• Title/Summary/Keyword: Low-density concentration

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Contribution of Counterion Entropy to the Salt-Induced Transition Between B-DNA and Z-DNA

  • Lee, Youn-Kyoung;Lee, Juyong;Choi, Jung Hyun;Seok, Chaok
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3719-3726
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    • 2012
  • Formation of Z-DNA, a left-handed double helix, from B-DNA, the canonical right-handed double helix, occurs during important biological processes such as gene expression and DNA transcription. Such B-Z transitions can also be induced by high salt concentration in vitro, but the changes in the relative stability of B-DNA and Z-DNA with salt concentration have not been fully explained despite numerous attempts. For example, electrostatic effects alone could not account for salt-induced B-Z transitions in previous studies. In this paper, we propose that the B-Z transition can be explained if counterion entropy is considered along with the electrostatic interactions. This can be achieved by conducting all-atom, explicit-solvent MD simulations followed by MM-PBSA and molecular DFT calculations. Our MD simulations show that counterions tend to bind at specific sites in B-DNA and Z-DNA, and that more ions cluster near Z-DNA than near B-DNA. Moreover, the difference in counterion ordering near B-DNA and Z-DNA is larger at a low salt concentration than at a high concentration. The results imply that the exclusion of counterions by Z-DNA-binding proteins may facilitate Z-DNA formation under physiological conditions.

The Effect of Magnesium and Aluminium Ions on Zeta Potential of Bubbles (수중의 마그네슘과 알루미늄 이온이 기포의 제타전위에 미치는 영향)

  • Han, Moo-Young;Ahn, Hyun-Joo;Shin, Min-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.573-579
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    • 2004
  • Electroflotation, which is used as an alternative to sedimentation, is a separation treatment process that uses small bubbles to remove low-density particulates. Making allowances for recent collision efficiency diagram based on trajectory analysis, it is necessary to tailor zeta potential of bubbles that collide with negatively charged particles. In this paper, the study was performed to investigate the effects of magnesium and aluminium ions on zeta potential of bubbles. And, it was studied to find out factors which could affect the positively charged bubbles. Consequently, zeta potential of bubbles increased both with higher concentration of metal ions and in the acidic pH value. And, a probable principle that explained the procedure of charge reversal could be a combined mechanism with both specific adsorption of hydroxylated species and laying down of hydroxide precipitate. It also depended on the metal ion concentration in the solution to display its capacity to control the bubble surface.

남해연안해역에 있어서 식물플랑크톤 군집의 계절변동 특성과 기초생산 1. 가뭄시 여수해만의 수질환경과 식물색소량 분포특성

  • 윤양호;김성아
    • Journal of Environmental Science International
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    • v.5 no.3
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    • pp.347-359
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    • 1996
  • A study was carried out on the distribution of chlorophyll a and water quality in the dry season in Yosuhae bay and adjoining sea, Southern Korea, in July of 1994. Concentration of salinity and phosphate were lower in the outer bay than in the inner bay. While nitrate and silicate were higher in the former than in the latter. We were identified with coastal waters of origin from China with the lower salinity in outer bay. The China coastal water was characteristic of high nutrients and phytoplankton biomass, such as chlorophyll a. The principal component analysis-(PCA) on the analytical data proved that high density of phytoplankton biomass , occurred under the condition of low salinity and high concentration of nissoived Inorganic nutrients. It is thought that the thermoharine structure and biological produtions of Yosuhae bay were controlled by the China coastal water in the outer bay.

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A Study of Electro-Deposition for Pb-Sn-Cu Alloy System (연-주석-동계 합금속도에 관한 연구)

  • Kang, T.;Cho, C. S.;Yum, H. T.
    • Journal of Surface Science and Engineering
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    • v.4 no.1
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    • pp.16-23
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    • 1971
  • In this study , fluoborte solution consisting of lead fluoborate, tin fluoborate and cupric acetate was used. By addition of small amount of Cu+= ion to the solution, the Cu content of deposition layer was almost controlled less than 5%. The amount of Cu in deposition layer was almost constant without any influence of Pb++ & Sn++ in the solution, and the amount of Pb was increased by the increase of total concentration of Pb++ +Sn++ in the solution, and the amount of Pb was increased by the increase of total concentration of Pb++ +Sn++ in the solution . Agitation of plating solution & low current density result in the increase of Cu content. Analyzing of microscopic structures and etching tests of the deposited alloy, it was believed that the alloy had a lamellar structure consisting of copper rich lamellar and lead rich layer.

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Ecological Characteristics of Some Algal Populations along Environmental Gradients of Zinc (아연환경구배에 의한 녹조류개체군생장의 생태학적 특성)

  • 송승달
    • Journal of Plant Biology
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    • v.20 no.3
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    • pp.119-126
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    • 1977
  • The maximum relative growth rate of algae treated with Zinc was shown as follows: 15, 8, 6, 3 and -5% per day for the rather sensitive Chlorella sp. populations, or 14, 7, 5 and 4% per day for the Pleurococcus sp. populations, and 22, 20, 13, 9 and 7% per day for the more resistant Scenedesmus spinosus populations, respectively for the culture medium with 0, 1, 5, 10 and 20 ppm of Zinc treatment. With mixed cultures of Chlorella sp. and Scenedesmus spinosus populations, the growth of the Chlorella sp. population overcame that of the S. spinomsus population from the cultures treated with relatively low concentration of Zinc. On the contrary, the population growth of the latter resistant species overcame that of the former sensitive species when the concentration of Zinc was above 5 ppm Zn of the medium. This paper describes the results of further investigations of the effects evaluated by direct cell counts method, optical density comparisons, oxygen production and consumption determinations and the measurements of the fate of Zinc treated in the solutions.

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Mobility Enhancement in Polycrystalline Silicon Thin Film Transistors due to the Dehydrogenation Mechanism

  • Lee, Seok Ryoul;Sung, Sang-Yun;Lee, Kyong Taik;Cho, Seong Gook;Lee, Ho Seong
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1329-1333
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    • 2018
  • We investigated the mechanism of mobility enhancement after the dehydrogenation process in polycrystalline silicon (poly-Si) thin films. The dehydrogenation process was performed by using an in-situ CVD chamber in a $N_2$ ambient or an ex-situ furnace in air ambient. We observed that the dehydrogenated poly-Si in a $N_2$ ambient had a lower oxygen concentration than the dehydrogenated poly-Si annealed in an air ambient. The in-situ dehydrogenation increased the (111) preferred orientation of poly-Si and reduced the oxygen concentration in poly-Si thin films, leading to a reduction of the trap density near the valence band. This phenomenon gave rise to an increase of the field-effect mobility of the poly-Si thin film transistor.

Effects of Dietary Dihydropyridine Supplementation on Laying Performance and Fat Metabolism of Laying Hens

  • Zou, X.T.;Xu, Z.R.;Zhu, J.L.;Fang, X.J.;Jiang, J.F.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.10
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    • pp.1606-1611
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    • 2007
  • The experiment was conducted to investigate the effects of dihydropyridine on laying performance and fat metabolism of laying hens. Five hundred and forty laying hens, 40 weeks old, were randomly allotted to three groups, each of which included four replicates of 45 hens. The groups were given a basal corn-soybean meal diet supplemented with 0, 150 mg/kg and 300 mg/kg dihydropyridine. Results showed that compared with the control group (0 mg/kg dihydropyridine), supplements of 150 and 300 mg/kg dihydropyridine increased egg production rate by 9.39% (p<0.01) and 12.97% (p<0.01), increased mean egg weight by 3% (p>0.05) and 4.8% (p>0.05), and improved feed efficiency by 9.54% (p<0.05) and 7.25% (p<0.05), respectively; The addition of 150 and 300 mg/kg dihydropyridine decreased percentage of abdominal fat by 35.4% (p<0.05) and 46.9% (p<0.05), decreased liver fat content by 32.4% (p<0.05) and 10.5% (p<0.05), increased HSL activity of abdominal fat by 39.64% (p<0.05) and 48.48% (p<0.05), increased HSL activity of liver by 9.4% (p>0.05) and 47.34% (p<0.05) and increased the content of cAMP in adenohypophysis by 14.67% (p<0.05) and 10.91% (p<0.05), respectively; The inclusion of 150 mg/kg dihydropyridine increased liver superoxide dismutase activity by 69.61% (p<0.05), and increased hepatic apoB concentration by 53.96% (p<0.05); The supplementation of 150 or 300 mg/kg dihydropyridine decreased malondialdehyde concentration of hepatic mitochondria by 30.90% (p<0.01) and 10.39% (p<0.05), respectively; Supplemented dihydropyridine had no significant effects on TG, Ch HDL-C and VLDL-C concentrations in serum; addition of 150 or 300 mg/kg dihydropyridine increased T3 levels in serum by 15.34% (p<0.05) and 11.88% (p<0.05) and decreased insulin concentration by 40.44% (p<0.05) and 54.37% (p<0.05), respectively. The results demonstrated that adding dihydropyridine had the tendency of improving very low density lipoprotein receptor (VLDLR) content in the ovary. It was concluded that dihydropyridine could improve laying performance and regulate the fat metabolism of laying hens and that 150 mg/kg dihydropyridine is the optimum dose for laying birds in practical conditions.

Manufacture of Some Korean Medicinal Herb Liquors by Soaking (몇가지 약초침출주의 제조)

  • Min, Young-Kyoo;Jeong, Heon-Sang
    • Korean Journal of Food Science and Technology
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    • v.27 no.2
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    • pp.210-215
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    • 1995
  • Korean medicinal herbs -sasam, gilkyung, jakyak, danggwi, hwangki and chunkung were soaked to the distillate of Korean rice wine for 75 days. The alcohol concentration of distillate, soaking media was adjusted to 45, 35, and 25% respectively with distilled water. Changes in alcohol concentration, pH, optical density, concentration of peoniflorin and decursin were analyzed. Quality of the final product was determined by sensory evaluation. Alcohol concentration was rapidly decreased but pH increased in 15 days and thereafter they showed slow decrease. Decrease of alcohol concentration was affected by the kind of herb and alcohol concentration of soaking media. The strongest effect was observed from danggwi and low alcohol concentration. Concentration of paeoniflorin and decursin, an index component of jakyak and danggwi respectively, showed the similar trend of decrease after increase to maximum concentration. From the sensory evaluation, the best overall quality was obtained from liquors made from 45% alcohol concentration. The quality was decreased in the order of sasam, jakyak, chunkung and hwanggi.

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Studies on the Response of Rhizobium Inoculation and Nitrogen Concentration to the Soybean Growth in Nutri-Culture I. Effects of Rhizobium Inoculation and Nitrogen Concentration on the Nodulation, Total and Allantoin Nitrogen Contents of the Plants, and Contents of crude fat and Protein of Soybean Seeds in Nutri-Culture (양액재배(養液栽培)에 있어 근류균(根瘤菌)의 접종(接種) 및 질소반응(窒素反應)에 관(關)한 연구(硏究) 1. 근류균(根瘤菌)의 접종(接種) 및 질소시용량(窒素施用量)이 대두품종(大豆品種)의 근류착생(根瘤着生), 전질소(全窒素) 및 Allantoin 질소함량(窒素含量)과 종실중(種實中)의 조지방(粗脂昉) 및 조단백함량(粗蛋白含量)에 미치는 영향(影響))

  • Lee, Hong-Suk;Ku, Ja-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.3
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    • pp.245-252
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    • 1989
  • This experiment was carried out to study the effects of nitrogen concentration of cultural solution, rhizobium inoculation, and planting density on nodulation, contents of total-N and allantoin-N of the plants, and contents of crude fat and protein of the seeds with 4 cultivars and 1 non-nodulation isogenic line (Hwangeumkong, Jangbaegkong, Paldalkong, Clark, non-nodulating Clark) in nutri-culture. Modulation was increased significantly by the rhizobium inoculation and decreased by the increase of nitrogen concentration of the cultural solution and planting density, and more nodule per plant was observed in Hwangeumkong than other cultivars. Total nitrogen contents of the soybean plant were higher in Hwangeumkong and Janbaegkong compared with other two cultivars, and were increased by rhizobium inoculation and the increase of nitrogen concentration of the cultural solution except in case of $R_3$ stage of non-inoculation of rhizobium, and was decreased by the increase of planting density. Allantoin nitrogen contents of stem were lower in Paldalkong compared with other cultivars and was increased significantly by the rhizobium inoculation, and thus was correlated significantly with nodulation. Allantoin-N contents were also decreased by the increase of planting density and nitrogen concentration of the solution, and was very low in case of non-nodulating isogenic line at any level of nitrogen concentration. The contents of crude fat of the seed were lower in cases of higher nitrogen concentration of the solution and more plants per pot, but no effects of rhizobium inoculation was observed. The contents of crude protein were tend to increase by the increase of nitrogen concentration, but were little effected by rhizobium inoculation and planting density.

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Binary Doping of N-B and N-P into Graphene: Structural and Electronic properties

  • Kim, Hyo seok;Kim, Seong Sik
    • Proceeding of EDISON Challenge
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    • 2013.04a
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    • pp.256-259
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    • 2013
  • We investigate co-doping effects of conjugated P-N B-N with increasing of N concentration in the graphene sheets using a first principles based on the density functional theory. N doping sites of the graphene consider two possible sites (pyridinic and porphyrin-like). Energy calculation shows that additional doping of B atom in the porphyrin-like N doped graphene ($V+B-N_x$) is hard to form. At the low chemical potential of N, one N atom with additional doping in the graphene ($V+P-N_1$, $P/B-N_1$) has low formation energy on the other hand at high chemical potential of N, high concentration of N ($V+P-N_4$, $P/B-N_3$) in the graphene is governing conformation. From the results of electronic band structure calculation, it is found that $V+P-N_4$ and $P/B-N_3$ cases change the Fermi energy therefore type change is occurred. On the other hand, the cases of $V+P-N_1$ and N+B recover the electronic structure of pristine graphene.

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