• Title/Summary/Keyword: MOP

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PIII&D(Plasma Immersion Ion Implantation & Deposition) 공정으로 제조된 인공 관절용 NbN 박막코팅층의 특성 평가

  • Park, Won-Ung;Choe, Jin-Yeong;Jeon, Jun-Hong;Im, Sang-Ho;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.349-349
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    • 2011
  • 인공관절은 노인성 질환이나 자가 면역질환, 신체적인 외상 등으로 인하여 발생하는 관절의 손상 부위를 대체하기 위해 고안된 관절의 인공 대용물이다. 인공 관절 중 인공 고관절의 경우 관절 운동을 하는 라이너(Liner)와 헤드(Head) 부분이 인공관절의 수명을 결정하게 되는데, 헤드 부분에 메탈소재와 라이너 부분에 고분자 소재를 사용하는 MOP(metal on polymer) 구조의 인공관절은 충격흡수의 장점이 있는 반면 wear debris에 의한 골용해로 인하여 관절이 느슨해지는 문제점이 발생하여 재 시술의 주요 원인이 되고 있다. 현재 인공관절의 수명을 늘리기 위해 DLC, ZrO, TiN 등의 높은 경도 값을 갖는 박막을 금속헤드 위에 증착하여 상대재인 인공관절용 고분자 소재의 마모량을 줄이고자 하는 연구가 활발하게 진행되고 있다. 따라서 본 연구에서는 PIII&D(Plasma Immersion Ion Implantation & Deposition)공정을 이용하여 Co-Cr-Mo 합금 소재에 질소 이온을 주입 한 후 NbN 박막을 증착하여 상대재인 초고분자량 폴리에틸렌(UHMWPE)의 마모량을 줄이고자 하였다. NbN 박막의 특성을 평가하기 위해 XRD, XPS, AFM 등의 분석을 수행하였으며, 상대재인 초고분자량 폴리에틸렌의 마모량을 측정하기 위해 Pin-on-disk tribometer를 이용하여 마모 실험을 진행하였다. 마모 실험 결과, NbN 박막을 단순 증착한 경우, 현재 인공관절용 헤드(Head) 소재로 가장 널리 사용되고 있는 Co-Cr-Mo 합금에 비하여, 상대재인 초고분자량 폴리에틸렌의 마모량을 약 20% 감소시키는 것을 알 수 있었다. 또한, Co-Cr-Mo 합금 소재에 질소 이온주입을 하여 표면을 개질한 후, NbN 박막을 증착한 경우, 마모량이 최대 50%까지 감소하는 것을 확인할 수 있었다.

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인공관절의 수명 향상을 위해 PIII&D (Plasma Immersion Ion Implantation & Deposition) 기술로 제조된 인공관절용 NbN 박막의 마모 특성 평가

  • Park, Won-Ung;Jeon, Jun-Hong;Mun, Seon-U;Choe, Jin-Yeong;Im, Sang-Ho;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.189-189
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    • 2011
  • 인공관절은 노인성 질환이나 자가 면역질환, 신체적인 외상 등으로 인하여 발생하는 관절의 손상 부위를 대체하기 위해 고안된 관절의 인공 대용물이다. 인공 관절 중 인공 고관절의 경우 관절 운동을 하는 라이너(Liner)와 헤드(Head) 부분이 인공관절의 수명을 결정하게 되는데, 헤드 부분에 메탈소재와 라이너 부분에 고분자 소재를 사용하는 MOP (metal on polymer) 구조의 인공관절은 충격흡수의 장점이 있는 반면 wear debris에 의한 골용해로 인하여 관절이 느슨해지는 문제점이 발생하여 재 시술의 주요 원인이 되고 있다. 또한 메탈 헤드의 마모로 인한 금속이온의 용출은 세포 독성의 문제를 야기하여 인공관절의 수명을 낮추는 또 하나의 요인이 되고 있다. 따라서 인공관절의 수명을 늘리기 위해 DLC, ZrO, TiN 등의 높은 경도 값을 갖는 박막을 금속 헤드 위에 증착하여 상대재인 인공관절용 고분자 소재의 마모량을 줄이고자 하는 연구가 활발하게 진행 되고 있다. 본 연구에서는 PIII&D (Plasma Immersion Ion Implantation & Deposition)공정을 이용하여 Co-Cr-Mo 합금 소재 niobium nitride (NbN) 박막을 증착하여 상대제인 UHMWPE (ultra high molecular polyethylene)의 마모를 줄이고자 하는 연구를 진행하였다. 마모량을 감소시키기 위하여, 박막 증착전에 질소를 이온주입하는 pre-ion implantation 공정을 도입하였으며, 또한 Co-Cr 합금과 NbN박막 사이의 접착력을 증가시키기 위하여 박막의 증착 초기에 이온주입과 증착을 동시에 수행하는 dynamic ion mixing공정을 수행하였다. NbN 박막의 특성을 평가하기 위해 XRD, XPS, AFM 등의 분석을 수행하였으며, 상대재인 초고분자량 폴리에틸렌의 마모량을 측정하기 위해 Pin-on-disk tester를 이용하여 마모 실험을 진행하였다. 마모 실험 결과, pre-ion implantation 공정을 도입한 경우 현재 상용화 되어있는 Co-Cr 합금에 비하여 마모량을 2배 이상 감소시키는 것을 확인 할 수 있었으며, dynamic ion mixing 공정을 도입한 경우 장시간의 마모 시험에 대한 마모 특성이 향상 되는 것을 확인 할 수 있었다.

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Effects of Observation Network Density Change on Spatial Distribution of Meteorological Variables: Three-Dimensional Meteorological Observation Project in the Yeongdong Region in 2019 (관측망 밀도 변화가 기상변수의 공간분포에 미치는 영향: 2019 강원영동 입체적 공동관측 캠페인)

  • Kim, Hae-Min;Jeong, Jong-Hyeok;Kim, Hyunuk;Park, Chang-Geun;Kim, Baek-Jo;Kim, Seung-Bum
    • Atmosphere
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    • v.30 no.2
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    • pp.169-181
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    • 2020
  • We conducted a study on the impact of observation station density; this was done in order to enable the accurate estimation of spatial meteorological variables. The purpose of this study is to help operate an efficient observation network by examining distributions of temperature, relative humidity, and wind speed in a test area of a three-dimensional meteorological observation project in the Yeongdong region in 2019. For our analysis, we grouped the observation stations as follows: 41 stations (for Step 4), 34 stations (for Step 3), 17 stations (for Step 2), and 10 stations (for Step 1). Grid values were interpolated using the kriging method. We compared the spatial accuracy of the estimated meteorological grid by using station density. The effect of increased observation network density varied and was dependent on meteorological variables and weather conditions. The temperature is sufficient for the current weather observation network (featuring an average distance about 9.30 km between stations), and the relative humidity is sufficient when the average distance between stations is about 5.04 km. However, it is recommended that all observation networks, with an average distance of approximately 4.59 km between stations, be utilized for monitoring wind speed. In addition, this also enables the operation of an effective observation network through the classification of outliers.

Modeling and Simulation for Evaluating the Submarine Detection Capability of ASW Missions for an Anti Submarine Helicopter (잠수함 탐지 효과도 증대를 위한 대잠 헬기 임무 할당 방안 연구)

  • Yu, Chan-Woo;Kim, Jae-Ick;Kim, Cheol-Ho;Jung, Young-Ran;Park, Sung-Woon
    • Journal of the Korea Society for Simulation
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    • v.20 no.2
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    • pp.59-66
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    • 2011
  • In this paper, a method to allocate a submarine search mission to an ASW(Anti-Submarine Warfare) helicopter is proposed. The aim of the proposed method is to increase the submarine detection capability. For this purpose, we modeled the behaviors that the ASW helicopter conduct during the search mission, and the relations between the behaviors are also modeled. To measure quantitatively the effectiveness of ASW search mission, the measure of effectiveness(MOP) is defined. Scenarios are designed to analyze the effectiveness utilizing the ASW mission model. We conducted simulations applying the designed scenarios and some parameters concerned with the friendly ship and the enemy submarine interacting each other in the ASW missions. We analyzed the result of simulation depending on the dipping interval and the pattern of dipping positions in the situation that the helicopter operates for a long time and should resupply several times on the friendly ship. From the analyzed data, we suggested the practical value of ratio between the detectable range of the sonar and the dipping interval to improve the effectiveness of ASW mission.

Review on the Occurrence and Studies of Potato Viral Diseases in Korea (한국에서의 감자 바이러스병 발생과 그 연구에 대한 고찰)

  • Hahm, Young-Il
    • Research in Plant Disease
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    • v.9 no.1
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    • pp.1-9
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    • 2003
  • The occurrence of potato(Sotanum tuberosum) viral diseases caused by Potato virus X(PVX), Potato virus Y (PVY), Potato leafroll virus(PLRV), Potato vims S(PVS), Potato virus M(PVM), Potato virus A(PVA), Potato virus T(PVT), Alfalfa mosic virus(AIMV), Tobacco mosic virus(TMV), Potato mop top virus(PMTV) Tobacco rattle virus(TRV) and Potato spindle tuber viroid(PSTVd), potato witches' broom phytoplasma, have been identified so far in Korea. Major viral diseases such as PVX, PVY and PLRV had been studied more deeply, however, the others are just identified and only partially characterized since the first study on the relation between PVX nucleic acid and virus protein by Kim in 1961. The most studies on potato viral diseases are mainly focused on the problems of seed potato production. The National Alpine Agricultural Experiment Station(NAAES), since it began its activities in 1961, has given special attention to this problem by doing studies to identify, characterize and control potato virus diseases. This effort resulted in the development of new potato virus detection methods as a basis for elaborating new method of control, such as the production of seed potato free of virus and the selection of new virus-resistant transgenic potatoes. The further studies of potato viral diseases required would be fallowings: the continuous monitoring for the occurrence of identified or not identified potato viruses in Korea, the isolation of resistant viral genes, the development of control method for the non-persistently transmitted viruses like PVY, special vectors such as nematode and fungus transmitted viruses, TRV and PMTV and the development of control methods against potato viral diseases by viral cross protection, therapy, transgenic plant, and the use of the agents or molecules, such as virus inhibitors and antiviral proteins, etc., blocking viral replication.

PHOTOCHEMISTRY AND PHOTOBIOLOGY OF PSORALENS

  • Shim, Sang-Chul;Jeon, Young Hee;Kim, DongWon;Han, GyuSeok;Yoo, Dong Jin
    • Journal of Photoscience
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    • v.2 no.1
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    • pp.37-45
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    • 1995
  • INTRODUCTION : Psoralens are planar tricyclic furocoumarins present in numerous plants and fungi found throughout the world.' Naturally occurring and synthesized psoralen derivatives(see Figure 1) are photosensitizers of UVA especially from 320 nm to 400 nm, a range at which cellular nucleic acids and proteins are weakly absorbing if any at all. Because of their skinphotosensitizing properties, these compounds have been used in the photochemotherapy of psoriasis and vitiligo. However, undesirable side effects such as carcinoma development in hairless mice as well as possible liver damage from the use of 8-methoxypsoralen(8-MOP) have been reported. The other photobiological effects include inactivation of DNA viruses, killing and mutagenesis of bacteria, inhibition of tumor transmitting capacity of various cells, and hyperpigmentation on human and guinea pig skin. PUVA(psoralen+UVA) photochemotherapy is in fact thousands of years old, having been used in Egypt and India since B.C. 1200-2000. Photochemotherapy for a common disfiguring disease, vitiligo, was practiced in the ancient world by physicians and herbalists who used boiled extracts of the fruits of certain umbelliferous plants, e.g. Ammi majus Linnaeus in Egypt or the leguminous plants, Psoralea corylifolia L. in India. It was first described by Kuske in 19388 that photosensitization of skin by plants was related to the presence of psoralen. He identified natural psoralens in plants as photosensitizers and isolated bergapten(5methoxypsoralen) from the oil of bergamot. The scientific interest in photosensitizing psoralens, however, has grown considerably after the introduction into clinics of the psoralen photochemotherapy for the treatment of psoriasis and of other skin (abbreviation)

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Mono-granular Compound Fertilizer Acting Slow Release for the Crops Under Vinyl Mulching Cultivation -I. Effect of formulation and granulation on slow release (비닐멀칭작물재배용(作物栽培用) 지효성(遲效性) 전용복비(專用複肥) 개발(開發) -I. 제립(製粒)이 지효성(遲效性)에 미치는 영향(影響))

  • Shin, Jae-Sun;Lim, Dong-Kyu;Seong, Ki-Seog;Kim, Bok-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.2
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    • pp.97-100
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    • 1987
  • Medium grade mongranular compound fertilizers for the crops under vinyl mulching cultivation were formulated using the principal materials of urea, DAP and MOP in combination with various fillers of zeolite, gypsum and treated human waste and granulated with waste liquid of glutamic acid fermentation as binder. The ratios of $N-P_2O_5-K_2O$ of trial products were 12-10-11.5 for red pepper, 8-8-6 for sesame and 4-9-14 for peanut. The rate of dissolution of trial products was comparatively low in water. The product for red pepper had N dissolution rate of 80 percent during 24 hrs. 70 for peanut and 55 for seasame. The optimum dissolution rate has reported to be 50 percent by the standard laboratory dissolution test for 24 hrs. in water. Therefore, the slowly released characteristics were obtained with the products that had 24 hrs. dissolution of 70 to 60 percent. One time basal application of trial products could readily be justified under muching cultivation.

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Radiometric examination of fertilizers and assessment of their health hazards, commonly used in Pakistan

  • Hannan Younis;Sumbilah Shafique;Zahida Ehsan;Aleena Ishfaq;Khurram Mehboob;Muhammad Ajaz;Abdullah Hidayat;Wazir Muhammad
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2447-2453
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    • 2023
  • The radioactivity concentrations of Naturally Occurring Radioactive Materials (NORM) i.e., 226Ra, 232Th, and 4K in various chemical fertilizers being used in the agricultural soil of Pakistan were determined utilizing gamma spectrometry by employing a High Purity Germanium (HPGe) detector. The radioactivity concentrations of 226Ra, 232Th, and 4K extended from 2.58 ± 0.8-265.7 ± 8.8 Bq kg-1, 1.53 ± 0.14-76.6 ± 1.07 Bq kg-1 and 36.5 ± 1.34-15606.7 ± 30.2 Bq kg-1 respectively. The radiological hazard parameters such as internal and external indices and annual effective dose rates were calculated, while excessive lifetime cancer risk factors for the indoor and outdoor areas were found in the range from 0.3×10-3 to 10.723×10-3 and 0.03×10-3 to 2.7948×10-3 of most fertilizers, however, some values were slightly higher than the UNSCEAR (The United Nations Scientific Committee on the Effects of Atomic Radiation) recommended values for potash-containing fertilizers such as MOP (Muriate of Potash).

Analysis of Q Values on the Crust of the Kimcheon and Mokpo Regions, South Korea (남한 김천.목포 일대 지각의 Q 값 분석)

  • Do, Ji-Young;Lee, Yoon-Joong;Kyung, Jai-Bok
    • Journal of the Korean earth science society
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    • v.27 no.4
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    • pp.475-485
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    • 2006
  • The physical properties of the central and southwestern crust of South Korea were estimated by comparing values of ${Q_P}^{-1}\;and\;{Q_S}^{-1}$ in the Kimcheon and Mokpo areas. In order to get ${Q_P}^{-1}\;and\;{Q_S}^{-1}$ values, seismic data were collected from two stations of the KIGAM network (KMC and MUN) and four stations of the KMA network (CPN, KUC, MOP, and WAN). An extended coda-normalization method was applied to these data. Estimates of ${Q_P}^{-1}\;and\;{Q_S}^{-1}$ show variations depending on frequency. As frequencies vary from 3 Hz to 24 Hz, the estimates decrease from $(1.4{\pm}3.9){\times}10^{-3}\;to\;(2.3{\pm}3.5){\times}10^{-4}\;for\;{Q_P}^{-1}\;and\;(1.8{\pm}1.3){\times}10^{-3}\;to\;(1.9{\pm}1.5){\times}10^{-4}\;for\;{Q_S}^{-1}$ in central South Korea, and $(5.9{\pm}4.8){\times}10^{-3}\;to\;(2.2{\pm}3.8){\times}10^{-4}\;for\;{Q_P}^{-1}\;and\;(0.5{\pm}2.8){\times}10^{-3}\;to\;(1.8{\pm}1.6){\times}10^{-4}\;for\;{Q_S}^{-1}$ in southwestern South Korea. According that a frequency-dependent power law is applied to the data, the best fits of ${Q_P}^{-1}\;and\;{Q_S}^{-1}\;are\;0.003f^{-0.49}\;and\;0.005f^{-1.03}$ in central South Korea, and $0.026f^{-1.47}$ and $0.001f^{-0.49}$ in southwestern South Korea, respectively. These values almost correspond to those of seismically stable regions although ${Q_P}^{-1}$ values of southwestern South Korea are a little high due to lack of data used.

Antioxidant Activity of the Oven-dried Paprika Powders with Various Colors and Phycochemical Properties and Antioxidant Activity of Pork Patty Containing Various Paprika Powder (파프리카의 색이 열풍 건조한 파프리카 분말을 첨가한 돈육 분쇄육의 이화학적 특성과 항산화 활성 평가)

  • Shim, Yong Woo;Chin, Koo Bok
    • Food Science of Animal Resources
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    • v.33 no.5
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    • pp.626-632
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    • 2013
  • This study was performed to determine the antioxidant activity of the oven-dried paprika powder as affected by the color differences of paprika and to evaluate physicochemical characteristics and antioxidant activity of pork patties with various levels of paprika powders. The total phenolic contents of the paprika were not affected by color and solvent (p>0.05). The methanol extracted paprika powder showed higher DPPH radical scavenging activity than water extracted counterpart, and no differences were observed at concentration of 0.5% as compared to the reference (ascorbic acid) (p>0.05). In all treatments, the iron chelating ability increased with increasing concentrations. At a concentration of 1.0%, methanol extracts of orange paprika (MOP) and water extracts of red paprika (WRP) were not different from the reference, (ethylendiaminetetraacetic acid, EDTA). The paprika color and extraction solvent didn't affect reducing power of paprika powder at each concentration (p>0.05). Pork patties with red paprika powder were higher redness values than those with orange ones, regardless of addition level. The addition of red paprika increased the yellowness, and patties with 1.0% orange paprika powder showed the highest value. TBARS values were decreased with increasing paprika powder, especially, patties with 1.0% paprika powder were lower TBARS than those with 0.5% paprika powder, resulting in similar to those with ascorbic acid (p>0.05). Although the microbial counts increased with storage time, paprika powders did not inhibit microorganisms during storage. In conclusion, paprika powders could be used as a natural antioxidant in meat products, regardless of paprika color.