• Title/Summary/Keyword: MBT

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Spectrophotometric Determination of Trace Hg(II) in Cetyltrimethylammonium Bromide Media

  • Jeoung, Moon-Sook;Choi, Hee-Seon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.12
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    • pp.1877-1880
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    • 2004
  • The simple and convenient determination of trace Hg(II) with its 2-mercaptobenzothiazole (MBT) complex in cetyltrimethylammonium bromide (CTAB) media has been studied. The UV-visible spectrum of Hg(II)-MBT complex in CTAB media had a good sensitivity and reproducibility. The Hg(II)-MBT complex in CTAB solution was very stable at pH 10.0 and could be quantitatively complexed if MBT were added to the sample solution more than 10 equivalent of Hg(II). The optimum concentration of CTAB was 0.001%. The calibration curve of Hg(II)-MBT complex with good linearity ($R^2$ = 0.9985) was obtained at the concentration range between $1.0{\times}10^-7$ and $1.0{\times}10^-5$ M in 0.001% CTAB media. The detection limit was $3.1{\times}10^-8$ M (6.2 ng m$L^{-1}$). Hg(II) in the synthetic samples and in the wastewater of the university's wastewater tank and the industrial wastewater tank could also be determined. Based on the experimental results, this proposed technique could be applied to the simple and convenient determination of trace Hg(II) in real samples.

A Study on the Application of Indolene -MPHA for Automotive Alternative Fuel (II) - (자동차 대체연료로서의 Indolene-MPHA의 적용에 관한 연구(II) - Indolene-MPHA가 엔진성능에 미치는 영향 -)

  • 이민호;오율권;차경옥
    • Journal of Energy Engineering
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    • v.12 no.3
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    • pp.190-196
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    • 2003
  • A study of the performance effect of Indolene-Methanol Plus High Alcolhols (MPHA) has been completed. The study invested the measurement of performance parameters. The performance parameters measured are minimum advance for best torque (MBT) spark timing, power output and thermal efficiency. The alcohol concentration was varied from 0 to 100 percent by volume in clear Indolene. The performance parameters were measured using a single cylinder spark ignition engine at different compression ratios. The results of the performance measurements indicated that Indolene-MPHA blends have a higher MBT spark advance, similar power output and lower thermal efficiencies than Indolene-Methanol blends.

새로운 가황계(加黃系)(OTOS/MBT)

  • Park, Yeong-Nam
    • Elastomers and Composites
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    • v.15 no.2
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    • pp.107-115
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    • 1980
  • 동자료(同資料)에서는 OTOS/MBT 촉진계(促進系)와 벤조티아졸 술펜아미드 촉진계(促進系)와를 4가지 응용면(應用面)에서 비교(比較)하였는 바, 이들은 승용차용(乘用車用) 타이어트레드, heavy duty용(用) 타이어트레드, 고온(高溫)에서 사용(使用)되는 콘베어벨트의 카버고무(저함유(低含有) 황(黃)) 및 off-the-road용(用) 트레드(저(低) 함유(含有) 황(黃)) 등이다. OTOS/MBT촉진계(促進系)의 사용비율(使用比率)은 1 : 1에서 2 : 1 까지이다. 물성(物性)의 균형(均衡)이 중요(重要)하므로 각(各) 용도별(用途別)로, 독립적(獨立的)으로 분리(分離)하여 비교(比較)하였다. 그 결과(結果) OTOS/MBT로 구성(構成)된 촉진계(促進系)를 이용(利用)한 가황체(加黃體)가 효과면(效果面)에서 여러가지 장점(長點)을 시현(示顯)하였다. 즉(卽) 저렴(低廉)한 가격(價格)의 촉진계(促進系), 스코오치 안전성(安定性), 황(黃) 활용도(活用度) 및 안정(安定)한 강상구조(綱狀構造) 등(等)이다.

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Effects of Stabilizing Additives on Electroless Copper Deposition (무전해 동 도금용액 속에서 안정제의 역할)

  • 최순돈;박범동
    • Journal of the Korean institute of surface engineering
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    • v.25 no.4
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    • pp.173-180
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    • 1992
  • The effects of the stabilizing additives such as NaCN, 2-MBT and Thiourea on bath decom-position, plating rate and surface morphology have been studied. Bath stability was increased in the order of an additive-free bath, and NaCN-, 2-MBT-, and Thiourea-stabilized baths. The sta-bilizing effects may be attributed to the stability of Cu(II) -complexes. The plating rate is the re-verse order of the bath stability. Accelerative effect of 2-MBT in proper quantity(0.3mg/$\ell$) may be explained by visualizing it absorbed through benzene ring or sulfur atom on portions of the sub-strates. The strong bond of the complexing part of the molecule to nearby chelated copper ions would tend to accelerate plating by making it easier for the Cu2+ -ligand bond to be broken. Sur-face morphologies of copper deposits depend on the bath additives. Electroless copper deposits from the 2-MBT stabilized baths are finer than the deposits from the NaCN- and Thiourea- stabi-lized baths due to the strong adsorption on the substrates.

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Butyltin Compounds Concentrations in Masan Bay

  • CHOI Hee Gu;KIM Pyoung Joong;LEE Won Chan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.6
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    • pp.923-928
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    • 1997
  • The occurrence of butyltin compounds in the seawater and sediment of Masan Bay was investigated. The concentrations were in the range of $ND-0.059{\mu}g/\ell$ for tributyltin (TBT), $ND-0.091{\mu}g/\ell$ for dibutyltin (DBT) and $ND-0.720{\mu}g/\ell$ for monobutyltin (MBT) in the seawater, and $ND-0.233{\mu}g\;TBT/g.dry$, $ND-0.197{\mu}g-DBT/g.dry$ and $ND-0.684{\mu}g-MBT/g.dry$ in the sediment. Among the butyltin compounds, the major component in the seawater was MBT, while the predominant species in the sediment changed with time. The tributyltin concentrations in the sediment are approximately three orders of magnitude greater than the associated water column levels. Sediment/water partition coefficients (K) of TBT were between $0.6\times10^3\;and\;5.0\times10^3$.

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KINETICS AND MECHANISM OF THE REACTION OF 2-MERCAPTOBENZOTHIAZOLE WITH N-(CYCLOHEXYLTHIO) PHTHALIMIDE AND RELATED COMPOUNDS

  • Son, P.N.;Andrews, K.E.;Schooley, A.T.
    • Elastomers and Composites
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    • v.13 no.3
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    • pp.197-206
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    • 1978
  • 반응속도면(反應速度面)에서의 동력학적(動力學的) 연구결과(硏究結果)에 의(依)하면 2-메르캅토벤쪼티아졸(MBT)은 N-t-부틸-벤쪼티아졸썰펜아미드(BBTS) 또는 2-(4-몰폴리노티오) 벤쪼티아졸(OBTS)과 같은 가황촉진제(加黃促進劑)들 보다는 N-(싸이클로헥실티오)프탈이미드(CPT)가 훨신 더 빨리 반응(反應)한다는 사실(事實)을 탐지(探知)하였다. 또한 우수(優秀)한 가황지연제(加黃遲延劑)는 MBT와 급속(急速)히 반응(反應)하여야 하지마는 실소(室素)와 황(黃)과의 화학결합(化學結合)이 너무 약(弱)하여 내열안정성(耐熱安定性)이 없음으로 아무리 MBT와 빠른 속도(速度)로 반응(反應)하여도 좋은 가황(加黃)지연제가 될 수는 없다. 예를들면 N-(싸이클로헥실티오-O-벤쪼의 썰펜이미드(CTBS))는 CTP보다 더 빨리 MBT와 반응(反應)하지만 열안정성(熱安定性)이 부족(不足)하여 가황(加黃)지연제로서는 CTB 보다 좋지 못하다.

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TCP Buffer Tuning based on MBT for High-Speed Transmissions in Wireless LAN (무선 랜 고속전송을 위한 최대버퍼한계 기반 TCP 버퍼튜닝)

  • Mun, Sung-Gon;Lee, Hong-Seok;Choo, Hyun-Seung;Kong, Won-Young
    • Journal of Internet Computing and Services
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    • v.8 no.1
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    • pp.15-23
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    • 2007
  • Wireless LAN (IEEE 802.11) uses traditional TCP for reliable data transmission, But it brings the unintentional packet loss which is not congestion loss caused by handoff, interference, and fading in wireless LAN. In wireless LAN, TCP experiences performance degradation because it consumes that the cause of packet loss is congestion, and it decrease the sending rate by activating congestion control algorithm. This paper analyzes that correlation of throughput and buffer size for wireless buffer tuning. We find MBT (Maximum Buffer Threshold) which does not increase the throughput through the analysis, For calculation of MBT, we experiment the throughput by using high volume music data which is creased by real-time performance of piano. The experiment results is shown that buffer tuing based on MBT shows 20.3%, 21.4%, and 45.4% throughput improvement under 5ms RTT, 10ms RTT, and 20ms RTT, respectively, comparing with the throughput of operation system default buffer size, In addition, we describe that The setting of TCP buffer size by exceeding MBT does not have an effect on the performance of TCP.

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Growth Inhibitions of Strains Exhibiting Resistances against General Disinfectants and Antibiotics by MBT-01108 Material. (MBT-01108 물질에 의한 일반 소독제 및 항생물질 내성균주의 생육억제)

  • Kim, Hae-Nam;Park, Jin-Young;Kim, Sam-Woong;Jun, Hong-Ki
    • Journal of Life Science
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    • v.17 no.9 s.89
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    • pp.1278-1283
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    • 2007
  • The 30% resistant frequencies of pathogenic bacteria were identified against generally utilizing disinfectants. Among the used disinfectants, foodsef, Taego, and Iodo 175 were dictated by lower sensitivities against pathogenic bacteria, as well as higher resistant frequencies when compared with other disinfectants. The resistant frequencies against antibiotics were also dictated by 30% through MIC (minimal inhibitory concentration) and paper disc methods. Especially, the used bacteria exhibited resistances against gentamycin, kanamycin, and streptomycin, which included in all aminoglycoside group. The MBT-01108 material, which extracted and purified from a powder obtained by processing of Opunita ficus-indica var. saboten Makino trunk, did not develop or grow resistant bacteria. Interestingly, the multi-drug resistant bacteria such as MRSA, resistant Pseudomonas aeruginosa, VRE, and E. coli 0157 did not resistant against MBT-01108 material. These results suggest that MBT-01108 material uses as an anti-microbial agent.

Comparative Analysis Between MBT Shoes(Functional walking shoes) and General Sporting Shoes for the Muscle Activity and Energy Consumption (보행용 MBT신발과 일반 신발 보행 시 에너지 소비량과 근 활성도의 비교 분석)

  • Yoon, Bum-Chul;Kang, Se-Yong;Kim, Yae-Jung;Yu, Min-Ho;Lee, Mi-Jung;Kim, Nan-Soo
    • Journal of Korean Physical Therapy Science
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    • v.13 no.3
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    • pp.65-75
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    • 2006
  • This study was to find out whether MBT shoes were more effective than general sporting shoes on the kinematic physiology. We comparatively analyzed energy consumption, heart rates, rating of perceived exertion, lactic acid density in blood and muscle activity with EMG. The subjects were 10 regular students of K Univ.(5 male and 5 female). They wore the general sporting shoes for stage 1(group 1), the MBT walking shoes for stage 2(group2) under the same conditions. There was one week interval between stages. 1. There was no significant difference in the energy consumption and the heart rates between two groups. Group 1 showed a higher energy consumption and heart rates than Group 2 under the speed of 4.0 mph. On the other hand, Group 2 showed higher ones over the speed of 4.0 mph. 2. There was no significant difference in the rating of perceived exertion and lactic acid density in blood between two groups. But Group 2 showed a lower fatigue strength than Group 1. 3. Group 2 showed a higher muscle activity with EMG than group 1, especially at the speed of 2.0, 2.5, 3.0, 3.5 mph in quadratus lumborum muscle and at 4.0mph in tibialis anterior muscle. In conclusion, we are less tired in MBT shoes than in general sporting shoes. Also, we can dorsiflex better in the ankle joint, straighten the lumbar region well and walk erect in MBT shoes. Specially, when it walks slowly, it is favorable in an erection walk and when it walks quickly, we have advantage of obesity management.

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Evaluation of Resource Recovery from Sorted Waste by MBT System (MBT시스템에 의해 선별(選別)된 생활폐기물(生活廢棄物)의 자원화(資源化) 평가(評價)에 관(關)한 연구(硏究))

  • Lee, Byung-Sun;Han, Sang-Kuk;Lee, Nam-Hoon;Kang, Jeong-Hee;Wie, June
    • Resources Recycling
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    • v.22 no.5
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    • pp.20-28
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    • 2013
  • This study was carried out to evaluate the possibility of resource recovery for municipal solid waste(MSW) that sorted by a MBT system. First, physical property of MSW was similar to wastes carried into Sudokown landfill site. However, moisture of MSW was little higher than that. As a result of BMP test using organic fraction of MSW(OFMSWs), approximately 60 ~ 80 mL $CH_4/g$-VS of methane was occurred. Compared to the other studies, the value of methane is lower. It seems to be caused that high ratio of vinyl/plastic in OFMSWs. The other BMP test using sample of MBT system located in Sudokwon landfill was conducted each physical properties. According to the result of experiment, food waste makes 193 mL $CH_4/g$-VS, and paper is 102 mL $CH_4/g$-VS. However, there was not methane production in vinyl and rubber. Additionally, others that can't sort no more show 30 m $CH_4L/g$-VS of methane production. From the result of experimental data OFMSWs has high fraction of vinyl, rubber and other substance that difficult for biodegradation. Therefore it is need to sort of them.