• Title/Summary/Keyword: M2P

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A Study on the Preparation of Halogen Free M-P Flame Retardant and Its Application to Composite Material (비할로겐 M-P 난연제 제조 및 복합재료 응용 연구)

  • Lee, Soon-Hong
    • Journal of the Korean Society of Safety
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    • v.24 no.6
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    • pp.63-71
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    • 2009
  • In order to improve flame retardancy, the halogen free organic melamine phosphate(M-P) flame retardant was synthesized from melamine and phosphoric acid by the reaction of precipitation. The ignition test was carried out preparing hybrid flame retardant compound($H_bFRC$) consisting of organic M-P and inorganic Mg$(OH)_2$ as a flame retardant in the polyolefin resins. The flame retardancy and mechanical properties of flame retardant aluminum composite panel($H_bFRC$-ACP) were performed to investigate the possibility of the composite material, which was contained M-P, as a inner core for $H_bFRC$-ACP. For this study, the results of ignition test indicate that a char formation and drip suppressing effect, and combustion time reduced as the content of M-P increased. The limited oxygen index(LOI) values were measured 17.4vol% and 31.5vol% for LDPE only and $H_bFRC$-3(M-P content: 15wt%), respectively. And it was verified that the $H_bFRC$-3 was needed more oxygen quantity with the increase of M-P content when it combustion. Also, the results from thermogravimetric analysis were observed endothermic peak at $350^{\circ}C$ and $550^{\circ}C$, it was confirmed predominant thermal stability though the wide temperature range by the mixture of M-P and Mg$(OH)_2$. The LDPE-ACP (using only LDPE as a inner core), $35.13kW/m^2$ of heat release rate(HRR) and 13.43MJ/m2 of total heat release(THR) were measured while the $H_bFRC$-ACP, $10.44kW/m^2$ of HRR and 1.84MJ/m2 of THR were measured by results of cone calorimeter test. In case of $H_bFRC$-ACP, the average gas emission amount of CO and $CO_2$ could be decreased down to 25% and 20%, respectively, in comparison with LDPE-ACP. The mechanical properties such as tensile strength, bending strength and adhesion strength of $H_bFRC$-ACP were revealed slightly high values $54N/mm^2$, $152N/mm^2$ and 120N/25mm, respectively, compared with LDPE-ACP. It was confirmed that flame retardancy was improved with the synergy effect because of char formation by M-P and hydrolysis by Mg$(OH)_2$. The result of this study suggest that $H_bFRC$ can be applied for an adequate halogen free flame retardant composite material as a inner core for ACP.

POSITIVE SOLUTIONS FOR MULTIPOINT BOUNDARY VALUE PROBLEMS WITH ONE-DIMENSIONAL p-LAPLACIAN OPERATOR

  • Xu, Fuyi;Meng, Zhaowei;Zhao, Wenling
    • Journal of applied mathematics & informatics
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    • v.26 no.3_4
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    • pp.457-469
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    • 2008
  • In this paper, we study the existence of positive solutions for the following nonlinear m-point boundary value problem with p-Laplacian: $\{{{{(\phi_p(u'))'\;+\;f(t,u(t))=0, \;0<t<1,} \atop u'(0)={\sum}{^{m-2}_{i=1}}\;a_iu'(\xi_i),} \atop u(1)={\sum}{^k_{i=1}}\;b_iu(\xi_i)\;-\;{\sum}{^s_{i=k+1}}\;b_iu(\xi_i)\;-\;{\sum}{^{m-2}_{i=s+1}}\;b_iu'(xi_i),}$ where ${\phi}_p(s)$ is p-Laplacian operator, i.e., ${\phi}_p(s)=\mid s\mid^{p-2}s$, p>1, ${\phi}_q\;=\;({\phi}_p)^{-1}$, $\frac{1}{p}+\frac{1}{q}=1$, $1\;{\leq}\;k\;{\leq}\;s\;{\leq}m\;-\;2$, $b_i\;{\in}\;(0,+{\infty})$ with $0\;<\;{\sum}{^k_{k=1}}\;b_i\;-\;{\sum}{^s_{i=k+1}}\;b_i\;<\;1$, $0\;<\;{\sum}{^{m-2}_{i=1}}\la_i\;<\;1$, $0\;<\;{\xi}_1\;<\;{\xi}_2\;<\;{\cdots}\;<\;{\xi}_{m-2}\;<\;1$, $f\;{\in}\;C([0,\;1]\;{\times}\;[0,\;+{\infty}),\;[0,\;+{\infty}))$. We show that there exists one or two positive solutions by using fixed-point theorem for operator on a cone. The conclusions in this paper essentially extend and improve the known results.

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Computation of Tides in the Northeast Asian Sea by Blending the Topex/Poseidon Altimeter Data (Topex/Poseidon 고도계 자료를 이용한 북동 아시아 해역의 조석 산정)

  • Kim, Chang-Shik;Matsumoto, Koji;Ooe, Masatsugu;Lee, Jong-Chan
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.1
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    • pp.1-12
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    • 2001
  • Tidal computations of $M_2,\;S_2,\; K_1$ and $O_1$ constituents in the northeast Asian sea are presented by blending the Topex/Poseidon (T/P) altimeter data into a hydrodynamic model with $5'{\times}5'$ resolution. A series of sensitivity experiments on a weighting factor, which is the control parameter in the blending method, are carried out using $M_2$ constituent. The weighting factor is set to be in inverse proportion to the square root of water depth to reduce noises which could occur in data-assimilative model by blending T/P data. Model results obtained by blending the T/P-derived $M_2,\;S_2,\; K_1$ and $O_1$ constituents simultaneously are compared with all T/P-track tidal data; Average values of amplitude and phase errors are close to zero. Standard deviations of amplitude and phase errors are approximately 2 cm and less than 10 degrees respectively. The data-assimilative model results show a quite good agreement with T/P-derived tidal data, particularly in shallow water region (h<250m). In deep water regions, T/P-derived tidal data show unreasonable spatial variations in amplitude and phase. The data-assimilative model results differ from T/P-derived data, but are improved to show reasonable spatial variations in amplitude and phase. In addition, the T/P-blended model results are in good agreement with coastal tide gauge data which are not blended into the model.

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Characterization of proteases of Toxoplasma gondii (Toxoplasma gondii에서 단백질 분해 효소의 특징)

  • Choe, Won-Yeong;Nam, Ho-U;Yun, Ji-Hye
    • Parasites, Hosts and Diseases
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    • v.27 no.3
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    • pp.161-170
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    • 1989
  • The proteases of Toxoplasma gcndii were purified partially and characterisrd for some biochemical properties including various chromatographic patterns, major catalytic classes, and conditions to promote the activity of these enzymes. When Toxoplasma extract was incubated with 3H-casein at various pH, peak hydrolysis of casein was observed at pH 6.0 and at pH 8.5. Proteasfs working at pH 6.0 and at pH 8.5 were purified partially by conventional methods of chromatographies of DE52 anion rxchange, Sephadex G-200 gel permeation, and hydroxylapatite chromatography. Partially purified enzymes were tested by site-specific inhibitors and promotorf. The protease working at pH 6.0 was inactivated by iodoacetamide with LDso of 10-5 M and promoted by dithiothreitol, while the protease working at pH 8.5 was inhibited by phenylmethylsulfonyl fluoride with LD50 of 10-5 M and was Promoted by ATP (excess ATP beyond 2 mM inhibited the activity reversely). The protease of pH 8.5 had the activity of ATPase which might exert the energy to its action. Therefore the former was referred to as a cysteinyl acid protease and the latter, ATP-dependent neutral serine protease.

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Design of a Parallel Multiplier for Irreducible Polynomials with All Non-zero Coefficients over GF($p^m$) (GF($p^m$)상에서 모든 항의 계수가 0이 아닌 기약다항식에 대한 병렬 승산기의 설계)

  • Park, Seung-Yong;Hwang, Jong-Hak;Kim, Heung-Soo
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.39 no.4
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    • pp.36-42
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    • 2002
  • In this paper, we proposed a multiplicative algorithm for two polynomials with all non-zero coefficients over finite field GF($P^m$). Using the proposed multiplicative algorithm, we constructed the multiplier of modular architecture with parallel in-output. The proposed multiplier is composed of $(m+1)^2$ identical cells, each cell consists of one mod(p) additional gate and one mod(p) multiplicative gate. Proposed multiplier need one mod(p) multiplicative gate delay time and m mod(p) additional gate delay time not clock. Also, our architecture is regular and possesses the property of modularity, therefore well-suited for VLSI implementation.

Nutrient Removal Potential of water Hyacinth Cultured in Nutrient-enriched Water and Swinery Wastewater (부레옥잠의 수중영양염 제거 잠재력에 관한 고찰)

  • 전만식;김범철
    • Korean Journal of Environmental Biology
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    • v.17 no.1
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    • pp.117-124
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    • 1999
  • Nutrients removal by water hyacinth, Eichhornia crassipes (Mart.) Solms from nutrient enriched waters and swinery wastewater were evaluated. The contents of nitrogen and phosphorus of dried water hyacinth increased from 1.4 to 3.3% and 0.21 to 0.80% when water hyacinth available N and P in the culture medium were increased from 0.7 to 5.0 mgN/1 and 0.06 o 1.5 mgP/l. respectively. Maximum N and P contents were found to be 4.1 and 0.90%, respectively. The significant relationship was observed between the standing crop of water hyacinth and the biomass yield per unit area and time. Biomass yield increased gradually until standing crop reached 15 kg wet wt./m$^2$, and then rapidly decreased. The high biomass yield of up to 0.5 kg/m$^2$/day was obtained in the range of 7 to 20 kg/m$^2$of standing crop. The potential removal rates of N and P by the water hyacinth during summer were found to be 2,250 to 2,710 mgN/m$^2$/day and 570 to 595 mgP/m$^2$/day, respectively, when 15 kg/m$^2$in standing crop and nutrient concentrations of culture medium were ranged from 1.24 to 6.2 mgP/1 and 3.2 to 32.5 mgN/1, respectively, Inorganic N and P concentrations of swinery wastewater were in the range of 82 to 121 mgN/1 and 22 to 79 mgP/1, respectively. Nitrogen and P removal rates of water hyacinth cultured in swinery wastewater were found to be in the ranges of 2,000 to 2,600 mgN/m$^2$/day and 157 to 254 mgP/m$^2$/day, respectively, at 10 times diluted water of swinery wastewater.

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A Study on Protein Separation with AOT-Isooctane Reverse Micellar System (AOT-Isooctane 역마이셀계를 이용한 단백질 분리에 관한 연구)

  • Rho, Young-Tae;Kim, Young-Sug;Cho, Hyung-Yong;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.21 no.4
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    • pp.542-548
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    • 1989
  • For the selective separation of proteins, the solubilization and desolubilization of proteins in sodium-di-2-ethylhexyl sulfosuccinate (AOT)-isooctane reverse micellar system were investigated. Protein solubilization increased with increasing the concentration of AOT to 200 mM and then decreased above that concentration. Protein was solubilized into reverse micelles in the pH range below the isoelectric Point of each protein, pH 4-10 for lysozyme and pH 5-6 for trypsin and ${\alpha}-chymotrypsin$, Lysozyme, trypsin and ${\alpha}-chymotrypsin$ were efficiently extracted in the precence of KCl and NaCl while larger molecular weight proteins such as pepsin and BSA had high solubilization with $CaCl_2$. At higher ionic strength all proteins exhibited murk less tendency to solubilize and the increase of ionic strength resulted in the decrease of micelle size. Lysozyme was successfully back transfered at pH 12.2 and 1.0M KCl; trypsin at pH 12.6 and 0.5M KCl; and ${\alpha}-chymotrypsin$ at pH 6.7 and 0.5M KCl. In a test group separation experiments, complete separation of lysozyme from BSA could be obtained.

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Analysis on Enzymatic Browning in Pine Needles (솔잎에서 발생하는 효소학적 갈변작용에 관한 분석)

  • Kong, Kwang-Hoon;Park, Hee-Joong;Choi, Sang-Sook;Cho, Sung-Hye;Kim, Yong-Tae
    • Analytical Science and Technology
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    • v.12 no.3
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    • pp.256-259
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    • 1999
  • Tyrosinases are related to the enzymatic browning of plants and attract the major scientific interest for the prevention of it. Three tyrosinase isozymes ($P_1$, $P_2$ and $P_3$) from pine needles were purified to homogeneity and characterized the factors that affect their activities. The L-ascorbic acid and ${\beta}$-mercaptoethanol notably inhibited the enzymatic activities of the three isozymes. The sodium diethyldithiocarbamate was a competitive inhibitor of isozymes with the $K_i$ values of $P_1$(0.030 mM), $P_2$(0.015 mM) and $P_3$(0.019 mM), respectively. Their enzyme activities were however, increased by the addition of most metal ions. The optimum pH for the three isozymes was 9.0~9.5 and the optimum temperatures ranged from 55 to $60^{\circ}C$ using L-DOPA as substrate.

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Effects of Tween 80 on In Vitro Fermentation of Silages and Interactive Effects of Tween 80, Monensin and Exogenous Fibrolytic Enzymes on Growth Performance by Feedlot Cattle

  • Wang, Y.;McAllister, T.A.;Baah, J.;Wilde, R.;Beauchemin, K.A.;Rode, L.M.;Shelford, J.A.;Kamande, G.M.;Cheng, K.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.7
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    • pp.968-978
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    • 2003
  • The effects of monensin, Tween 80 and exogenous fibrolytic enzymes on ruminal fermentation and animal performance were studied in vitro and in vivo. In Expt 1, the effects of the surfactant Tween 80 (0.2% wt/wt, DM basis) on ruminal fermentation of alfalfa, corn and orchardgrass silages were investigated using in vitro gas production techniques. Tween 80 did not affect (p>0.05) cumulative gas production at 24 h, but it reduced (p<0.05) the lag in fermentation of all three silages. With corn silage and orchardgrass silage, gas production rates and concentrations of total volatile fatty acids (VFA) were increased (p<0.05) by Tween 80; with alfalfa silage, they were reduced (p<0.05). Tween 80 increased (p<0.05) the proportion of propionate in total VFA, and reduced (p<0.05) acetate to propionate ratios (A:P) with all three silages. In Expt 2, exogenous fibrolytic enzymes (E; at 0, 37.5 or 75 g/tonne DM), monensin (M; at 0 or 25 ppm and Tween 80 (T; at 0 or 2 L/tonne DM) were added alone or in combination to backgrounding and finishing diets fed to 320 crossbred steers in a feeding trial with a $3{\times}2{\times}$2 factorial arrangement of treatments. The backgrounding and finishing diets contained barley grain and barley silage in ratios of 57.8:42.2 and 93.5:6.5 (DM basis), respectively. Added alone, none of the additives affected DM intake (p>0.1) in the backgrounding or in the finishing period, but interactive $M{\times}T$ effects were observed in the finishing period (p=0.02) and overall (p=0.04). In the finishing period, T without M tended to reduce DM intake (p=0.11), but T with M increased (p=0.05) DM intake. Monensin increased average daily gain (ADG) during backgrounding (p=0.07) and finishing (p=0.01), and this ionophore also improved overall feed efficiency (p=0.02). Warm carcass weight was increased (p<0.001) by M, but dressing percentage was reduced (p=0.07). In the backgrounding period, T increased ADG by 7% (p=0.06). Enzymes increased (p=0.07) ADG by 5 and 6% (low and high application rates, respectively) during backgrounding, but did not affect (p>0.10) ADG during finishing, or overall feed efficiency. Whereas T enhanced the positive effects of M on ADG during backgrounding (p=0.04) and overall (p=0.05), it had no impact (p>0.1) on the effects of E. Interactions between M and T suggest that the surfactant may have potential for enhancing the positive effects of monensin on beef production, but this requires further research.