• Title/Summary/Keyword: MMA 수지

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Hardening State and Basic Properties Changes According to the Mixture Ratio of MMA Resin Used as a Waterproofing Coating Material in Concrete Bridges (콘크리트 교면용 도막방수재로 사용되는 MMA 수지의 배합비율에 따른 경화상태 및 기본 물성에 관한 연구)

  • An, Ki-Won;Kang, Hyo-Jin;Oh, Sang-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.224-234
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    • 2019
  • Waterproof layers are installed in civil engineering structures and bridge construction is commonly finished by applying a layer of regular or asphalt concrete above the waterproof layer. However, asphalt materials are susceptible to melting at high temperature due to its superior temperature sensitivity, and this causes the waterproofing material to melt due to the high temperature of the asphalt concrete, thereby increasing the defect occurrence rate due to the thickness reduction. In this study, tensile strength and elongation of hard and soft type of MMA(Methyl Methacrylate) applied to bridges were compared in accordance to standard performance criteria based on different mixture ratios. Results of comparative testing showed that hard MMA resin can display a satisfactory tensile strength, and soft MMA resin displays satisfactory elongation properties, but as the two resin types are separately used, neither types are able to satisfy the standard requirements outlined in KS F 4932. When the amount of the powder exceeds 56.25% of the total amount, voids are generated on the surface after curing and self leveling was impossible and a heterogeneous surface is formed. Furthermore, when the hard resin: soft resin: powder mixture ratio was set to 15g: 85g: 150g. the tensile strength was $1.5N/mm^2$ and the elongation percentage was 133% which satisfy the tensile performance of KS F 4932.

Low Temperature Harding Property of UP with MMA Proportions (MMA 모노머 혼입률에 따른 UP의 저온경화 특성)

  • Song, Hun;Lee, Jung-Hui;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.497-498
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    • 2009
  • Unsaturated polyester(UP) and epoxy resin require 8${\sim}$11 hours long harding times and heating systems used by reinforcement liner. This study is to evaluate the effects of low temperature harding property of UP with methyl methacrylate(MMA) monomer mixing proportions.

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Hardening properties in MMA monomer using UP and EPS in addition hardener (경화제의 첨가에 따른 UP와 EPS 혼입 MMA 수지의 경화특성)

  • Lee, Jung-Hui;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.445-448
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    • 2008
  • The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) and UP in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS and UP contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

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Hardening properties of MMA Monomer Using EPS in addition of Initiator and Promoter (개시제 및 촉진제의 첨가에 따른 EPS 혼입 MMA 수지의 경화특성)

  • Lee, Jung-Hui;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.929-932
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    • 2008
  • The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

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Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Redispersible Polymer Powder with Nitrite-Type Hydrocalumite (재유화형 분말수지와 아질산형 하이드로칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Wan-Ki;Hong, Sun-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.3
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    • pp.275-283
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    • 2012
  • Nitrite-type hydrocalumite (calumite) is a material that can adsorb the chloride ions ($Cl^-$)that cause the corrosion of reinforcing bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. In this study, VA/E/MMA-modified mortars with calumite were prepared with various calumite contents and polymer binder-ratios, and tested for corrosion inhibition, chloride ion penetration, carbonation and drying shrinkage. As a result, regardless of polymer-binder ratio, the replacement of ordinary Portland cement with hydrocalumite has a marked effect on the corrosion inhibiting property of the polymer-modified mortars. However, chloride ion penetration and carbonation depths are somewhat increased with higher calumite content, but can be remarkably decreased depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to increase with the polymer-binder ratio and calumite content. VA/E/MMA-Modified mortars with 10 % calumite did not satisfy KS requirements. Accordingly, a calumite content of 5 % is recommended for the VA/E/MMA-modified mortars with calumite.

A Study on the Compatibility of PMMA-Poly(butadiene-g-MMA) Blends (PMMA와 Poly(butadiene-g-MMA) 블렌드의 상용성에 관한 연구)

  • Park, Sung-Ick;Han, Seung;Suh, Kyung-Do;Mun, Tak-Jin
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.182-188
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    • 1994
  • Poly(butadiene-g-MMA) was synthesized by grafting methyl metharcylate on polybutadiene which is intrinsically incompatible with poly(mothy methacrylate)(PMMA) and this graft copolymer was blended with PMMA. Mechanical properties of PMMA-poly(butadiene-g-MMA) blends and PMMA-polybutadiene blends, such as impact strength, tensile strength and haze were determined. Morphological changes of the blends as a function of graft percentage were observed by scanning electron microscopy. Mechanical properties of PMMA-poly(butadiene-g-MMA) blends were better than PMMA-polybutndiene blends. Especially, mechanical properties of PMMA-poly(butadiene-g-MMA) blends were improved nth increasing graft percentage of MMA.

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A Basic Study on the Self-Corrosion Inhibition Function Identification of VA/E/MMA-Modified Mortar with Nitrite-Type Hydrocalumite (칼루마이트 및 VA/E/MMA 분말수지 병용 PMM의 자기방청기능 규명을 위한 기초적 연구)

  • Hong, Sun-Hee;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.253-254
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    • 2011
  • The purpose of this study is to investigate chloride ion adsoption property of cement mortar using nitrite type hydrocalumite(calumite) with self-corrosion inhibition function. Superior corrosion inhibition function of the VA/E/MMA-modified mortars with calumite was ascertained from accelerated corrosion test in the previous study. In this study, VA/E/MMA-modified mortars with calumite were prepared with calumite contents of 0, 5, 10% and polymer-binder ratio of 0, 10%, and tested for chloride ion adsorption to make it clear how calumite gives self-corrosion inhibition function to cement mortar. As a result, chloride ion adsorption property of VA/E/MMA-modified mortars with calumite was improved by increasing calumite contents compared to unmodified mortar regardless of using VA/E/MMA terpolymer powder or not.

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Durability of VA/E/MMA-Modified Mortars with Nitrite-Type Hydrocalumite (VA/E/MMA 터폴리머 분말수지와 아질산형 hydrocalumite를 병용한 폴리머 시멘트 모르타르의 내구성)

  • Hong, Sun-Hee;Lee, Jae-Hwa;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.41-42
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    • 2011
  • In this study, VA/E/MMA-modified mortars with nitrite-type hydrocalumite were prepared with various calumite contents and polymer binder-ratios, and tested for chloride ion penetration, carbonation and drying shrinkage. As a result, the chloride ion penetration and carbonation depths were somewhat increased with calumite contents, but those were remarkably decreased depending on the polymer-binder ratios. The 28-d drying shrinkage showed a tendency to increase with polymer-binder ratios and calumite contents. VA/E/MMA-Modified mortars with a calumite of 10 % were dissatisfied with KS requirements. Accordingly, a calumite content of 5 % for the VA/E/MMA-modified mortars with calumite is recommended.

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Characterization of Porous Asphalt Concrete Coated with MMA Resin (아크릴 수지로 코팅한 배수성 아스팔트 콘크리트의 특성 평가)

  • Choi, Tae-Jun;Lee, Hyun-Jong;Kim, Tae-Woo;Song, Jae-Hyok
    • International Journal of Highway Engineering
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    • v.11 no.2
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    • pp.111-120
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    • 2009
  • This paper presents a fundamental findings of the functional and structural performance of the porous asphalt concrete coated with MMA resin. To evaluate the structural performance, cantabro, wheel tracking, moisture sensitivity and indirect tensile fatigue tests are performed. The tests results show that the cantabro loss is reduced three times and fatigue resistance is significantly increased after the specimens are coated with MMA resin. However there are little changes in the rutting and moisture damage resistances before and after the coating. Air voids, permeability and BPT(British Pendulum Test) tests are conducted to study the functional performance. It is observed form the tests that the air voids and permeability are slightly decreased after the coating. However, the changes in the air voids and permeability are negligible. The skid resistance of the coated specimens is lower than reference specimens. However, the skid resistance is maintained beyond the level of the reference specimens when silica sands are chipped on top of the coated surface.

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Study on the Preparation and Properties of Polyurethane-Acryl Emulsion Resin (폴리우레탄-아크릴 에멀젼 수지 제조 및 물성에 관한 연구)

  • Kim, Hong-Tae;Lee, Myung-Cheon
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.39-44
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    • 2005
  • In this study, polyurethane-acryl emulsion resins were synthesized from HDI (hexamethylene diisocyanate), IPDI (isophorone diisocyanate), Polyol, 2-HEMA (2-hydroxy ethylmethacrylate), n-BA (n-butyl acrylate) and MMA (methylmethacrylate). The effects of polyol types on the properties of polyurethane-acryl emulsion resin, such as degree of strength and water resistance and on the manufacturing process were investigated. In addition, the results were compared with those of acrylic emulsion. The test results showed that polyester type polyol demonstrated stronger tensile strength and higher water resistance with time than did acrylic emulsion and polyether type polyol.