• Membrane and Water Treatment
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• 제11권1호
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• pp.1-10
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• 2020

An understanding of particle-particle interactions in filtration requires studying the detachment as well as the attachment of nanoparticles. Nanoparticles captured in a granular media filter can be released by changing the physicochemical factors. In this study, the detachment of captured silver nanoparticles (AgNPs) in granular media filtration was examined under different ionic strengths, ion type, and the presence or absence of natural organic matter (NOM). Filtration velocity and ionic strength were chosen as the physical and chemical factors to cause the detachment. Increasing filtration velocity caused a negligible amount of AgNP detachment. On the other hand, lowering ionic strength showed different release amounts depending on the background ions, implying a population of loosely captured particles inside the filter bed. Overall detachment was affected by ionic strength and ion type, and to a lesser degree by NOM coating which resulted in slightly more detachment (in otherwise identical conditions) than in the absence of that coating, possibly by steric effects. The secondary energy minimum with Na ions was deeper and wider than with Ca ions, probably due to the lack of complexation with citrate and charge neutralization that would be caused by Ca ions. This result implies that the change in chemical force by reducing ionic strength of Na ions could significantly enhance the detachment compared to that caused by a change in physical force, due to a weak electrostatic deposition between nanoparticles and filter media. A modification of the 1-D filtration model to incorporate a detachment term showed good agreement with experimental data; estimating the detachment coefficients for that model suggested that the detachment rate could be similar regardless of the amount of previously captured AgNPs.

• Membrane and Water Treatment
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• 제11권1호
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• pp.11-23
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• 2020

The effectiveness of in situ sediment capping as a technique for heavy metal risk mitigation in Hyeongsan River estuary, South Korea was studied. Sites in the estuary were found previously to show moderate to high levels of contamination of mercury, methylmercury and other heavy metals. A 400 m × 50 m section of the river was selected for a thin layer capping demonstration, where the total area was divided into 4 sections capped with different combinations of capping materials (zeolite, AC/zeolite, AC/sand, zeolite/sand). Pore water concentrations in the different sites were studied using diffusive gradient in thin film (DGT) probes. All capping amendments showed reduction in the pore water concentration of the different heavy metals with top 5 cm showing %reduction greater than 90% for some heavy metals. The relative maxima for the different metals were found to be translated to lower depths with addition of the caps. For two-layered cap with AC, order of placement should be considered since AC can easily be displaced due to its relatively low density. Investigation of methylmercury (MeHg) in the site showed that MeHg and %MeHg in pore water corresponds well with maxima for sulfide, Fe and Mn suggesting mercury methylation as probably coupled with sulfate, Fe and Mn reduction in sediments. Our results showed that thin-layer capping of active sorbents AC and zeolite, in combination with passive sand caps, are potential remediation strategy for sediments contaminated with heavy metals.

• Membrane and Water Treatment
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• 제9권3호
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• pp.181-188
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• 2018

A sidestream contains the filtrate or concentrate from the belt filter press, filter backwash and supernatant from sludge digesters. The sidestream flow, which heads back into the sewage treatment train, is about 1-3% less than the influent flow. However, the sidestream can increase the nutrient load since it contains high concentrations of phosphorus and nitrogen. In this study, the removal of PO4-P with organic matter characteristics and bacteriological changes during the sidestream treatment via ladle furnace (LF) slag was investigated. The sidestream used in this study consisted of 11-14% PO4-P and 3.2-3.6% soluble chemical oxygen demand in influent loading rates. LF slag, which had a relatively high $Ca^{2+}$ release compared to other slags, was used to remove $PO_4-P$ from the sidestream. The phosphate removal rates increased as the slag particle size decreased 19.1% (2.0-4.0 mm, 25.2% (1.0-2.0 mm) and 79.9% (0.5-1.0 mm). The removal rates of dissolved organic carbon, soluble chemical oxygen demand, color and aromatic organic matter ($UV_{254}$) were 17.6, 41.7, 90.2 and 77.3%, respectively. Fluorescence excitation-emission matrices and liquid chromatography-organic carbon detection demonstrated that the sidestream treatment via LF slag was effective in the removal of biopolymers. However, the removal of dissolved organic matter was not significant during the treatment. The intact bacterial biomass decreased from $1.64{\times}10^8cells/mL$ to $1.05{\times}10^8cells/mL$. The use of LF slag was effective for the removal of phosphate and the removal efficiency of phosphate was greater than 80% for up to 100 bed volumes.

• Membrane and Water Treatment
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• 제9권3호
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• pp.163-172
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• 2018

This study investigated the effect of organic matter on the precipitation of struvite and calcium phosphate for phosphorus recovery from synthetic dairy wastewater. Batch precipitation experiments were performed to precipitate phosphorus from solutions containing $PO_4{^{3-}}$ and $NH_4{^+}$ by the addition of $Mg^{2+}$ and $Ca^{2+}$, separately, at varying pH, Mg/P and Ca/P molar ratios, and organic matter concentrations. Soluble total organic solids exhibited more inhibition to precipitation due to potential interaction with other dissolved ionic species involved in phosphorus precipitation. Xylan with low total acidity only exhibited significant inhibition at very high concentrations in synthetic wastewater (at up to 100 g/L). No significant inhibition was observed for Mg and Ca precipitation at relatively lower concentrations (at up to 1.2 g/L). MINTEQ simulations show that dissolved organic matter (DOM) as humic substances (HS) can cause significant inhibition even at relatively low concentrations of 0.165 g/L fulvic acid. However, scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis suggested that xylan altered the crystal structure of both precipitates and had caused the formation of smaller sized struvite crystals with slightly rougher surfaces This could be due to xylan molecules adhering on the surface of the crystal potentially blocking active sites and limit further crystal growth. Smaller particle sizes will have negative practical impact because of poorer settleability.

• Membrane and Water Treatment
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• 제9권3호
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• pp.137-146
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• 2018

Soil washing is one of the most frequently used remediation technologies for heavy metal-contaminated soils. Inorganic and organic acids and chelating agents that can enhance the removal of heavy metals from contaminated soils have been employed as soil washing agents. However, the toxicity, low removal efficiency and high cost of these chemicals limit their use. Given that humic substance (HS) can effectively chelate heavy metals, the development of an eco-friendly, performance-efficient and cost-effective soil washing agent using a nano-scale chelator composed of HS was examined in this study. Copper (Cu) and lead (Pb) were selected as target heavy metals. In soil washing experiments, HS concentration, pH, soil:washing solution ratio and extraction time were evaluated with regard to washing efficiency and the chelation effect. The highest removal rates by soil washing (69% for Cu and 56% for Pb) were achieved at an HS concentration of 1,000 mg/L and soil:washing solution ratio of 1:25. Washing with HS was found to be effective when the pH value was higher than 8, which can be attributed to the increased chelation effect between HS and heavy metals at the high pH range. In contrast, the washing efficiency decreased markedly in the low pH range due to HS precipitation. The chelation capacities for Cu and Pb in the aqueous phase were determined to be 0.547mmol-Cu/g-HS and 0.192mmol-Pb/g-HS, respectively.

• 한국통신학회논문지
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• 제35권5A호
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• pp.466-473
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• 2010

에너지 효율성과 같은 센서 네트워크에 중요한 요소들을 보장하기 위한 트리기반 프로토콜들이 여럿 제시되었다. 하지만 선박이나 해양 분야와 같이 베이스 노드의 이동성이 큰 네트워크 환경을 전제로 한 토폴로지에 대한 연구는 부족하였다. 본 논문에서는 베이스 노드의 이동성이 큰 센서 네트워크 환경에 적합한 토폴로지로 최소 Wiener 수 신장트리를 제안한다. 가중치 있는 그래프로부터 최소 Wiener 수를 가진 신장트리를 구하는 문제는 NP-hard로 알려져 있다. 문제 해결을 위해 분기 한정 알고리즘을 설계하고 대표적인 신장트리 중 하나인 최소신장트리를 대상으로 1라운드 패킷 전송에 필요한 전송 거리 및 에너지 소모량, 네트워크 수명을 모의실험을 통해 비교하였다. 전송 거리와 에너지 소모량은 제시한 트리가 최소신장트리에 비해 우수하였지만 네트워크 수명은 오히려 열등함을 알 수 있었다.

• 에너지공학
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• 제21권3호
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• pp.292-300
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• 2012

한수원 중앙연구원은 2007년부터 정부과제의 하나로 열출력 4361MWt GEN.III+ 원전인 APR+를 개발하고 있다. APR1400에 비해 보다 개선된 안전성과 경제성을 갖는 원전을 개발하기 위해 국내외 건설 중인 원전설계와 해외 개발 중인 ALWR(Advanced Light Water Reactor)의 설계내용 및 후쿠시마 원전사고로부터 도출된 개선사항을 반영하여 한국 실정에도 맞고, 해외 수출형 원전에도 부합되는 신개념원전 설계를 진행하고 있다. 기술개발 2단계인 표준상세설계에서 2회의 경제성 평가가 수행되었다. 2단계 표준상세설계 2차 경제성 평가결과 APR+ N-th호기는 국내석탄화력 1000MWe급 대비 24.6% 경쟁력우위와 해외원전 대비 충분한 경쟁력을 갖는 것으로 평가되었다.

• 한방재활의학과학회지
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• 제21권2호
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• pp.227-238
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• 2011

Objectives : This study was to investigate the effects on using Virtual reality exercise program($Wii-Fit^{TM}$) for dynamic balance and walking ability in patients with stroke. Methods : The 22 subjects were randomly selected from the patients of the S hospital who met the study conditions. They were divided into a $Wii-Fit^{TM}$ balance game group of 12 patients and a conventional physical therapy group of 10 patients. The $Wii-Fit^{TM}$ balance game group received $Wii-Fit^{TM}$ balance game group general physiotherapy for 5 days a weeks, 30 minutes a day, for a 4 weeks and the conventional physical therapy group received general physiotherapy for the same period. The subjects were measured and compared for Brunel balance assessment, functional gait assessment, 6 minute walk test, GAITRite system before and after the program. Results : The experimental group tend to improve more than control group in shifting the weight to the affected side(p=0.040) and tap test(p<0.001). The experimental group tend to improve more than control group in FGA(p=0.016). The experimental group improved significantly more than control group in 6MWT(p=0.008). The experimental group improved significantly more than control group in gait speed, cadence, stride length. Conclusions : Virtual Reality program($Wii-Fit^{TM}$) with conventional physical therapy shows the benefits on dynamic balance and gait parameters in patients with stroke.

• Current Photovoltaic Research
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• 제1권1호
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• pp.17-26
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• 2013

In contrast to conventional crystalline cells, back-contact solar cells feature high efficiencies, simpler module assembly, and better aesthetics. The highest commercialized cell and module efficiency was recorded by n-type back-contact solar cells. However, the mainstream PV industry uses a p-type substrate instead of n-type due to the high costs and complexity of the manufacturing processes in the case of the latter. P-type back-contact solar cells such as metal wrap-through and emitter wrap-through, which are inexpensive and compatible with the current PV industry, have consequently been developed. In this paper the characteristics of EWT (emitter wrap-through) solar cells and their status and prospects for development are discussed.

• Membrane and Water Treatment
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• 제6권3호
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• pp.237-249
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• 2015

In this study we investigate a laboratory scale vacuum membrane distillation system to produce pure water from model oil in water emulsion. Experimental determination of liquid entry pressure (LEP) of a commercial Durapore$^{TM}$ GVPH flat sheet membrane using model emulsions in various oil concentrations has been carried out. Two different methods of liquid entry pressure determination - a frequently used, so-called static and a novel dynamic method - have been investigated. In case of static method, LEP value was found to be 2.3 bar. No significant effect of oil content on LEP was detected up to 3200 ppm. In contrast, LEP values determined with dynamic method showed strong dependence on the oil concentration of the feed and decreased from 2.0 bar to a spontaneous wetting at 0.2 bar in the range 0-250 ppm, respectively. Vacuum membrane distillation tests were also performed. The separation performance is evaluated in terms of flux behavior, total organic carbon removal and droplet size distribution of the feed and final retentate. No significant effect of oil content on the flux was found ($5.05{\pm}0.31kgm^{-2}h^{-1}$) up to 250 ppm, where a spontaneous wetting occurred. High separation performance was achieved along with the increasing oil concentration between 93.4-97.0%.