• Title/Summary/Keyword: Low-density concentration

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Effect of the Photosensitizer on the Photo refractive Effect Using a Low $T_g$ Sol-Gel Glass

  • Choi, Dong-Hoon;Jun, Woong-Gi;Oh, Kwang-Yong;Yoon, Han-Na;Kim, Jae-Hong
    • Macromolecular Research
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    • v.11 no.4
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    • pp.250-255
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    • 2003
  • We prepared the photorefractive sol-gel glass based on organic-inorganic hybrid materials containing a charge transporting molecule, second-order nonlinear optical (NLO) chromophore, photosensitizer, and plasticizer. Carbazole and 2-{ 4-[(2-hydroxy-ethyl)-methyl-amino]-benzylidene}-malononitrile were reacted with isocyanato-triethoxy silane and the functionalized silanes were employed to fabricate the efficient photorefractive media induding 2,4,7-trinitrot1uorenone (TNF) to form a charge transfer complex. The prepared sol-gel glass samples showed a large net gain coefficient and high diffraction efficiency at a certain composition. As the concentration of photosensitizer increased, the photorefractive properties were enhanced due to an increment of charge carrier density. Dynamic behavior of the diffraction efficiency was also investigated with the concentration of the photosensitizer.

Growth and salting properties influenced by culture methods, cultivars and storage packaging of kimchi cabbage (Brassica rapa) in spring

  • Lee, Jung-Soo
    • Korean Journal of Agricultural Science
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    • v.45 no.4
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    • pp.623-634
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    • 2018
  • This experiment was conducted to determine the effects of the pre- and post-harvest variable factors on the processed product of kimchi cabbage. Two kimchi cabbage cultivars, namely 'Chungwang' and 'Dongpung,' were grown in a field and under a plastic greenhouse condition and stored at $5^{\circ}C$ after harvesting with and without low-density polyethylene (LDPE) film packaging. Growths were determined after harvesting while salting characteristics were determined after the processing and storage. The results show that the height, weight and leaf thickness were higher in kimchi cabbages grown in the greenhouse than those grown in the field. The plastic house culture increased the kimchi cabbage growth of the head weight, head height and leaf thickness compared with that of the open field culture. However, the osmolality and firmness were higher in the outdoor cultivated kimchi cabbages. Kimchi cabbage packed in film covered sacks and stored at $5^{\circ}C$ showed lower weight loss than unpacked cabbages during storage. Salt concentration and pH were also affected by the different pre- and post-harvest factors after salting the kimchi cabbages. Salt concentrations of the kimchi cabbage were influenced by various factors such as the cultivars, cultivation methods and storage covering. Though the present findings showed a limited difference in salt concentration and pH between the cultivars of kimchi cabbages, this study suggests that there is a relationship between processed agricultural products and their pre- and post-harvest methods.

Study for Improved Photocurrent via High Concentrated Tin-lead Perovskite Precursor Solution (주석-납 기반 페로브스카이트 고농도 전구체 용액을 이용한 광전류 향상 연구)

  • Hyojin Hong;Seungmin Lee;Jeong Min Im;Jun Hong Noh
    • Current Photovoltaic Research
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    • v.11 no.3
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    • pp.96-102
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    • 2023
  • Sn-Pb narrow-bandgap perovskite solar cells, which is a light-harvesting layer thicker than 1.3 micrometers, is needed to enhance the low photocurrent. The fabrication of such a thick film through solution processing is a key challenge. Here, we studied and characterized the film by using a precursor solution of increased concentration, comparing it with the universally used 1-micrometer Sn-Pb perovskite film. The increase in molar concentration clearly induced thickness enhancement, but we observed that it also created numerous voids at the interface with bottom charge transporting layer. We hypothesized that these voids might hinder the increase in photocurrent associated with thickness enhancement. By introducing methylammonium chloride (MACl), we successfully fabricated Sn-Pb perovskite film with a thickness of 1.3 micrometer and no voids. Void-controlled Sn-Pb perovskite solar cells not only demonstrated superior short-circuit current density compared to those with voids but also operated smoothly under light exposure.

Production of Ammonia Water and Sulfuric Acid from Ammonium Sulfate by Electrodialysis with a Bipolar Membrane (바이폴라막 전기투석을 이용한 황산암모늄으로부터 암모니아수와 황산의 제조)

  • Hwang, Ui-Son;Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.36-42
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    • 2005
  • This study examined the feasibility of producing sulfuric acid and ammonia water from ammonium sulfate solution using two-compartment electrodialysis with a bipolar membrane (EDBM). Electrodialysis experiments were carried out with 20 wt% ammonium sulfate at different current densities and sulfuric acid concentrations in a concentrate compartment. The current efficiency increased with the current density from 25 to $100\;mA/cm^2$. Nevertheless, the efficiency was relatively low compared with that of general desalting electrodialysis, owing to the diffusion of sulfuric acid from the concentrate compartment to the diluate. The diffusion rate through the anion exchange membrane increased with the sulfuric acid concentration in the concentrate compartment, which decreased the current efficiency. Conversely, the electrical resistance decreased with increasing current density owing to the Joulian heat generated during water dissociation in the transition region of the bipolar membrane under a high electric field. From the experimental results, we concluded that operating at a higher current density is effective from the perspective of current efficiency and electrical resistance when producing sulfuric acid and ammonia water from ammonium sulfate using a two-compartment EDBM process. Further studies on the effects of increasing the sulfuric acid concentration on current efficiency are required to apply the EDBM process practically.

Application of Priority Order Selection Technique for Water Quality Improvment in Stream Watershed by Relationship of Flow and Water Quality (유량-수질관계 비교를 통한 하천 수질개선 우선순위 선정기법 적용)

  • Lim, Bong-Su;Cho, Byung-Wook;Kim, Young-Il;Kim, Do-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.802-808
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    • 2010
  • This study was carried out to apply the method of priority order selection for water quality improvement of watershed. The monitoring of flow and water quality, grouping branch streams and discharge load density were estimated on 18 branch streams located in middle and lower area of Geum River, Chungcheongnam-do. Based on average BOD concentration of stream at low flow, the results of the water quality analysis of stream which excess river living standard class 2 (less than BOD 3 mg/L) are Jeongancheon, Bangchukcheon, Gilsancheon, Jocheon, Seokseongcheon and Ganggyeongcheon. As a result of grouping stream, stream that have more than $10\;m^3/min$ of flow and more than 3.0 mg/L of average BOD concentration such as Group A are Jocheon, Seokseongcheon, Ganggyeongcheon and Jeongancheon. In Group A, stream corresponds to over than discharge load density as of 10 BOD kg/$day{\cdot}km^2$ is Jocheon, Seokseongcheon and Ganggyeongcheon. In view of the selected results to improve water quality basin through monitoring of flow and water quality, grouping stream, and estimation of discharge load density, Jocheon in Yeongi, Seokseongcheon located on the border of Buyeo and Nonsan, Ganggyeongcheon on Nonsan such as stream basin were urgent to improve water quality.

Changes of Chemical Composition in Blood Serum during the Antler Growth Period in Spotted Deer (Cervus nippon)

  • Jeon, B.T.;Kim, M.H.;Lee, S.M.;Thomas, David G.;Moon, S.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.9
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    • pp.1298-1304
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    • 2006
  • The aim of this study was to provide basic haematological information to allow improved nutritional management for velvet production in spotted deer (Cervus nippon) by investigating biochemical changes in blood values during the antler growth period. Blood samples, obtained from the jugular vein of twenty-five deer, were taken every 10 days from casting (day 0) to harvesting (day 50) of velvet antler. Negligible changes were found in the concentrations of total protein, albumin, and creatinine during the antler growth period, but there were significant changes in the concentrations of urea (p<0.05) and uric acid (p<0.01). The concentration of triglyceride was significantly higher (p<0.05) during the antler growth period compared to casting time, while serum high-density lipoprotein concentrations were low and remained unchanged during the antler growth period. Serum glucose concentration increased (p<0.05) significantly and was slightly changeable during antler growth. The serum concentrations of Ca and P did not fluctuate during antler growth, while those of Na, K and Cl showed slight differences between the time of casting and the rest of the antler growth period. No significant changes in concentrations of AST, ALT, amylase, CK, GGT and LDH were detected during the antler growth period. However, the concentration of ALK-P increased during antler growth reaching its peak on day 50 after casting. We found a significant difference in the concentration of ALK-P between the time of casting and the rest of the antler growth period (p<0.01). Consequently, antler growth was associated with mild changes in measured serum biochemical values with the exception of ALK-P activity in spotted deer.

Control of dissolved Oxygen Concentration and Specific Growth Rate in Fed-batch Fermentation (유가식 생물반응기에서의 용존산소농도 및 비성장속도의 제어)

  • Kim, Chang-Gyeom;Lee, Tae-Ho;Lee, Seung-Cheol;Chang, Yong-Keun;Chang, Ho-Nam
    • Microbiology and Biotechnology Letters
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    • v.21 no.4
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    • pp.354-365
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    • 1993
  • A novel control method with automatic tuning of PID controller parameters has been developed for efficient regulation of dissolved oxygen concentration in fed-batch fermentations of Escherichia coli. Agitation speed and oxygen partial pressure in the inlet gas stream were chosen to be the manipulated variables. A heuristic reasoning allowed improved tuning decisions from the supervision of control performance indices and it coule obviate the needs for process assumptions or disturbance patterns. The control input consisted of feedback and feedforword parts. The feedback part was determined by PID control and the feedforward part is determined from the feed rate. The proportional gain was updated on-line by a set of heuristics rules based on the supervision of three performance indices. These indices were output error covariance, the average value of output error, and input covariance, which were calculated on-line using a moving window. The integral and derivative time constants were determined from the period of output response. The specific growth rate was maintained at a low level to avoid acetic acid accumulation and thus to achieve a high cell density. The specific growthe rate was estimated from the carbon dioxide evolution rate. In fed-batch fermentation, the simutaneous control of dissolved oxygen concentration (at 0.2; fraction of saturated value) and specific growth rate (at 0.25$hr^{-1}$) was satisfactory for the entire culture period in spite of the changes in the feed rate and the switching of control input.

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담배세초현탁배양을 이용한 human granulocyte-macrophage colony stimulating factor의 생산에서 배지 성분이 미치는 영향

  • Lee, Gi-Yong;Lee, Sang-Yun;Myeong, Hyeon-Jong;No, Yun-Suk;Kim, Dong-Il
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.325-328
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    • 2002
  • Production of human granulocyte-macrophage colony stimulating factor (hGM-CSF) by Nicotiana tabacum cell suspension culture was studied in Murashige and Skoog (MS) medium with sucrose as a carbon source, ammonium nitrate and potassium nitrate as nitrogen sources, potassium dihydrogen phosphate and sodium dihydrogen phosphate hydrate as phosphate sources, respectively. Optimum concentrations for carbon, nitrogen, phosphate was determined to enhance the production of hGM-CSF. Cell growth was better at high initial sucrose concentration (60 g/L), high initial nitrogen concentration (121.04 mM). Maximum cell density (18.28 g/L) was obtained at 60 g/L of sucrose after 14 days. Cell growth was not so good at low initial sucrose concentration 00 g/L), but the highest hGM-CSF production was obtained at the latter half of exponential phase. hGM-CSF production increased about 3 fold at initial phosphate concentration of 4.96 nM

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High Performance GaN-Based Light-Emitting Diodes by Increased Hole Concentration Via Graphene Oxide Sheets

  • Jeong, Hyun;Jeong, Seung Yol;Jeong, Hyun Joon;Park, Doo Jae;Kim, Yong Hwan;Kim, HyoJung;Lee, Geon-Woong;Jeong, Mun Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.244.1-244.1
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    • 2013
  • The p-type GaN which act as a hole injection layer in GaN-based LEDs has fundamental problems. The first one arises from the difficulty in growing a highly doped p-GaN (with a carrier concentration exceeding ~1018 $cm^{-3}$). And the second one is the absence of appropriate metals or conducting oxides having a work function that is larger than that of p-type GaN (7.5 eV). Moreover, the LED efficiency is decreases gradually as the injection current increases (the so-called 'efficiency droop' phenomenon). The efficiency droop phenomenon in InGaN quantum wells (QWs) has been a large obstacle that has hindered high-efficiency operation at high current density. In this study, we introduce the new approaches to improve the light-output power of LEDs by using graphene oxide sheets. Graphene oxide has many functional groups such as the oxygen epoxide, the hydroxyl, and the carboxyl groups. Due to nature of such functional groups, graphene oxide possess a lot of hole carriers. If graphene oxide combine with LED top surface, graphene oxide may supply hole carriers to p-type GaN layer which has relatively low free carrier concentration less than electron concentration in n-type GaN layer. To prove the enhancement factor of graphene oxide coated LEDs, we have investigated electrical and optical properties by using ultra-violet photo-excited spectroscopy, confocal scanning electroluminescence microscopy.

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Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion Between CFRP and A516Gr.55 Carbon Steel

  • Hur, Seung Young;Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.18 no.4
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    • pp.129-137
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    • 2019
  • CFRP (Carbon Fiber Reinforced Plastics) is composed of carbon fiber and plastic resin, and is approximately 20 - 50% lighter than metallic materials. CFRP has a low density, higher specific stiffness, specific strength, and high corrosion resistance. Because of these excellent properties, which meet various regulation conditions needed in the industrial fields, CFRP has been widely used in many industries including aviation and ship building. However, CFRP reveals water absorption in water immersion or high humidity environments, and water absorption occurs in an epoxy not carbon fiber, and can be facilitated by higher temperature. Since these properties can induce volume expansion inside CFRP and change the internal stress state and degrade the chemical bond between the fiber and the matrix, the mechanical properties including bond strength may be lowered. This study focused on the effects of NaCl concentration (0.01 - 1% NaCl) and solution temperature ($30-75^{\circ}C$) on the galvanic corrosion between CFRP and A516Gr.55 carbon steel. When NaCl concentration increases 10 times, corrosion rate of a specimen was not affected, but that of galvanic coupled carbon steel increased by 46.9% average. However, when solution temperature increases $10^{\circ}C$, average corrosion rate increased approximately 22%, regardless of single or galvanic coupled specimen.