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시멘트계 및 유기계 도포재료의 방청성능에 관한 실험적 연구 (The Experimental Study on Performance of Cementitious and Organic Anti-corrossion Coatings)

  • 신도철;이종열;박정순;오희갑;이태규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1995년도 가을 학술발표회 논문집
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    • pp.150-154
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    • 1995
  • The purpose of this study is to evalute the mechanical and the anti-corrosion characteristics of cementitious, organic coatings on steel plates. Tests are performed according to KS M 5331, 5250, etc'. For the test, we used water based epoxy, Tar epoxy, the red lead, and cementitious anti-corrosion coatings. The results of adhension tests satisfying the requirements in relevant standards The impact test shown that the impact test shown that the impact resistance of cementitious anti-corrosion test, rred lead, epoxy, cementitiouse show good corrosion resistance.

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숯가마에서 발생하는 대기오염물질의 배출특성에 관한 현장조사 연구 (A Field Survey on the Characteristics of Air Pollutants Emission from Commercial Charcoal Kiln)

  • 박성규;최상진;김진윤;박건진;황의현;이정주;김태식
    • 한국대기환경학회지
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    • 제29권5호
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    • pp.601-614
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    • 2013
  • The commercial charcoal kiln was projected the largest source of biomass burning sector in Korea. Commercial charcoal kiln was operated to emit air pollutants into the air without any air pollution prevention equipment. The object of this field survey was to understand characteristics of air pollutants concentration and emission factors and to provide preliminary data for effective processor from oak charcoal manufacturing process. As result of field survey, TSP, $PM_{10}$ and $PM_{2.5}$ concentration from charcoal kiln were 400~37,000 $mg/m^3$. These values were over the 100 $mg/m^3$ in TSP, this value was effluent quality standard of Clean Air Conservation Act. The average concentration of CO, $SO_2$ and TVOC were 2~5%. 0~110 ppm and 820~10,000 ppm respectively. The emission factors were 42.4 g-PM/kg-oak in TSP, 40.3 g-PM/kg-oak in $PM_{10}$, 38.2 g-PM/kg-oak in $PM_{2.5}$, 182.5 g-CO/kg-oak, 1.0 g-NO/kg-oak, $SO_2$ 0.2 g-$SO_2/kg$-oak and 104.4 g-TVOC/kg-oak. The part of commercial charcoal kiln had air pollution prevention equipment but it was difficult to work properly. Much wood tar excreted in exhaust emissions from oak charcoal manufacturing process. This wood tar was cause of many troubles sticking in the air pollutant prevention equipment. For handling particulate matters and gaseous air pollutants from oak charcoal manufacturing process in biomass burning, air pollutant prevention equipment design and management needs preprocessor for removal wood tar.

인산 처리된 표면 개질 음극 석탄계 피치의 전기화학적 특성 (Electrochemical Characteristics of Surface Modified CTP Anode by H3PO4 Treatment)

  • 이호용;이종대
    • 공업화학
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    • 제27권4호
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    • pp.415-420
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    • 2016
  • 음극소재의 전기화학적 성능을 향상시키기 위해, 인산의 화학처리를 통한 헤테로 원자를 도입함으로써 석탄계 피치의 표면 개질을 수행하였다. 제조된 표면 개질 피치 음극소재의 물리적 특성은 XRD, FE-SEM, XPS 분석을 통하여 수행되었으며, 전기화학적 특성은 $LiPF_6$ (EC : DMC = 1 : 1 vol% + VC 3 wt%) 전해액을 사용하여 충 방전 테스트, 율속 테스트, 순환 전압 전류 테스트와 임피던스 테스트를 통해 조사하였다. 인산 3 wt% 첨가된 표면 개질 피치 전지의 초기 충전 용량 및 초기효율은 489 mAh/g, 82%로 다른 조성의 음극소재보다 우수하였다. 또한 3 wt% 인산으로 표면개질된 CTP 음극소재의 용량 보존율은 30사이클 후에 86%를 나타냈으며, 2 C/0.1 C에서 87%의 우수한 율속 특성을 보여줌을 알 수 있었다.

첨단복합방식재를 이용한 각종 선박구조물의 마찰마모손상의 최소화 (Minimization of Friction and Wear Damage of Marine Structures by Using the Advanced Anti-corrosive Composite Materials)

  • 김윤해;김진우
    • 해양환경안전학회지
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    • 제5권2호
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    • pp.15-26
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    • 1999
  • The marine structures with sea water cooling system always expose to the oceanic atmosphere. Therefore, the protection of the equipments is very important. To investigate the effectiveness of advanced composite materials for the application in offshore environments, the tensile test, hardness test, undercutting property test, permeance test and the friction and wear test were carried out by using various applicable coating materials. The main results obtained can be summarized as follows; 1. The micro-hardness of the Archcoat 502B showed the highest value. 2. The coefficient of friction of the Rigspray coating at the speed of 2.21m/sec showed the lowest value, and that of the Archcoat 502B coating at 1.08m/sec and 0.18m/sec indicated the lowest values. 3. The wear mass at the speed of 0.18m/sec and 1.08m/sec in dry condition showed the smallest values. 4. The Archcoat 502B coating is fitted to the dynamic instruments in the range of low speed and middle speed. Rigspray coating is fitted to the dynamic instruments in the range of high speed. 5. The wear mass of five kinds of coating materials at the range of low speed was very small, and those of the Archcoat S02B, Archcoat 402B and Rigspray coating at high speed range were quitely smaller than those of the Modified Epoxy and Tar Epoxy.

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Macrophages Promote Coal Tar Pitch Extract-induced Tumorigenesis of BEAS-2B Cells and Tumor Metastasis in Nude Mice Mediated by AP-1

  • Zhang, Peng;Jin, Yue-Fei;Zhang, Qiao;Wu, Yi-Ming;Wu, Wei-Dong;Yao, Wu;Wu, Yong-Jun;Li, Zhi-Tao;Zhao, Yong;Liu, Yu;Feng, Fei-Fei
    • Asian Pacific Journal of Cancer Prevention
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    • 제15권12호
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    • pp.4871-4876
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    • 2014
  • Background: We sought to evaluate the role of tumor associated macrophages (TAMs) on the promotion of coal tar pitch extract (CTPE)-induced tumorigenesis of human bronchial epithelial cells (BEAS-2B) and tumor metastasis in nude mice, and related mechanisms. Materials and Methods: BEAS-2B cells were first treated with 2.4 mg/mL CTPE for 72 hours. After removal of CTPE, the cells were continuously cultured and passaged using trypsin-EDTA. THP-1 cells were used as macrophage-like cells. BEAS-2B cells under different conditions (n=6/group) were injected into the back necks of nude mice, and alterations of tumor xenograft growth, indicative of tumorigenicity, and tumor metastasis were determined. Pathological changes (tumor nests and microvascular lesions) of HE-stained tumor tissues were also evaluated. The expression of AP-1(c-Jun) in xenografts and metastatic tumors was determined using immunohistochemistry. Results: Tumor size and weight in nude mice transplanted with the mixture of CTPE-induced passage 30 BEAS-2B and THP-1 cells (2:1) were increased compared to those from the CTPE-treated BEAS-2B cells at passage 30 alone at different observation time points. Tumor metastasis to lymph nodes and liver was only detected after transplantation of a mixture the two kinds of cells. The numbers of tumor nests and microvascular lesions, and the expression levels of AP-1 (c-Jun) in tumors from the mixture of two kinds of cells were increased apparently in contrast to those in tumor from the CTPE-treated BEAS-2B cells of passage 30 alone. In addition, there was positive correlation between AP-1 (c-Jun) expression level and the number of microvascular lesions, or between AP-1 (c-Jun) expression level and tumor metastasis in these two groups. Conclusions: TAMs not only facilitate tumorigenesis transformation of CTPE-induced BEAS-2B cells, but also promote tumor growth, angiogenesis and metastasis in nude mice in vivo, which may be mediated by AP-1.

KOH 활성화에 의한 피치계 고품질 활성탄의 제조 및 특성 (Preparation and Characterization of high-quality activated carbon by KOH activation of pitch precursors)

  • 이은지;권순형;최푸름;우종표;정지철;김명수
    • 한국응용과학기술학회지
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    • 제31권3호
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    • pp.408-415
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    • 2014
  • In order to prepare high-quality activated carbons (ACs), coal tar pitch (CTP), and mixtures of CTP and petroleum pitch (PP) were activated with KOH. The ACs prepared by activation of CTP in the range of $700{\sim}1000^{\circ}C$ for 1~5 h had very porous textures with large specific surface areas of $2470{\sim}3081m^2/g$. The optimal activation conditions of CTP were determined as CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained AC showed the highest micro-pore volume, and pretty high specific surface area and meso-pore volume. The micro-pore volumes and specific areas of activated mixtures of CTP and PP were similar to each other but the meso-pore volume could be increased. In order to change the degree of crystallinity of precursors before KOH activation process, the CTPs were carbonized in the range of $500{\sim}900^{\circ}C$. As the carbonization temperature increased, the specific surface area and pore volume of the activated ACs with the same activation conditions for CTP decreased dramatically. It was demonstrated that the increased pore size distribution of AC electrodes in the range of 1 to 2 nm plays an important role in the performance of electric double-layer capacitor.

니켈을 함유한 콜타르 피치 결합제를 이용한 미생물연료전지 산화전극 성능개선 (Improvement of Anodic Performance by Using CTP Binder Containg Nickel)

  • 윤형선;송영채;최태선
    • 대한환경공학회지
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    • 제37권9호
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    • pp.499-504
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    • 2015
  • 팽창흑연과 탄소나노튜브를 이용한 산화전극을 CTP에 Ni을 혼합한 결합제로 제작하였으며, 산화전극에 CTP와 Ni을 혼합한 결합제와 Nafion 결합제를 대조구로 미생물연료전지의 성능에 미치는 영향을 회분식 실험을 통하여 조사하였다. 산화전극 제작에 사용된 CTP 양이 적을수록, Ni 함량이 증가할수록 산화전극 표면에 부착성장한 미생물량이 증가하였으며, 내부저항이 감소하였다. CTP 4 g과 Ni 0.2 g을 혼합한 결합제로 제작한 산화전극의 경우 최대전력밀도는 $731.8mW/m^2$, 내부저항은 $146.19{\Omega}$이다. 대조구인 Nafion결합제로 제작한 산화전극와 비교하여 최대전력밀도는 23.68% 컸으며, 내부저항은 33.82% 낮았다. 따라서, CTP와 Ni을 혼합한 물질은 저렴하고 효율이 높은 미생물연료전지의 산화전극결합제로서 좋은 대안이 될 수 있다.

중방식 도료의 내식성에 관한 전기 화학적 평가(II) (An Electrochemical Evaluation on the Corrosion Resistance of Heavy Anticorrosive Paint(II))

  • 성호진;김진경;이명훈;김기준;문경만
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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    • pp.382-387
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    • 2005
  • An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint was carried out for 5 kinds of heavy anticorrosive paints such as High solid epoxy(HE), Solvent epoxy(SE), Tar epoxy(TE), Phenol epoxy(PE), and Ceramic epoxy(CE) as parameters of DFT(Dry Film Thickness, 25${\mu}m$50${\mu}m$, solution condition(Flow of Nonflow). Corrosion current density of HE(DFT 50${\mu}m$ in case of flow condition was larger than that of nonflow condition. However, their values of the other anticorrosive paints were decreased compared to the nonflow condition. The values of AC impedance were increased with increasing of DFT regardless of kinds of anticorrosive paints. And the polarization resistance of cyclic voltammogram showed a good tendency to correspond with well the values of AC impedance measurement. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paint.

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다핵방향족탄화수소류에 노출된 페인트 취급 근로자에서 요 중 1- Hydroxypyrene을 이용한 생물학적 모니터링 (Biological Monitoring of Paint Handling Workers exposed to PAHs using Urinary 1-Hydroxypyrene)

  • 이종성;김은아;이용학;문덕환;김광종
    • 한국산업보건학회지
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    • 제15권2호
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    • pp.124-134
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    • 2005
  • To investigate the exposure effect of polynuclear aromatic hydrocarbons (PAHs), we measured airborne total PAHs as an external dose, urinary 1-hydroxypyrene (1-OHP) as an internal dose of PAHs exposure, and analyzed the relationship between urinary 1-OHP concentration and PAHs exposure. The study population contained 44 workers in steel-pipe coating and paint manufacture industries. The airborne PAHs was obtained during survey day, and urine were sampled at the end of shift. Personal information on age, body weight, height, eniployment duration, smoking habit, and alcohol consumption was obtained by a structured questionnaire. Airborne PAHs were analyzed by the gas chromatograph with mass selective detector. Urinary 1-OHP levels were analyzed by the high performance liquid chromatograph with ultraviolet wavelength detector. For statistical estimation, t-test, ${\chi}^2$-test, analysis of variance, correlation analysis, arid regression analysis were executed by SPSS/PC (Windows version 10). The mean of environmental total PAHs was $87.8{\pm}7.81{\mu}g/m^3$. The mean concentration ($526.5{\pm}2.85{\mu}g/m^3$) of workers in steel-pipe coating industries using coal tar enamel was the higher than that ($17.5{\pm}3.36{\mu}g/m^3$) of workers in paint manufacture industries using coal tar paint. The mean of urinary 1-OHP concentration ($51.63{\pm}3.144{\mu}\;mol/mol$ creatinine) of workers in steel-pipe coating industries was the higher than that ($2.33{\pm}4.709{\mu}\;mol/mol$ creatinine) of workers in paint manufacture industries. The mean of urinary 1-OHP concentration of smokers was the higher than that of non-smokers. There was significant correlation between the urinary concentration of 1-OHP and the environmental concentration of PAHs (r=O.S48, p<0.001), pyrene(r=0.859, p<0.001), and urinary cotinine (r=0.324, p<0.05). The regression equation between the urinary concentration of 1-OHP in ${\mu}g/g$ creatinine($C_{1-OHP}$) and airborne concentration of PAHs (or pyrene) in ${\mu}g/m^3$ ($C_{PAHs}$ or Cpyrene) is: Log ($C_{1-OHP}$)=-0.650+0.889×Log($C_{PAHs}$), where $R^2=0.694$ and n=38 for p<0.001.Log ($C_{1-OHP}$)=1.087+0.707${\times}$Log(Cpyrene), where $R^2=0.713$ and n=38 for p<0.001. From the results of stepwise multiple regression analysis about 1-OHP, significant independents were total PAHs and urinary cotinine (adjusted $R^2=0.743$, p<0.001). In this study, there were significant correlation between the urinary concentration of 1-OHP and the airborne concentration of PAHs. The urinary 1-OHP was effective index as a biomarker of airborne PAHs in workplace. But it was influenced by non-occupational PAHs source, smoking.

Personal, Occupational, and Public Health Perspectives on Dealing with the First Case of Influenza A (H1N1) in the United Arab Emirates

  • Shah, Syed M.;Aw, Tar-Ching;Blair, Iain;Hashmey, Rayhan;Sheek-Hussein, Mahmoud
    • Safety and Health at Work
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    • 제2권1호
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    • pp.83-86
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    • 2011
  • New epidemics of infectious diseases often involve health care workers. In this short communication we present a case report of a health care professional who became the first case of influenza H1N1 virus to be notified in the United Arab Emirates. There are several issues related to workplace considerations and general public health, including preventive measures, the need for isolation of the patient, dealing with contacts, return to work, and communication with the workforce.