 2018
  • Employing the density functional theory, we have investigated the roles of Coulomb and Hund's interactions in the electronic and magnetic properties of newly discovered ${\alpha}-RuCl_3$ having the $R{\overline{3}}$ symmetry, which is in close proximity of the Kitaev system. We show that both the size and the direction of local magnetic moment are highly dependent on Coulomb and Hund's interactions, and the spin and orbital parts show different behaviors. The validity of the so-called $j^{eff}$ picture is accessed upon interaction parameters, and the explicit roles of Hund's interaction in the local electronic structures and magnetic properties are discussed.

Soft X-ray Synchrotron-Radiation Spectroscopy Study of [Co/Pd] Multilayers as a Function of the Pd Sublayer Thickness (Pd층의 두께 변화에 따른 [Co/Pd] 다층박막의 연엑스선 방사광 분광 연구)

  • Kim, D.H.;Lee, Eunsook;Kim, Hyun Woo;Seong, Seungho;Kang, J.-S.;Yang, Seung-Mo;Park, Hae-Soo;Hong, JinPyo
    • Journal of the Korean Magnetics Society
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    • v.26 no.4
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    • pp.124-128
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    • 2016
  • We have investigated the electronic structures of intermetallic multilayer (ML) films of [$Co(2{\AA})/Pd(x{\AA})$] (x: the thickness of the Pd sublayer; x = $1{\AA}$, $3{\AA}$, $5{\AA}$, $7{\AA}$, $9{\AA}$) by employing soft X-ray absorption spectroscopy (XAS) and soft X-ray magnetic circular dichroism (XMCD). Both Co 2p XAS and XMCD spectra are found to be similar to one another, as well as to those of Co metal, providing evidence for the metallic bonding of Co ions in [Co/Pd] ML films. By analyzing the measured Co 2p XMCD spectra, we have determined the orbital magnetic moments and the spin magnetic moments of Co ions in [$Co(2{\AA})/Pd(x{\AA})$] ML films. Based on this analysis, we have found that the orbital magnetic moments are enhanced greatly when x increases from $1{\AA}$ to $3{\AA}$, and then do not change much for $x{\geq}3{\AA}$. This finding suggests that the interface spin-orbit coupling plays an important role in determining the perpendicular magnetic anisotropy in [Co/Pd] ML films.

Calculation of the Magnetic Moments for Transition Metal Complexes (Ⅱ). The Magnetic Moments for Distorted Octahedral $[V(III)A_3B_3]$ Type Complexes and the Contribution of $^3T_1$ Term to the Dipole Moments and Polarizability [A and B = O, Cl, N or Br] (전이원소착물의 자기모멘트의 계산 (제2보). $t^2_2$ 전자구조를 갖는 일그러진 판면체 $[V(III)A_3B_3]$형태 착물의 자기모멘트와 쌍극자모멘트 및 편극율에 대한 $^3T_1$항의 기여분 [A 와 B = O, Cl, N 또는 Br])

  • Sangwoon Ahn;Se Woung Oh;Kee Hag Lee;Eu Suh Park
    • Journal of the Korean Chemical Society
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    • v.24 no.4
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    • pp.269-279
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    • 1980
  • A method for calulation of the magnetic moments for both octahedral and distorted octahedral $[V(III)A_3B_3]$ type complexes, all with $t^2_2$ configuration, has been developed [A and B = O, Cl, N, F or Br]. The calculated magnetic moments by this method are in reasonable agreements with the experimental values. The calculated magnetic moments for distorted octahedral $[V(III)A_3B_3]$/TEX> type complexes decrease as the extent of tetragonal distortion increases.The effects of k (orbital reduction faction factor), $\xi'$/TEX> and temperature on the magnetic moments are also investigated.A new method for calculation of the contribution of $^3T_1$ molecular orbitals to the dipole moment and polarizability has also developed. The calculated contribution of $^3T_1$ molecular orbitals falls in the reasonable range of values.

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