• Journal of Magnetics
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• v.6 no.2
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• pp.70-72
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• 2001

We have investigated the activation magnetic moment, which characterizes the basic magnetic moment acting as a single magnetic particle during magnetization reversal. The activation magnetic moment was measured from each local area on continuous ferromagnetic thin films, by analyzing the magnetic field dependence of magnetization reversal of the corresponding local area, based on a thermally activated relaxation process. It was found that the activation magnetic moment was nonuniform on a submicrometer scale; the fluctuation increased with increasing the number of layers in Co/Pd multilayers. The distribution could be well described by exp($\delta m^{3/2}$), where $\delta$m is the deviation of the activation magnetic moment from the mean value.

• Journal of the Korean Magnetic Resonance Society
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• v.8 no.2
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• pp.127-138
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• 2004

We obtained the chemical shifts of amide protons (NHs) in helical peptides at various temperatures and trifluoroethanol (TFE) concentrations using 2-dimensional NMR spectroscopy. These NH chemical shifts and their temperature dependence exhibited characteristic periodicity of 3-4 residues per cycle along the helix, where downfield shifted NHs showed larger temperature dependence. In an attempt to understand these observations, we focused on hydrogen bonding changes in the peptides and examined the validity of two possible explanations: (1) changes in intermolecular hydrogen bonding caused by differential solvation of backbone carbonyl groups by TFE, and (2) changes in intramolecular hydrogen bonding due to disproportionate variations in the hydrogen bonding within the peptide helix. Interestingly, the slowly exchanging NHs, which were on the hydrophobic side of the helix, showed consistently larger temperature dependences. This could not be explained by the differential solvation assumption, because the slowly exchanging NHs would become more labile if the preceding carbonyl groups were preferentially solvated by TFE. We suggest that the disproportionate changes in intramolecular hydrogen bonding better explain both the temperature dependence and the exchange behavior observed in this study.

• Journal of the Korean Magnetics Society
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• v.3 no.4
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• pp.277-283
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• 1993

The temperature dependence of DC magnetic susceptibilities of three austenitic Fe-Cr-Ni stainless alloys were measured in the temperature range of 4.2 and 300 K. Two alloys support a general magnetic description of austen-itic stsinless steels in terms of a two-magnetic-phase (spin glass + superparamagnetic cluster) model and one alloy shows magnetic double transition phenomena. Also this study shows that incressing the Ni/Cr ratio in Fe-Cr-Ni alloys causes a increase of the DC susceptibility peak value and a decrease of the magnetic transition temperature.

• Proceedings of the KIEE Conference
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• 1989.11a
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• pp.65-67
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• 1989

To study hopping conducting mechanism in PAN(polyacrylonitrile) carbon fiber, the temperature and frequency dependence of electrical conductivity and magnetoresistance characteristics were investigated. Electrical conductivity in the range of $60^{\circ}K-300^{\circ}K$ show VRH(variable range hopping) properties which introduced by Mott's theory, and also such properties can be explained by the frequency dependence of electrical conductivity below $5{\times}10^6$ Hz. The negative magnetoresistance observed below 35KG magnetic field, and the properties difference between M40 and T300 with increasing magnetic field is supposed due to on effect connected with crystalline state and orientation of structure.

• Journal of the Korean Magnetic Resonance Society
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• v.2 no.1
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• pp.66-83
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• 1998

Study on spin-rotation relaxation of nuclear spins located on a methyl group can reveal valuable dynamic information related to the internal rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotational relaxation rate in toluene and 2-chloro-p-xylene over the temperature range of 179-363K. To interpret the temperature dependence of measured spin-rotational relaxation rate we have revised the temperature dependence of measured spin-rotational relaxation rate we have revised the expression derived thus far by other authors and reproduced experimental data on the basis of the newly derived expression. The results confirmed that our expression leads to better agreement with experimental data than the previous one over observed temperature range, especially at high temperature.

• Progress in Superconductivity
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• v.9 no.2
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• pp.136-139
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• 2008

InAs semiconductor nanowires can provide a promising platform to integrate superconducting quantum circuit, which exploits tunable supercurrent under the operation of gate voltage. We report temperature and magnetic field dependence of the nanowire superconducting junctions, which is in agreement with the proximity-effect theory of superconductor-normal metal-superconductor weak link. Superconducting coherence length of the InAs nanowire is estimated from the fit and magnetic-field dependence of the critical current and the subgap structure of dI/dV is discussed as well.

• Journal of Magnetics
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• v.2 no.4
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• pp.135-137
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• 1997

We report the salient features of the magnetic properties of amorphous TM70Cr5Si10B15(TM=Fe, Co, Ni) alloys. The temperature dependence of magnetization for amorphous ribbons were measured by a SQUID and a VSM from 5 K to 700 K under an external field of 10 kOe. Except TM70Cr5Si10B15 that shows a paramagnetic behaviour, both Fe and Co based amorphous alloys show a typical ferromagnetic thermo-magnetization curves. For these two ferromagnetic alloys, the saturation magnetization in the temperature range from 5 K to about 0.4 Tc can be descrived by the Bloch relation, Ms (T)=Ms(0) [1-BT3/2-CT5/2]. The spin wave stiffness constants and the range of exchange interaction were analyzed from the magnetization behaviour. The variation of the magnetic properties are discussed and compared with the composition of the alloys.

• Bulletin of the Korean Chemical Society
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• v.30 no.5
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• pp.1143-1146
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• 2009

[$Mn_{12}O_{12}(azo-L)_{16}(H_2O)_4$] (1), a new Mn12 single molecule magnet containing a photochromic azobenzene ligand, has been successfully synthesized by substitution of acetate ligand of Mn12 with 6-[4-{4-hexyloxyphenyl( azo)}-phenoxy]hexanoic-1-acid. The reversible photoisomerization of the azobenzene group was confirmed by UV-visible absorption spectroscopy. The temperature and field dependence of dc susceptibility and the temperature and the frequency dependence of ac susceptibility were measured for the cis and the trans isomer of 1. The magnetization value of the cis isomer in dc measurement is higher than that of the trans isomer. The cis isomer of 1 has a slower relaxation because cis-trans photoisomerization of the azobenzene group in peripheral ligands induces changes in its structure and dipole moment.

• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.279-286
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• 2000

Magnetic field dependence of magnetization reversal in Co/Pt multilayers has been quantitatively investigated. Serial samples of Co/Pt multilayers have been prepared by dc-magnetron sputtering under various Ar pressure. Magnetization reversal was monitored by magnetization viscosity measurement and direct domain observation using a magneto-optical microscope system, and the wall-motion speed and the nucleation rate R were determined using a domain reversal model based on time-resolved domain reversal patterns. Both and R were found to be exponentially dependent on the reversing applied field. From the exponential dependencies, the activation volumes of the wall motion and nucleation could be determined based on a thermally activated relaxation model, and the wall-motion activation volume was revealed to be slightly larger than the nucleation activation volume.

• Journal of the Korean Magnetic Resonance Society
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• v.17 no.2
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• pp.92-97
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• 2013

We study the electron spin resonance line-width (ESRLW) of $Fe^{3+}$ in crystalline $LiNbO_3$ ; the ESRLW is obtained using the projection operator method (POM) developed by Argyres and Sigel. The ESRLW is calculated to be axially symmetric about the c-axis and is analyzed by the spin Hamiltonian with an isotopic g factor at a frequency of 9.5 GHz. The ESRLW increases exponentially as the temperature increases, and the ESRLW is almost constant in the high-temperature region (T>8000 K). This kind of temperature dependence of the ESRLW indicates a motional narrowing of the spectrum when $Fe^{3+}$ ions substitute the $Nb^{5+}$ ions in an off-center position. It is clear from this feature that there are two different regions in the graph of the temperature dependence of the ESRLW.