• Tribology and Lubricants
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• v.30 no.5
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• pp.247-255
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• 2014

Charged polymer chains, i.e., polyelectrolytes, are known to show superior aqueous lubricating properties compared to those of neutral polymer chains, especially in brush conformation. This is primarily because of the incorporation of a large amount of counterions within the polymer layers and the consequently increased osmotic pressure. However, this effect is active only when the polymer chains remain immobilized even under tribostress, which is not realistic for high-contact pressure tribological applications, especially when they are irreversibly immobilized on tribopair surfaces. In contrast, with free polymers, which can be included as surface-active additives in the base lubricant (water), long-term lubricating performance based on "self-healing" properties is readily expected. In order to assess whether the superior aqueous lubricating properties of polyelectrolyte chains are valid for free polymers too, this study reviews recent studies on the tribological properties of many charged biopolymer and synthetic copolymers at a nonpolar, hydrophobic interface. In contrast to the irreversibly immobilized polyelectrolyte chains, free polyelectrolyte chains show inferior aqueous lubricating properties compared to their neutral counterparts owing to charge accumulation and the consequently impeded surface adsorption on the nonpolar surface. Nevertheless, bovine submaxillary mucin (BSM), a representative biopolymer, shows a sufficiently effective surface adsorption and aqueous lubricating capabilities even at neutral pH without losing the polyanionic characteristics.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.43-44
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• 2002

Langmuir-Blodgett mono- and multilayer films from 2,4-heneicosanedione have been examined as lubrication coatings In the process of wear. Tribological properties of the films have been studied by atomic force microscopy and microtribometer. It has been observed that the wear resistance of silicon surface coated with OTS/LB multilayer system increased by several orders of magnitude compared to uncoated surfaces at low normal load. The results obtained suggest that the system constructed on silicon surface reduces surface energy, friction coefficient and increases life of substrate due to a possibility of LB film self-repairing during frictional contact.

• Tribology and Lubricants
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• v.19 no.5
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• pp.280-284
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• 2003

High performance characteristics are required for rolling bearings and the various functions of bearing are greatly influenced by grease. Recently, higher performance is being demanded of rolling bearing greases for bearing lubrication. Four special greases with different composition such as lithium soap/ester oil, urea/ester oil, urea/ether oil and PTFE/fluorine oil were synthesized to compare the performance of these greases with that of the conventional lithium soap/mineral oil grease. The grease properties were investigated using a series of typical grease testing methods and grease life test. After the life test, the greases were charaterized by FTIR analysis and a microscope. And the iron amount in the greases was analyzed by AAS after ashing. The composition and manufacturing process determined the grease performance. The grease with a base oil of synthetic oil showed higher performance and the urea/ester oil and PTFE/fluorine oil showed about three times longer life as compared with conventional lithium grease.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2001.11a
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• pp.364-373
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• 2001

This paper describes the variation of lubricant's temperature effects on elastohydrodynamic lubrication. The Newton-Raphson technique was used to solve the simultaneous system of Reynolds and elasticity equations. To show effects of lubricant's temperature, average temperature across the oil film was calculated using the energy equation. Pressure distribution, film shape, and temperature distribution were obtained for fully flooded conjunctions, and various dimensionless speed parameters while load and material parameters were held constant. Minimum film thickness were obtained for various material properties while load and velocity were held constant. It is drawn that the thermal effects have a strong influence on a minimum film thickness under high rolling velocity and slip ratio.

• Tribology and Lubricants
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• v.16 no.5
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• pp.341-350
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• 2000

The study reported in this paper deals with the development for parametric investigation of the influence of the rheological properties of the lubricant in the thermohydrodynamic (THD) film conditions which occur in slider and journal bearings. A parametric investigation based on a Bingham model with a shear yield stress which best fit the experimental pressure is performed for predicting the thickness of the shear Bone in lubricating films with fixed geometry between the stationary and moving surfaces. The results suggest that the shear yield stress for the lubricating film is proportional to the pressure developed in the film within the range of the investigated cases and the shear zone thickness which is of the same order of magnitude as that obtained by the empirical formula is significantly smaller than the fluid film thickness in the lubrication zone.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2003.11a
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• pp.129-138
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• 2003

Rolling bearings are classified one of the most important machine elements. The various function of bearings are greatly influenced by grease, and higher performance of rolling bearing greases is required in improve bearing lubrication. Three urea/ether oil greases with identical composition were synthesized to compare the performance of these greases according to the thickener content of grease. The typical grease physical properties were investigated. And life test of these greases was conducted by FE-9 grease life tester. The characteristics of the greases before and after life test were investigated using FT-IR, microscope, OIT and TAN meter. Large differences in the grease performance depending on the content of the thickener were observed. The grease with higher content of the hickener showed higher performance such as long life time and low TAN value. After preliminary test, twelve greases were synthesized and evaluated the performance of dropping point and OIT, then optimized two greases were selected by SSRED (Six Sigma Robust Engineering Design) using dropping point and OIT data. Characteristics of the optimized two greases were on the same level with estimated value. The optimized grease by means of OIT value showed longer grease life in comparison with optimized grease by dropping point. However two greases showed higher performance than typical urea/ether oil.

• Tribology and Lubricants
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• v.39 no.2
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• pp.43-48
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• 2023

In this study, we investigate the tribological behavior of AISI 304 stainless steel pairs under deionized water and hexagonal boron nitride (h-BN) water dispersion lubrication. The specimen friction and wear properties are evaluated using a reciprocating ball-on-flat tribometer. The coefficient of friction remains nearly constant throughout the test under both lubricant conditions. The wear depth of the specimens under h-BN lubrication is smaller than that under deionized water lubrication, indicating the inhibition behavior of h-BN nanolubricants on direct metal-metal contacts. Optical micrographs and stylus profilometer measurements are performed to evaluate the severity of damage caused by the sliding motion and to determine the wear morphology of the specimens, respectively. The results show that h-BN nanolubricants does not have a significant effect on the friction behavior but demonstrates reduced wear owing to their trapping effect between the sliding interfaces. Moreover, scanning electron microscopy and energy-dispersive X-ray spectroscopy images of the specimens were acquired to confirm the trapping effect of h-BN between the sliding interfaces. The results also suggest that the trapped lubricants can distribute the contact pressure, reducing the wear damage caused by the metal-metal contact at the interface. In conclusion, h-BN nanolubricants have potential as an anti-wear additive for lubrication applications. Further investigation is needed to provide direct evidence of the trapping effect of h-BN nanoparticles between the sliding interfaces. These findings could lead to the development of more efficient and effective lubricants for various industrial applications.

• Tribology and Lubricants
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• v.40 no.3
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• pp.78-83
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• 2024

The development of eco-friendly alternative energy sources has become a global priority owing to the depletion of fossil fuels and an increase in environmental concerns. Hydrogen energy has emerged as a promising clean energy source, and hydrogen compressors play a crucial role in the storage and distribution of compressed hydrogen. However, harsh operating conditions lead to the rapid deterioration of conventional lubricants in hydrogen compressors, thereby necessitating the development of advanced lubrication technologies. This study introduces micrometer-sized silicone rubber powders as lubricant additives to enhance the lubrication performance of hydraulic oils in hydrogen compressors. We prepare silicone rubber powders by varying the ratio of the silicone rubber base to the curing agent and investigate their effects on interfacial properties, friction behavior, and wear characteristics. The findings reveal that the incorporation of silicone rubber powders positively influences the surface affinity, wettability, friction reduction, and wear resistance of the lubricants on the 304SS substrate. Moreover, we identify the optimal lubricant formulations, with a 15:1 ratio demonstrating the most effective friction reduction and a 5:1 ratio exhibiting the highest wear resistance. The controlled surface modification by the silicone rubber powder and the enhanced interfacial characteristics of the powder-containing lubricants synergistically contribute to the improved lubrication performance. These results indicate the potential of silicone rubber powder additives for the development of long-life lubrication solutions for hydrogen compressors and related applications, ultimately contributing to the advancement of sustainable energy technologies.

• Tribology and Lubricants
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• v.19 no.3
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• pp.139-145
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• 2003

In this paper, static characteristics of a cryogenic hydrostatic journal bearing which has 2-rows staggered recesses are numerically analyzed. The regime of operation of this bearing is fully turbulent with large fluid inertia effects. The turbulent lubrication equation is solved under the assumption that turbulence parameters are decided by the Reynolds numbers. Pressure drop caused by inertia effect at the recess edge is considered in this analysis. Also density and viscosity of working fluid are considered as function of only pressure. Numerical results for a cryogenic Hydrostatic journal bearing show pressure distribution, load capacity, flow rate, and recess pressure. The effects of turbulent flow, pressure drop and variable liquid properties are discussed.

• Tribology and Lubricants
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• v.29 no.2
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• pp.117-123
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• 2013

Dimethyl ether (DME) has a high cetane number that is suitable for diesel fuel. DME does not contain sulfur or nitrogen, and is an oxygenated fuel so it produces no particulate matter when combusted and is environmentally friendly. DME fuel for diesel engines show excellent material properties such as a lower volumetric heating value, lower boiling point, lower lubricity, and stronger solvent effect than light oil. This study experimentally examined a lubricity improver (LI) for dimethyl ether. A diesel LI based on biodiesel and fatty acid methyl ester was tested among DME LI candidates. The long-term storage stability and physical properties of the optimum LI for DME were determined.