• Transactions on Electrical and Electronic Materials
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• 제5권1호
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• pp.29-33
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• 2004

The materials showing high structure dispersity have been developed on the quartz base by mechano-chemical technology. Depending on the processing conditions and subsequent applications, the materials produced by mechano-chemical reaction (MCR) showed concurrently magnetic, dielectric and electrical properties. The obtained magnetic-electrical powders classified by aggregate complex of their features as segneto-magnetics, contained a dielectric material as a carrying nucleus, particularly the quartz on that surface one or more layers of different compounds was synthesized having thickness up to 10∼50 nm and showing magnetic properties and etc.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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• pp.1241-1244
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• 2003

The materials showing high structure dispersity are developed on the natural quartz base and they are obtained by mechano-chemical technology. Depending on the processing conditions and subsequent applications the materials produced by mechano-chemical reaction (MCR) show concurrently magnetic, dielectric and electrical properties. The obtained magnetic-electrical powders classified by aggregate complex of their features as segnetomagnetics, contain a dielectric material as a carrying nucleus, particularly the quartz on that surface one or more layers of different compounds are synthesized having thickness up to $10{\sim}50nm$ and showing magnetic, electrical and other properties.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.666-669
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• 2002

The differences of the effects of mechanical substance pre-activation in the mills with divers force effect schemes on the self-propagating high temperature synthesis (SHS) of the $SiO_2$ + 37.5% Al system were investigated. The power saturation of activated material state are estimated referring on the variations of dilatometry curve paths. The effects of activation time on the temperature of sample self-ignited in the furnace, combustion temperature and completeness of the quartz reaction with aluminium were determined. The enhancing effects of organic modifiers of quartz particle surfaces on the further SHS synthesis development were shown.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
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• pp.113-116
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• 2004

The materials showing high structure dispersion with functional properties were developed on the quartz base and those were obtained by mechano-chemical reaction technology. Depending on the processing conditions and subsequent applications the materials produced by mechano-chemical reaction show concurrently magnetic, dielectric and electrical properties. The obtained magnetic-electrical powders classified by aggregate complex of their features as segnetomagnetics, containing a dielectric material as a carrying nucleus, particularly the quartz on that surface one or more layers of different compounds were synthesized having thickness up to 10~50 nm showing magnetic, electrical properties and others. The similarity of the structure of surface layers of quartz particles subjected to mechano-chemical processing and nano-structure cluspol (clusters in a polymer matrics) material was also confirmed by the fact that the characteristics of ferromagnetic quartz of insulating nano-composite powder were changed with time, after its preparing process was completed. The magnetic permeability of the sample was decreasing within first two months down by 15~20 %. Then, the magnetic characteristics were almost stabilized steadily and continuously. The observed changes were related with defective structure of the particles, elastic stress relief, and changes of electron density and magnetic moment in deformation zones. This process of stabilization of the investigated properties could be intensified by the thermal annealing heat treatment in short time period of the nano-composite quartz powders at the temperature ranges of 100~15$0^{\circ}C$.

• 동굴
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• 제63호
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• pp.1-8
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• 2004

비자성이며 비전도성의 물리적 성질을 갖는 자연산 퀄쯔(quartz)와 제주도 삼방산 근처에서 채취한 화산 용암석 스코리아를 대상으로 자성화(magnetization) 처리를 하여 특성을 분석하였다. 마그네타이징(magnetizing) 처리를 위하여 강력한 기계화학적 분쇄 반응을 시켰으며, 분쇄 반응시 알코올계의 솔벤트를 반응용매로 사용하였다. 퀼쯔와 스코리아의 마그네타이징 처리에서 비중이 작은 스코리아와 비교적 비중이 큰 퀼쯔의 경우에서도 분쇄반응 후 분말이 수면 위에 떠있는 부유특성이 있음을 확인하였고, 친유성(oleophilic)으로 기름에 대한 흡착성이 우수함을 확인하였다. 실험과정에서 자연산 퀼쯔와 함께 스코리아를 바탕물질로 기계-화학적 반응(MCR) 기술로 고 분산성 흡착 반응에 의한 고분자 물질을 생성, 유도하여 퀼쯔-나노복합체(quartz nanocomposite)를 제조하였다. 부착성 융합복합물질의 특징으로부터 시그니토마그네틱스(Segnetomagnetics)로 분류되는 합성분말은 특히 유류성분에 대하여 높은 흡착성을 가지며, 강한 자기적 성질을 띄는 10～50 nm두께의 하나 또는 그 이상의 이질적 융합화합물 층이 석영이나 수정체의 표면에 형성되어 특유의 자기적, 전기적 성질을 나타냄이 확인되었다. 따라서 퀼쯔에 비하여 제주도를 비롯한 화산지역에 널리 분포되어있는 양질의 저렴한 화산암재 스코리아를 활용하여 자성화 양산체제를 갖춘다면, 최근에 빈발하고 있는 해양 선박사고를 비롯하여 내수면 선박사고 등으로 수면 상에 유출된 회수곤란성 저밀도 유류물질을 연속적으로 흡착, 제거할 수 있는 흡유성자기유류 회수용 기능성 재료로의 응용개발 가능성과 함께 유용한 산업용 기능성 신소재로의 활용성에서 환경복원용신기능성 신소재, 국민보건 향상과 건강산업 육성발전을 위한 건강용품 개발 및 목재 등의 식물성 유기재료의 자성화 처리를 위한 응용기술로의 활용가능성면에서도 기대되는 바가 크다.